Recent Progress in Rapid Sintering of Nanosilver for Electronics Applications

Recently, nanosilver pastes have emerged as one of the most promising high temperature bonding materials for high frequency and high power applications, which provide an effective lead-free electronic packaging solution instead of high-lead and gold-based solders. Although nanosilver pastes can be sintered at lower temperature compared to bulk silver, applications of nanosilver pastes are limited by long-term sintering time (20–30 min), relative high sintering temperature (>250 °C), and applied external pressure, which may damage chips and electronic components. Therefore, low temperature rapid sintering processes that can obtain excellent nanosilver joints are anticipated. In this regard, we present a review of recent progress in the rapid sintering of nanosilver pastes. Preparation of nanosilver particles and pastes, mechanisms of nanopastes sintering, and different rapid sintering processes are discussed. Emphasis is placed on the properties of sintered joints obtained by different sintering processes such as electric current assisted sintering, spark plasma sintering, and laser sintering, etc. Although the research on rapid sintering processes for nanosilver pastes has made a great breakthrough over the past few decades, investigations on mechanisms of rapid sintering, and the performance of joints fabricated by pastes with different compositions and morphologies are still far from enough.

[1]  J. Frenkel Viscous Flow of Crystalline Bodies under the Action of Surface Tension , 1945 .

[2]  V. Mendhulkar,et al.  Photosensitized synthesis of silver nanoparticles using Withania somnifera leaf powder and silver nitrate. , 2014, Journal of photochemistry and photobiology. B, Biology.

[3]  Fanjun Meng,et al.  Synthesis of silver and gold nanoparticles by a novel electrochemical method. , 2004, Chemphyschem : a European journal of chemical physics and physical chemistry.

[4]  Z. A. Munir,et al.  The effect of electric field and pressure on the synthesis and consolidation of materials: A review of the spark plasma sintering method , 2006 .

[5]  C. Grigoropoulos,et al.  Laser wavelength effect on laser-induced photo-thermal sintering of silver nanoparticles , 2015 .

[6]  Cao Xue-lin Research of nano-silver colloids prepared by microwave-assisted synthesis method and its fresh-keeping of strawberry , 2014 .

[7]  L. Wang,et al.  Improvement on the microstructure stability, mechanical and wetting properties of Sn-Ag-Cu lead-free solder with the addition of rare earth elements , 2004 .

[8]  Cui Guoshi Control of morphology and size of nano-silver particles in the liquid irradiation reduction process , 2010 .

[9]  G. Lu,et al.  Measurements of electrical resistance and temperature distribution during current assisted sintering of nanosilver die-attach material , 2014, 2014 International Conference on Electronics Packaging (ICEP).

[10]  G. Southam,et al.  Biosynthesis of silver nanoparticles by filamentous cyanobacteria from a silver(I) nitrate complex. , 2007, Langmuir : the ACS journal of surfaces and colloids.

[11]  Michael A. Gaynes,et al.  Development of wafer level underfill materials and assembly processes for fine pitch Pb-free solder flip chip packaging , 2011, 2011 IEEE 61st Electronic Components and Technology Conference (ECTC).

[12]  Ulrich S. Schubert,et al.  Alternative sintering methods compared to conventional thermal sintering for inkjet printed silver nanoparticle ink , 2014 .

[13]  Yoshiaki Morisada,et al.  A Low-Temperature Bonding Process Using Mixed Cu–Ag Nanoparticles , 2010 .

[14]  Y. Shacham-Diamand,et al.  Rapid laser sintering of metal nano-particles inks , 2016, Nanotechnology.

[15]  Xiaojian Wang,et al.  Mechanisms of PVP in the preparation of silver nanoparticles , 2005 .

[16]  J. K. Chen,et al.  Femtosecond laser sintering of copper nanoparticles , 2016 .

[17]  K. S. Siow,et al.  Mechanical properties of nano-silver joints as die attach materials , 2012 .

[18]  Zhu Zhi-hon Microwave Method for Preparing Nano Silver Sol , 2014 .

[19]  Byunghoon Kang,et al.  Preparation and Characterization of Silver Nanoparticles Embedded in Silica Sol Particles , 2011 .

[20]  Yi-Shao Lai,et al.  Stress–strain characteristics of tin-based solder alloys at medium strain rate , 2008 .

[21]  J. Yeo,et al.  Large-Area Compatible Laser Sintering Schemes with a Spatially Extended Focused Beam , 2017, Micromachines.

