Characterization of K-Al-, K-Fe- and K-Mg-priderite grown from melts.

Single crystals of K-priderites (Kx(M,Ti)8O16, M=Al, Fe and Mg) were grown from melts. Despite of the wide range of the solid solution the composition of all the single crystals obtained was around x=1.5. The prismatic faces of K–Al– and K–Mg-priderite consisted mainly of planes {100} with small {110} and those of K-Fe-priderite consist mainly of {110} with small {100}. The terminal faces of the crystals were made up of vicinal faces with irregular interfacial angle. The cleavage of the crystals was parallel to {110} on each priderite. Pleochroism of K–Al-priderite: O-colorless, E-blue; K–Fe-priderite: O-dark brown, E-dark brown with blue; K–Mg-priderite: O-pale blue, E-dark blue. The optical properties of Al2TiO5 and MgTi2O5 crystals included in priderite single crystals were also described.

[1]  H. Ohsato,et al.  Formation Region of K-Al-Priderite (KxAlxTi8-xO16) , 1992 .

[2]  S. Yoshikado,et al.  Growth of Ba-AL - and K-Zn-priderite single-crystals by the FZ method and ionic conductivities , 1988 .

[3]  H. Kanbayashi,et al.  Preparation and Crystal Structure of the Potassium-Priderite Type Solid Solutions , 1987 .

[4]  H. Toraya,et al.  Whole-powder-pattern fitting without reference to a structural model: application to X-ray powder diffraction data , 1986 .

[5]  R. W. Cheary An analysis of the structural characteristics of hollandite compounds , 1986 .

[6]  T. Sasaki,et al.  Flux growth of potassium-priderite single crystals , 1983 .

[7]  L. Bursill,et al.  Incommensurate superlattice ordering in the hollandites BaxTi8−xMgxO16 and BaxTi8−2xGa2xO16 , 1980 .

[8]  A. E. Ringwood,et al.  The structure and chemistry of a barium titanate hollandite‐type phase , 1980 .

[9]  C. Schüler,et al.  Crystal growth and structural properties of some Hollandites , 1980 .

[10]  A. Albee,et al.  Empirical Correction Factors for the Electron Microanalysis of Silicates and Oxides , 1968, The Journal of Geology.

[11]  G. Bayer,et al.  Complex alkali titanium oxides Ax(ByTi8−y)O16 of the α-MnO2 structure-type , 1966 .

[12]  L. W. Coughanour,et al.  Phase equilibria in the system MgO-TiO_2 , 1953 .

[13]  L. H. Maxwell,et al.  The system beryllia-alumina-titania: phase relations and general physical properties of three-component porcelains , 1952 .

[14]  K. Norrish Priderite, a new mineral from the leucite-lamproites of the west Kimberley area, Western Australia , 1951 .

[15]  A. Byström,et al.  The crystal structure of hollandite, the related manganese oxide minerals, and α-MnO2 , 1950 .