论文信息 - [Mn6] under pressure: a combined crystallographic and magnetic study.

[Mn6] under pressure: a combined crystallographic and magnetic study.

Folding under pressure: Crystallographic studies on a Mn6 single-molecule magnet under high pressure conditions show the drastic structural changes of the magnetic core (see picture, Mn purple, O red, N blue), which impact on the magnetic properties of ferromagnetic exchange between the metal atoms will be in booster weaker, and under extremely high pressure, a transition to antiferromagnetic behavior.

[1] W. Wernsdorfer,et al. Toward a magnetostructural correlation for a family of Mn6 SMMs. , 2007, Journal of the American Chemical Society.

[2] W. Wernsdorfer,et al. Enhancing SMM properties in a family of [Mn6] clusters. , 2007, Chemical communications.

[3] P. Wood,et al. Spin switching via targeted structural distortion. , 2007, Journal of the American Chemical Society.

[4] W. Wernsdorfer,et al. A record anisotropy barrier for a single-molecule magnet. , 2007, Journal of the American Chemical Society.

[5] P. Wood,et al. A single-molecule magnet with a "twist". , 2007, Journal of the American Chemical Society.

[6] K. Awaga,et al. Magneto-structural correlation in the Jahn–Teller isomers of Mn12 , 2006 .

[7] H. Güdel,et al. Single‐Molecule Magnets Under Pressure , 2006 .

[8] H. Güdel,et al. Effect of pressure on the magnetic anisotropy in the single-molecule magnet Mn12-acetate: an inelastic neutron scattering study. , 2005, Angewandte Chemie.

[9] G. Christou,et al. Pressure dependence of the magnetic anisotropy in the single-molecule magnet Mn4O3Br(OAc)3(dbm)3 , 2004, cond-mat/0407235.

[10] K. Awaga,et al. Enhancement of Jahn-Teller isomerism in Mn12Ac under high quasi-hydrostatic pressure , 2003 .

[11] William A. Bassett,et al. Miniature diamond anvil pressure cell for single crystal x‐ray diffraction studies , 1974 .