[22]  Fu-chi Wang,et al.  A novel and rapid route for synthesizing nanocrystalline aluminum , 2014 .

[23]  R.W. Johnson,et al.  The changing automotive environment: high-temperature electronics , 2004, IEEE Transactions on Electronics Packaging Manufacturing.

[24]  L. Balan,et al.  Silver nanoparticles: New synthesis, characterization and photophysical properties , 2007 .

[25]  S. Hannula,et al.  Spark plasma sintering of submicron-sized Cu-powder—Influence of processing parameters and powder oxidization on microstructure and mechanical properties , 2010 .

[26]  Hongyuan Chen,et al.  Preparation of silver nanorods by electrochemical methods , 2001 .

[27]  Zuhair A. Munir,et al.  Electric Current Activation of Sintering: A Review of the Pulsed Electric Current Sintering Process , 2011 .

[28]  A. Wu,et al.  Low Temperature Bonding of Cu Metal through Sintering of Ag Nanoparticles for High Temperature Electronic Application , 2010 .

[29]  Zeag Xiaoyan Synthesis of Silver Nanoparticles by Chemical Reduction Method and Properties of Nano-silver Conductive Paste , 2011 .

[30]  Xin Li,et al.  Electric-current-assisted sintering of nanosilver paste for copper bonding , 2017, Journal of Materials Science: Materials in Electronics.

[31]  S. Devi,et al.  Microwave-assisted synthesis of silver nanoparticles using ethanol as a reducing agent , 2009 .

[32]  K. S. Siow,et al.  Are Sintered Silver Joints Ready for Use as Interconnect Material in Microelectronic Packaging? , 2014, Journal of Electronic Materials.

[33]  A. Shaler,et al.  Mechanism of Sintering , 1948 .

[34]  T. Morita,et al.  Evaluation of Copper Oxide-Based Interconnecting Materials , 2010 .

[35]  Jun Zhang,et al.  Uniaxial ratchetting behavior of anisotropic conductive adhesive film under cyclic tension , 2011 .

[36]  O. Guillon,et al.  Field‐Assisted Sintering Technology/Spark Plasma Sintering: Mechanisms, Materials, and Technology Developments , 2014 .

[37]  Chunqing Wang,et al.  Fabrication of interconnects using pressureless low temperature sintered Ag nanoparticles , 2012 .

[38]  L. Mendizabal,et al.  Review on Joint Shear Strength of Nano-Silver Paste and Its Long-Term High Temperature Reliability , 2014, Journal of Electronic Materials.

[39]  Akira Watanabe,et al.  Conductive network structure formed by laser sintering of silver nanoparticles , 2014, Journal of Nanoparticle Research.

[40]  R. L. Coble,et al.  Sintering Crystalline Solids. I. Intermediate and Final State Diffusion Models , 1961 .

[41]  Khai D. T. Ngo,et al.  Simplification of the Nanosilver Sintering Process for Large-Area Semiconductor Chip Bonding: Reduction of Hot-Pressing Temperature Below 200/spl deg/C , 2013, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[42]  G. Lu,et al.  Characterization and Reliability of Sintered Nanosilver Joints by a Rapid Current-Assisted Method for Power Electronics Packaging , 2014, IEEE Transactions on Device and Materials Reliability.

[43]  Ming-Tsang Lee,et al.  Laser direct synthesis and patterning of silver nano/microstructures on a polymer substrate. , 2014, ACS applied materials & interfaces.

[44]  H. Hou,et al.  A simple template method for hierarchical dendrites of silver nanorods and their applications in catalysis , 2008 .

[45]  Wu Ma Molecular dynamics simulation for the sintering process of Au nanoparticles , 2014 .

[46]  Li Chen,et al.  Synthesis of Silver Nanoparticles through the Soft Template Method and their Applications to Surface-Enhanced Raman Scattering , 2013 .

[47]  G. Lu,et al.  Microstructure and Joint Properties of Nano-Silver Paste by Ultrasonic-Assisted Pressureless Sintering , 2016, Journal of Electronic Materials.

[48]  Hongyuan Chen,et al.  Ultrasonic-assisted synthesis of monodisperse single-crystalline silver nanoplates and gold nanorings. , 2004, Inorganic chemistry.

[49]  A. Kudelski,et al.  Light-induced transformation of citrate-stabilized silver nanoparticles: Photochemical method of increase of SERS activity of silver colloids , 2014 .

