Structure-property relationships in 1,2,4-tri-donor-substituted anthraquinones — 2-amino-1,4-dihydroxyanthraquinones

Condensation of 2-bromo-, 2-sulpho- or 2-phenoxy-1,4-dihydroxyanthraquinone with primary or secondary amines affords a series of 2-aminated derivatives. These compounds colour synthetic-polymer fibres, particularly polyester, in red hues of good build-up and fastness to light. Colour-structure relationships of the dyes are discussed within the general context of substituent effects in 1,2,4-tri-donor-substituted anthraquinones.