Wavelength‐dependent determination of the recombination rate coefficients in single‐quantum‐well GaInN/GaN light emitting diodes

The recombination rate coefficients (RRCs) A, B, and C in MOVPE-grown single-quantum-well light emitting diodes spanning the entire blue-green spectral range are determined by fitting efficiency curves and differential carrier lifetimes. The results show definite trends for each of the RRCs: A tendentially decreases with increasing wavelength, B definitely decreases, and C remains approximately constant. Therefore, the increase of the droop with increasing wavelength (the green gap problem) is rather due to the decrease of B than an increase of C. The determined values of C are shown to be similar to what has been predicted by others with first-principles computer simulations accounting for phonon-assisted Auger recombination. Samples grown on sapphire and silicon substrates are compared and show significant differences only for the RRC A, presumably due to the difference in threading dislocation density.

[1]  Lateral charge carrier diffusion in InGaN quantum wells , 2012 .

[2]  S. Nakamura,et al.  Characteristics of InGaN-Based UV/Blue/Green/Amber/Red Light-Emitting Diodes , 1999 .

[3]  B. Hahn,et al.  Micro‐electroluminescence of cyan InGaN‐based multiple quantum well structures , 2011 .

[4]  E. F. Schubert,et al.  High-efficiency AlGaInP light-emitting diodes for solid-state lighting applications , 2004 .

[5]  M. Goano,et al.  A numerical study of Auger recombination in bulk InGaN , 2010 .

[6]  K. Delaney,et al.  Indirect Auger recombination as a cause of efficiency droop in nitride light-emitting diodes , 2011 .

[7]  Takashi Mukai,et al.  P-GaN/N-InGaN/N-GaN Double-Heterostructure Blue-Light-Emitting Diodes , 1993 .

[8]  S. Nakamura,et al.  Spontaneous emission of localized excitons in InGaN single and multiquantum well structures , 1996 .

[9]  A. I. Zhmakin Enhancement of light extraction from light emitting diodes , 2011 .

[10]  T. Mukai,et al.  White light emitting diodes with super-high luminous efficacy , 2010 .

[11]  Jorg Hader,et al.  On the origin of IQE‐‘droop’ in InGaN LEDs , 2009 .

[12]  Michael R. Krames,et al.  Carrier distribution in (0001)InGaN∕GaN multiple quantum well light-emitting diodes , 2008 .

[13]  Jorg Hader,et al.  Density-activated defect recombination as a possible explanation for the efficiency droop in GaN-based diodes , 2010 .

[14]  P. K. Basu Theory of Optical Processes in Semiconductors , 2003 .

[15]  Patrick Rode,et al.  Influence of indium content and temperature on Auger-like recombination in InGaN quantum wells grown on (111) silicon substrates , 2012 .

[16]  Moritz Brendel,et al.  Auger recombination in GaInN/GaN quantum well laser structures , 2011 .

[17]  H. Morkoç,et al.  On carrier spillover in c- and m-plane InGaN light emitting diodes , 2009 .

[18]  M. H. Crawford,et al.  Internal quantum efficiency and non-radiative recombination coefficient of GaInN/GaN multiple quantum wells with different dislocation densities , 2009, 2009 Conference on Lasers and Electro-Optics and 2009 Conference on Quantum electronics and Laser Science Conference.

[19]  Tobias Meyer,et al.  New developments in green LEDs , 2009 .

[20]  Michael R. Krames,et al.  Auger recombination in InGaN measured by photoluminescence , 2007 .

[21]  Han-Youl Ryu,et al.  Analysis of Time-resolved Photoluminescence of InGaN Quantum Wells Using the Carrier Rate Equation , 2010 .

[22]  S. Lutgen,et al.  On the importance of radiative and Auger losses in GaN-based quantum wells , 2008 .

[23]  B. Hahn,et al.  A combined electro-optical method for the determination of the recombination parameters in InGaN-based light-emitting diodes , 2009 .

[24]  Meng Zhang,et al.  Direct measurement of auger recombination in In0.1Ga0.9N/GaN quantum wells and its impact on the efficiency of In0.1Ga0.9N/GaN multiple quantum well light emitting diodes , 2009 .

[25]  M. Albrecht,et al.  Impact of buffer growth on crystalline quality of GaN grown on Si(111) substrates , 2012 .

[26]  Xing Li,et al.  Pivotal role of ballistic and quasi-ballistic electrons on LED efficiency , 2010 .

[27]  J. Piprek Efficiency droop in nitride‐based light‐emitting diodes , 2010 .

[28]  S. Karpov Effect of localized states on internal quantum efficiency of III‐nitride LEDs , 2010 .

[29]  S. Denbaars,et al.  Group III-nitride lasers: a materials perspective , 2011 .

[30]  James W. Kretchmer,et al.  Blue and near-ultraviolet light-emitting diodes on free-standing GaN substrates , 2004 .

[31]  G. W. ’t Hooft,et al.  Method for determining effective nonradiative lifetime and leakage losses in double‐heterostructure lasers , 1981 .

[32]  Michelle A. Moram,et al.  X-ray diffraction of III-nitrides , 2009 .

[33]  Jong-In Shim,et al.  An Explanation of Efficiency Droop in InGaN-based Light Emitting Diodes: Saturated Radiative Recombination Rate at Randomly Distributed In-Rich Active Areas , 2011 .

[34]  Jerry R. Meyer,et al.  Band parameters for nitrogen-containing semiconductors , 2003 .

[35]  B. Hahn,et al.  High-Power and High-Efficiency InGaN-Based Light Emitters , 2010, IEEE Transactions on Electron Devices.

[36]  E. Schubert,et al.  Analytic model for the efficiency droop in semiconductors with asymmetric carrier-transport properties based on drift-induced reduction of injection efficiency , 2012 .

[37]  W. Read,et al.  Statistics of the Recombinations of Holes and Electrons , 1952 .

[38]  Aurelien J. F. David,et al.  Droop in III-nitrides: Comparison of bulk and injection contributions , 2010 .

[39]  Petr G. Eliseev,et al.  Recombination balance in green-light-emitting GaN/InGaN/AlGaN quantum wells , 1999 .

[40]  Robert W. Martin,et al.  Colorimetry and efficiency of white LEDs: Spectral width dependence , 2012 .