[50]  M. Brochu,et al.  Microstructure and mechanical properties of air atomized aluminum powder consolidated via spark plasma sintering , 2014 .

[51]  Chunqing Wang,et al.  Laser Sintering of Nano-Ag Particle Paste for High-Temperature Electronics Assembly , 2017, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[52]  V. Subramaniam,et al.  Silver Nanoparticle Aggregates as Highly Efficient Plasmonic Antennas for Fluorescence Enhancement , 2012 .

[53]  Kojiro F. Kobayashi,et al.  Metal-metal bonding process using Ag metallo-organic nanoparticles , 2005 .

[54]  A. Sa’ar,et al.  Laser sintering of copper nanoparticles , 2014 .

[55]  Yanlong Tai,et al.  Green approach to prepare silver nanoink with potentially high conductivity for printed electronics , 2011 .

[56]  M. Brochu,et al.  Consolidation of aluminum-based metal matrix composites via spark plasma sintering , 2015 .

[57]  N. Eltugral,et al.  Preparation of nano-silver-supported activated carbon using different ligands , 2016, Research on Chemical Intermediates.

[58]  J. K. Chen,et al.  Modeling of Ultrafast Phase Change Processes in a Thin Metal Film Irradiated by Femtosecond Laser Pulse Trains , 2011 .

[59]  Suk‐Joong L. Kang,et al.  Sintering: Densification, Grain Growth and Microstructure , 2005 .

[60]  Yoon-Sik Lee,et al.  Spontaneous formation of silver nanoparticles on polymeric supports , 2009 .

[61]  Antonio Mario Locci,et al.  Energy efficiency during conventional and novel sintering processes: the case of Ti–Al2O3–TiC composites , 2009 .

[62]  Guofeng Bai,et al.  Low-temperature sintering of nanoscale silver paste for semiconductor device interconnection , 2005 .

[63]  S. Moon,et al.  Thermal conductivity estimation of inkjet-printed silver nanoparticle ink during continuous wave laser sintering , 2015 .

[64]  Qi Zhang,et al.  Synthesis of silver nano particles and fabrication of aqueous Ag inks for inkjet printing , 2011 .

[65]  K. S. Shin,et al.  One-Step Fabrication of Poly(ethylenimine)-Stabilized Silver Nanoparticles from Insoluble Silver Chloride Salt , 2011 .

[66]  Yi Li,et al.  Recent advances of conductive adhesives as a lead-free alternative in electronic packaging: Materials, processing, reliability and applications , 2006 .

[67]  X. Lan,et al.  Microwave-assisted synthesis of size-controlled silver nanoparticles using polyvinyl pyrrolidone as a reducing agent , 2014 .

[68]  T. Scheper,et al.  Electrochemical method for the synthesis of silver nanoparticles , 2009 .

[69]  D. Dimos,et al.  Development of conductivity in low conversion temperature silver pastes via addition of nanoparticles , 2002 .

[70]  G. Lu,et al.  Characterizations of Rapid Sintered Nanosilver Joint for Attaching Power Chips , 2016, Materials.

[71]  S. H. Park,et al.  One-step large-scale synthesis of micrometer-sized silver nanosheets by a template-free electrochemical method , 2013, Nanoscale Research Letters.

[72]  X. Qiao,et al.  Controllable Synthesis and Ostwald Ripening of Silver Nanoparticles , 2013 .

[73]  Rita Singh,et al.  Radiation synthesis of PVP/alginate hydrogel containing nanosilver as wound dressing , 2012, Journal of Materials Science: Materials in Medicine.

[74]  K. Cheong,et al.  Thermal characteristic of sintered Ag–Cu nanopaste for high-temperature die-attach application , 2015 .

[75]  Guanwei Luo,et al.  Wada bifurcations and partially Wada basin boundaries in a two-dimensional cubic map☆ , 2013 .

[76]  P. Maheswari,et al.  Preparation and performance of silver nanoparticle incorporated polyetherethersulfone nanofiltration membranes , 2013 .

[77]  Ioanna Zergioti,et al.  Selective laser sintering of Ag nanoparticles ink for applications in flexible electronics , 2015 .

[78]  Luis M. Liz-Marzán,et al.  Reduction and Stabilization of Silver Nanoparticles in Ethanol by Nonionic Surfactants , 1996 .

