In situ pore water sampling in deep intertidal flat sediments

In this study, we present a multilevel in situ pore water sampler that allows pore water sampling down to 5 m sediment depth. The sampler forms a crucial tool to study biogeochemical processes on different time scales in advective pore water systems. After insertion into the sediment, the sampler stays on site, allowing repetitive sampling at identical locations and depth intervals. The sampler has been successfully tested for 1 year in sandy sediments in the backbarrier tidal flats of Spiekeroog Island at the German North Sea coast. Depth profiles of redox‐sensitive elements show a high depth resolution and are not affected by oxidation artifacts during extraction. Seasonal variations because of advection and changing microbial activity are apparent for some element species even at sediment depths of 5 m.

[1]  Rainer Reuter,et al.  Sources and fate of manganese in a tidal basin of the German Wadden Sea , 2007 .

[2]  U. Werner,et al.  Surficial and deep pore water circulation governs spatial and temporal scales of nutrient recycling in intertidal sand flat sediment , 2006 .

[3]  U. Werner,et al.  Nutrient release from an exposed intertidal sand flat , 2006 .

[4]  M. Charette,et al.  Precision Ground Water Sampling in Coastal Aquifers Using a Direct‐Push, Shielded‐Screen Well‐Point System , 2006 .

[5]  L. Gardner,et al.  Tidally driven groundwater flow and solute exchange in a marsh: Numerical simulations , 2006 .

[6]  D. Miller,et al.  A simple, inexpensive and large volume pore water sampler for sandy and muddy substrates , 2006 .

[7]  Michael Schlüter,et al.  Rhizon sampling of porewaters near the sediment‐water interface of aquatic systems , 2005 .

[8]  J. J. Morgan Kinetics of reaction between O2 and Mn(II) species in aqueous solutions , 2005 .

[9]  Debra S. Stakes,et al.  Continuous chemical monitoring with osmotically pumped water samplers: OsmoSampler design and applications , 2004 .

[10]  G. Helz,et al.  Capture of molybdenum in pyrite-forming sediments: role of ligand-induced reduction by polysulfides , 2004 .

[11]  P. Berg,et al.  A high‐resolution pore water sampler for sandy sediments , 2001 .

[12]  C. A. Abella A high-resolution pore water sampler for sandy sediments , 2001 .

[13]  R. Anderson,et al.  Authigenic molybdenum formation in marine sediments: A link to pore water sulfide in the Santa Barbara Basin , 2000 .

[14]  Markus Huettel,et al.  Advective particle transport into permeable sediments—evidence from experiments in an intertidal sandflat , 2000 .

[15]  M. Huettel,et al.  Transport and degradation of phytoplankton in permeable sediment , 2000 .

[16]  B. Erickson,et al.  Molybdenum(VI) speciation in sulfidic waters:. Stability and lability of thiomolybdates , 2000 .

[17]  G. Luther,et al.  Advective Transport Affecting Metal and Nutrient Distributions and Interfacial Fluxes in Permeable Sediments , 1998 .

[18]  I. Rodushkin,et al.  Determination of trace metals in estuarine and sea-water reference materials by high resolution inductively coupled plasma mass spectrometry , 1997 .

[19]  R. Pattrick,et al.  Mechanism of molybdenum removal from the sea and its concentration in black shales: EXAFS evidence , 1996 .

[20]  P. Ugo,et al.  A new device for in-situ pore-water sampling , 1995 .

[21]  H. Allen,et al.  Sediment pore water collection methods for trace metal analysis : a review , 1995 .

[22]  B. Thamdrup,et al.  Manganese oxidation and in situ manganese fluxes from a coastal sediment , 1994 .

[23]  D. Burdige The biogeochemistry of manganese and iron reduction in marine sediments , 1993 .

[24]  A. Hursthouse,et al.  Communication. Sampling interstitial waters from intertidal sediments: an inexpensive device to overcome an expensive problem? , 1993 .

[25]  P. Watson,et al.  A multilevel in situ pore-water sampler for use in intertidal sediments and laboratory microcosms , 1990 .

[26]  P. Saager,et al.  A simple pore-water sampler for coarse, sandy sediments of low porosity , 1990 .

[27]  B. Wehrli,et al.  Vanadyl in natural waters: Adsorption and hydrolysis promote oxygenation , 1989 .

[28]  R. Jahnke,et al.  A simple, reliable, and inexpensive pore‐water sampler1 , 1988 .

[29]  C. Lambert,et al.  A whole‐core squeezer for interfacial pore‐water sampling1 , 1987 .

[30]  B. L. Howes,et al.  Effects of sampling technique on measurements of porewater constituents in salt marsh sediments1 , 1985 .

[31]  H. Brumsack,et al.  Interstitial water trace-metal chemistry of laminated sediments from the Gulf of California, Mexico , 1983 .

[32]  N. Silverberg,et al.  Pathways of manganese in an open estuarine system , 1981 .

[33]  M. Price,et al.  A close-interval sampler for collection of sediment pore waters for nutrient analyses , 1981 .

[34]  R. Hesslein An in situ sampler for close interval pore water studies1 , 1976 .

[35]  J. Robbins,et al.  A squeezer for efficient extraction of pore water from small volumes of anoxic sediment1 , 1976 .

[36]  S. Norton,et al.  A large‐volume interstitial water sediment squeezer for lake sediments1 , 1974 .

[37]  J. Vosjan Sulphate in water and sediment of the Dutch Wadden Sea , 1974 .

[38]  F. Sayles,et al.  In situ Sampler for Marine Sedimentary Pore Waters: Evidence for Potassium Depletion and Calcium Enrichment , 1973, Science.

[39]  J. Makemson An Interstitial Water Sampler for Sandy Beaches , 1972 .

[40]  J. Bischoff,et al.  Composition of Interstitial Waters of Marine Sediments: Temperature of Squeezing Effect , 1970, Science.

[41]  W. Reeburgh AN IMPROVED INTERSTITIAL WATER SAMPLER1 , 1967 .