Thermo-mechanical properties of randomly oriented carbon/epoxy nanocomposites

The thermo-mechanical properties of epoxy-based nanocomposites based on low weight fractions (from 0.01 to 0.5 wt%) of randomly oriented single- and multi-walled carbon nanotubes were examined. Preparation methods for the nanocomposites, using two types of epoxy resins, were developed and good dispersion was generally achieved. The mechanical properties examined were the tensile Young's modulus by Dynamic Mechanical Thermal Analysis and the toughness under tensile impact using notched specimens. Moderate Young's modulus improvements of nanocomposites were observed with respect to the pure matrix material. A particularly significant enhancement of the tensile impact toughness was obtained for specific nanocomposites, using only minute nanotube weight fractions. No significant change in the glass transition temperature of SWCNT/epoxy nanocomposites was observed, compared to that of the epoxy matrix. The elastic modulus of the SWNT-based nanocomposites was found to be slightly higher than the value predicted by the Krenchel model for short-fiber composites with random orientation.

[1]  Asa H Barber,et al.  Static and dynamic wetting measurements of single carbon nanotubes. , 2004, Physical review letters.

[2]  R. Ruoff,et al.  Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load , 2000, Science.

[3]  A. Rinzler,et al.  Electronic structure of atomically resolved carbon nanotubes , 1998, Nature.

[4]  H. Wagner Nanotube-polymer adhesion: a mechanics approach , 2002 .

[5]  L. Montagnier,et al.  Prospects for the Future , 2002, Science.

[6]  R. Superfine,et al.  Bending and buckling of carbon nanotubes under large strain , 1997, Nature.

[7]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[8]  M. Hodak,et al.  Carbon nanotubes, buckyballs, ropes, and a universal graphitic potential , 2000 .

[9]  C. Lieber,et al.  Atomic structure and electronic properties of single-walled carbon nanotubes , 1998, Nature.

[10]  M. S. de Vries,et al.  Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls , 1993, Nature.

[11]  T. Chou,et al.  On the elastic properties of carbon nanotube-based composites: modelling and characterization , 2003 .

[12]  Rodney S. Ruoff,et al.  Mechanical and thermal properties of carbon nanotubes , 1995 .

[13]  T. Chou,et al.  Advances in the science and technology of carbon nanotubes and their composites: a review , 2001 .

[14]  P. Ajayan,et al.  Capillarity-induced filling of carbon nanotubes , 1993, Nature.

[15]  Hiroshi Fukuda,et al.  On Young's modulus of short fibre composites , 1974 .

[16]  Sidney R. Cohen,et al.  Detachment of nanotubes from a polymer matrix , 2002 .

[17]  Quantized phonon spectrum of single-wall carbon nanotubes , 2000, Science.

[18]  Karl Schulte,et al.  Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites , 2003 .

[19]  Sidney R. Cohen,et al.  Measurement of carbon nanotube-polymer interfacial strength , 2003 .

[20]  Reshef Tenne,et al.  Stress-induced fragmentation of multiwall carbon nanotubes in a polymer matrix , 1998 .

[21]  Charles M. Lieber,et al.  Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes , 1997 .

[22]  Milo S. P. Shaffer,et al.  Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties , 1999 .

[23]  T. Ebbesen,et al.  Exceptionally high Young's modulus observed for individual carbon nanotubes , 1996, Nature.

[24]  David Hui,et al.  The revolutionary creation of new advanced materials - Carbon nanotube composites , 2002 .

[25]  S. Namilae,et al.  Transmission electron microscopy observations of fracture of single-wall carbon nanotubes under axial tension , 1998 .

[26]  K. Schulte,et al.  Carbon nanotube-reinforced epoxy-composites: enhanced stiffness and fracture toughness at low nanotube content , 2004 .

[27]  T. Ichihashi,et al.  Single-shell carbon nanotubes of 1-nm diameter , 1993, Nature.

[28]  Linda S. Schadler,et al.  LOAD TRANSFER IN CARBON NANOTUBE EPOXY COMPOSITES , 1998 .