[79]  A. Weibel,et al.  Spark plasma sintering of alumina: Study of parameters, formal sintering analysis and hypotheses on the mechanism(s) involved in densification and grain growth , 2011 .

[80]  Yutaka Kagawa,et al.  Spark Plasma Sintering of Zirconium Diborides , 2008 .

[81]  A. Wu,et al.  Polymer-Protected Cu-Ag Mixed NPs for Low-Temperature Bonding Application , 2012, Journal of Electronic Materials.

[82]  G. Dirras,et al.  Microstructure and mechanical behavior of ultrafine-grained Ni processed by different powder metallurgy methods , 2009 .

[83]  Akio Hirose,et al.  Bonding Technique Using Micro-Scaled Silver-Oxide Particles for In-Situ Formation of Silver Nanoparticles , 2008 .

[84]  Peter J. Hesketh,et al.  Finite-element analysis of thermal stresses in a silicon pressure sensor for various die-mount materials , 1994 .

[85]  Chunxiang Xu,et al.  Low temperature sintering of Ag nanoparticles for flexible electronics packaging , 2010 .

[86]  A. López-Valdivieso,et al.  Silver nanoparticles synthesis in aqueous solutions using sulfite as reducing agent and sodium dodecyl sulfate as stabilizer , 2012, Journal of Nanoparticle Research.

[87]  Xian Jian-wei Research advancement of high temperature lead-free electronic packaging , 2009 .

[88]  N. Kim,et al.  Synthesis of Silver Nanoparticles at the Liquid–Liquid Using Ultrasonic Wave , 2013 .

[89]  Yingyu Zhou,et al.  Radiation synthesis and characterization of nanosilver/gelatin/carboxymethyl chitosan hydrogel , 2012 .

[90]  A. Wu,et al.  Mechanism of Low Temperature Sintering-Bonding through In-Situ Formation of Silver Nanoparticles Using Silver Oxide Microparticles , 2013 .

[91]  Xu Chen,et al.  Simplification of Low-Temperature Sintering Nanosilver for Power Electronics Packaging , 2013, Journal of Electronic Materials.

[92]  S. Pandey,et al.  Green synthesis of biopolymer-silver nanoparticle nanocomposite: an optical sensor for ammonia detection. , 2012, International journal of biological macromolecules.

[93]  G. Lu,et al.  Effects of Die-Attach Material and Ambient Temperature on Properties of High-Power COB Blue LED Module , 2015, IEEE Transactions on Electron Devices.

[94]  S. Dubas,et al.  Green synthesis of silver nanoparticles for ammonia sensing. , 2008, Talanta.

[95]  Y. Zhou,et al.  Silver Nanoparticle Paste for Low-Temperature Bonding of Copper , 2011 .

[96]  Khiam Aik Khor,et al.  Spark plasma sintering of silver nanopowder , 2007, SPIE Micro + Nano Materials, Devices, and Applications.

[97]  B. Ding,et al.  Monodisperse silver microspheres: A facile BSA template method , 2013 .

[98]  N. Takeda,et al.  Evaluation of Interfacial Bonding Utilizing Ag2O-Derived Silver Nanoparticles Using TEM Observation and Molecular Dynamics Simulation , 2010 .

[99]  Kojiro F. Kobayashi,et al.  Study of Bonding Technology Using Silver Nanoparticles , 2008 .

[100]  X. Qiao,et al.  Synthesis of nanosilver colloidal particles in water/oil microemulsion , 2007 .

[101]  K. Maekawa,et al.  Laser Sintering of Silver Nanoparticles for Electronic Use , 2010 .

[102]  M. Jeong,et al.  Microwave Sintering of Silver Nanoink for Radio Frequency Applications. , 2015, Journal of nanoscience and nanotechnology.

[103]  V. Subramanian,et al.  Investigation of Gold Nanoparticle Inks for Low-Temperature Lead-Free Packaging Technology , 2009 .

[104]  宗宮 重行,et al.  Sintering key papers , 1990 .

[105]  Jing-fu Liu,et al.  Methods for separation, identification, characterization and quantification of silver nanoparticles , 2012 .

[106]  Morphological Effect on Fluorescence Behavior of Silver Nanoparticles , 2014, Journal of Fluorescence.

[107]  Wang Chunqing Pressureless Low Temperature Sintering of Ag Nanoparticles Applied to Electronic Packaging , 2012 .

[108]  Hiroshi Saito,et al.  Drop-on-Demand Laser Sintering With Silver Nanoparticles for Electronics Packaging , 2012, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[109]  Y. Sakka,et al.  Electric current activated/assisted sintering (ECAS): a review of patents 1906–2008 , 2009, Science and technology of advanced materials.

[110]  Hu Anming,et al.  Preparation of PVP coated Cu NPs and the application for low-temperature bonding , 2011 .

[111]  H. Ghorbani,et al.  Synthesis of silver nanoparticles with different shapes , 2015, Arabian Journal of Chemistry.

[112]  M. Ge,et al.  Properties investigation on isotropical conductive adhesives filled with silver coated carbon nanotubes , 2007 .

[113]  M. Y. Yang,et al.  The effect of negative pressure aging on the aggregation of Cu2O nanoparticles and its application to laser induced copper electrode fabrication. , 2015, Physical chemistry chemical physics : PCCP.

[114]  Wang Chun-xi Preparation of Nano-sized Silver Particles by Liquid Chemical Reduction Method , 2014 .

[115]  Tokeer Ahmad,et al.  Silver nanoparticles: Ultrasonic wave assisted synthesis, optical characterization and surface area studies , 2011 .

[116]  Matti Mäntysalo,et al.  Comparison of laser and intense pulsed light sintering (IPL) for inkjet-printed copper nanoparticle layers , 2015, Scientific Reports.

[117]  Shear strength of copper joints prepared by low temperature sintering of silver nanoparticles , 2014, Electronic Materials Letters.

[118]  F. Schoenstein,et al.  Spark Plasma Sintering constrained process parameters of sintered silver paste for connection in power electronic modules: Microstructure, mechanical and thermal properties , 2014 .

[119]  Y. Liu,et al.  Microstructure characteristic, mechanical properties and sintering mechanism of nanocrystalline copper obtained by SPS process , 2009 .

[120]  S. Iravani,et al.  Synthesis of silver nanoparticles using methanol and dichloromethane extracts of Pulicaria gnaphalodes (Vent.) Boiss. aerial parts , 2016, Artificial cells, nanomedicine, and biotechnology.

[121]  Bing Zhao,et al.  A simple method to synthesize triangular silver nanoparticles by light irradiation. , 2006, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[122]  K. Suganuma,et al.  Time-dependent sintering properties of Ag nanoparticle paste for room temperature bonding , 2009, International Conference on Nanotechnology.

[123]  D. Berk,et al.  Precipitation of silver powders in the presence of ethylenediamine tetraacetic acid , 2006 .

[124]  K. D. T. Ngo,et al.  Low-Pressure Joining of Large-Area Devices on Copper Using Nanosilver Paste , 2013, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[125]  N. Takeda,et al.  A novel metal-to-metal bonding process through in-situ formation of Ag nanoparticles using Ag2O microparticles , 2009 .

[126]  G. Lu,et al.  Rapid Sintering Nanosilver Joint by Pulse Current for Power Electronics Packaging , 2013, IEEE Transactions on Device and Materials Reliability.

[127]  I. El-Sherbiny,et al.  Preparation of silver nanoparticles in the presence of chitosan by electrochemical method. , 2012, Carbohydrate polymers.

[128]  D. Bonfert,et al.  Experimental method for low-temperature sintering of nano-Ag inks using electrical excitation , 2012, 2012 12th IEEE International Conference on Nanotechnology (IEEE-NANO).

[129]  Qingsong Xu,et al.  Preparation of solid silver nanoparticles for inkjet printed flexible electronics with high conductivity. , 2014, Nanoscale.

[130]  Philippe Godignon,et al.  Thermomechanical Assessment of Die-Attach Materials for Wide Bandgap Semiconductor Devices and Harsh Environment Applications , 2014, IEEE Transactions on Power Electronics.

[131]  G. Zou,et al.  Joining of Silver Nanomaterials at Low Temperatures: Processes, Properties, and Applications. , 2015, ACS applied materials & interfaces.

[132]  Kuan Yew Cheong,et al.  Die Attach Materials for High Temperature Applications: A Review , 2011, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[133]  M. Yuen,et al.  Highly conductive die attach adhesive from percolation control and its applications in light-emitting device thermal management , 2013 .

[134]  Thomas R. Bieler,et al.  Cyclic twin nucleation in tin-based solder alloys , 2010 .

[135]  Jianguo Liu,et al.  Silver nanoparticles prepared by chemical reduction-protection method, and their application in electrically conductive silver nanopaste , 2010 .

[136]  K. S. Siow,et al.  Rapid sintering of nano-Ag paste at low current to bond large area (>100 mm2) power chips for electronics packaging , 2018 .

[137]  G. Lu,et al.  Control of nanosilver sintering attained through organic binder burnout , 2007 .

[138]  Chunsheng Guo,et al.  Determination of Thermal Fatigue Delamination of Die Attach Materials for High-Brightness LEDs , 2012, IEEE Photonics Technology Letters.

[139]  Z. Murthy,et al.  Highly monodisperse and sub-nano silver particles synthesis via microemulsion technique , 2010 .

[140]  W. Kingery,et al.  Effects of Applied Pressure on Densification During Sintering in the Presence of a Liquid Phase , 1963 .

[141]  A. Wu,et al.  Sintering mechanisms and mechanical properties of joints bonded using silver nanoparticles for electronic packaging applications , 2015, Welding in the World.

[142]  P. Švec,et al.  Effect of indium on the microstructure of the interface between Sn3.13Ag0.74CuIn solder and Cu substrate , 2009 .

[143]  J. Lee,et al.  Laser-Sintered Silver Nanoparticles as a Die Adhesive Layer for High-Power Light-Emitting Diodes , 2014, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[144]  Sang-Ho Lee,et al.  Rapid sintering of copper nano ink using a laser in air , 2014 .

[145]  A. Wu,et al.  Pressureless bonding process using Ag nanoparticle paste for flexible electronics packaging , 2012 .

[146]  Seung Hwan Ko,et al.  Selective sintering of metal nanoparticle ink for maskless fabrication of an electrode micropattern using a spatially modulated laser beam by a digital micromirror device. , 2014, ACS applied materials & interfaces.

[147]  K. Maekawa,et al.  On-Demand Infrared Laser Sintering of Gold Nanoparticle Paste for Electrical Contacts , 2015, IEEE Transactions on Components, Packaging and Manufacturing Technology.

[148]  Xiangrong Xi,et al.  Research of silver plating nano-graphite filled conductive adhesive , 2009 .

[149]  Pradeep Lall,et al.  Experimental determination of fatigue behavior of lead free solder joints in microelectronic packaging subjected to isothermal aging , 2016, Microelectron. Reliab..

[150]  R. German Manipulation of Strength During Sintering as a Basis for Obtaining Rapid Densification without Distortion , 2001 .

[151]  Guo-Quan Lu,et al.  Low-Temperature Sintered Nanoscale Silver as a Novel Semiconductor Device-Metallized Substrate Interconnect Material , 2006, IEEE Transactions on Components and Packaging Technologies.

[152]  K. Maekawa,et al.  Laser sintering of Ag nanopaste film and its application to bond-pad formation , 2008, 2008 58th Electronic Components and Technology Conference.

[153]  M. Brochu,et al.  Fabrication of bulk nanostructured silver material from nanopowders using shockwave consolidation technique , 2008 .

[154]  X. Qiao,et al.  Controllable Preparation of Silver Nanostructures and the Effects of Acidity-Basicity of the Reaction System , 2014 .

[155]  A. Kudelski,et al.  Light-induced growth of various silver seed nanoparticles: A simple method of synthesis of different silver colloidal SERS substrates , 2015 .

[156]  K. Nishio,et al.  Spark Plasma Sintering of Sol–Gel Derived Amorphous ZrW2O8 Nanopowder , 2009 .

[157]  Qingsong Xu,et al.  Properties of polyacrylic acid-coated silver nanoparticle ink for inkjet printing conductive tracks on paper with high conductivity , 2014 .

[158]  Fu-chi Wang,et al.  The sintering mechanism in spark plasma sintering – Proof of the occurrence of spark discharge , 2014 .

[159]  N. Samadi,et al.  Synthesis and antimicrobial effects of silver nanoparticles produced by chemical reduction method , 2010, Daru : journal of Faculty of Pharmacy, Tehran University of Medical Sciences.

[160]  Sanat Wagle,et al.  Using Silver Nano-Particle Ink in Electrode Fabrication of High Frequency Copolymer Ultrasonic Transducers: Modeling and Experimental Investigation , 2015, Sensors.

[161]  Guo-Quan Lu,et al.  Thermomechanical Reliability of Low-Temperature Sintered Silver Die Attached SiC Power Device Assembly , 2006, IEEE Transactions on Device and Materials Reliability.