Study on the Sensing Coating of the Optical Fibre CO2 Sensor

Optical fibre carbon dioxide (CO2) sensors are reported in this article. The principle of operation of the sensors relies on the absorption of light transmitted through the fibre by a silica gel coating containing active dyes, including methyl red, thymol blue and phenol red. Stability of the sensor has been investigated for the first time for an absorption based CO2 optical fiber sensor. Influence of the silica gel coating thickness on the sensitivity and response time has also been studied. The impact of temperature and humidity on the sensor performance has been examined too. Response times of reported sensors are very short and reach 2–3 s, whereas the sensitivity of the sensor ranges from 3 to 10 for different coating thicknesses. Reported parameters make the sensor suitable for indoor and industrial use.

[1]  Vlastimil Matejec,et al.  Optical fibre sensor coated with porous silica layers for gas and chemical vapour detection , 1997 .

[2]  A. Berg,et al.  Ammonia sensors and their applications - a review , 2005 .

[3]  M. Hernaez,et al.  Nanostructured Materials in Optical Fiber Sensing , 2013 .

[4]  Jaime Herrán,et al.  Performance of a CO2 Impedimetric Sensor Prototype for Air Quality Monitoring , 2011, Sensors.

[5]  Kaiming Zhou,et al.  Toward a New Generation of Photonic Humidity Sensors , 2014, Sensors.

[6]  Otto S. Wolfbeis,et al.  Towards a gastric pH-sensor: an optrode for the pH 0–7 range , 1989 .

[7]  Zhongjun Zhao,et al.  A low cost fiber-optic humidity sensor based on silica sol–gel film , 2011 .

[8]  George Stewart,et al.  Prospects for fibre-optic evanescent-field gas sensors using absorption in the near-infrared , 1997 .

[9]  B. Renganathan,et al.  Nanocrystalline ZnO coated fiber optic sensor for ammonia gas detection , 2011 .

[10]  Francesco Pilati,et al.  Plastic Optical Fiber pH Sensor Using a Sol-Gel Sensing Matrix , 2012 .

[11]  J. Bechara,et al.  Fabrication and characterization of an evanescent wave fiber optic sensor for air pollution control , 2000 .

[12]  B D Gupta,et al.  Detection of gases with porous-clad tapered fibers. , 1995, Applied optics.

[13]  V. V. Speybroeck,et al.  Substituent effects on absorption spectra of pH indicators: An experimental and computational study of sulfonphthaleine dyes , 2014 .

[14]  Brian D. MacCraith,et al.  Dye-doped organically modified silica glass for fluorescence based carbon dioxide gas detection , 1998 .

[15]  Yu-Lung Lo,et al.  Highly sensitive optical fiber oxygen sensor using Pt(II) complex embedded in sol-gel matrices , 2006 .

[16]  Michael Tiemann,et al.  Porous metal oxides as gas sensors. , 2007, Chemistry.

[17]  J R Lakowicz,et al.  A lifetime-based optical CO2 gas sensor with blue or red excitation and stokes or anti-stokes detection. , 1995, Analytical biochemistry.

[18]  A. L. Harmer,et al.  Environmental Monitoring , 2018, Nano-Tera.ch.

[19]  Rajinder Singh Kaler,et al.  Long Period Fiber Grating Humidity Sensor With Gelatin/Cobalt Chloride Coating , 2012, IEEE Sensors Journal.

[20]  F. Arregui,et al.  An experimental study about hydrogels for the fabrication of optical fiber humidity sensors , 2003 .

[21]  Stanley M. Klainer,et al.  Fiber-optic fluorescence carbon dioxide sensor for environmental monitoring , 1998 .

[22]  Russell Binions,et al.  Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring , 2010, Sensors.

[23]  Marcos A. R. Franco,et al.  Microstructured-core optical fibre for evanescent sensing applications. , 2006, Optics express.

[24]  Zbigniew Opilski,et al.  Optical interferometric structures for application in gas sensors , 2007 .

[25]  Qida Zhao,et al.  Relative Humidity Sensor Based on Tilted Fiber Bragg Grating With Polyvinyl Alcohol Coating , 2009, IEEE Photonics Technology Letters.

[26]  R. Binions,et al.  13 – Metal oxide semiconductor gas sensors in environmental monitoring , 2013 .

[27]  Halina Podbielska,et al.  Viscosity, surface tension and refractive index of tetraethylorthosilicate-based sol-gel materials depending on ethanol content , 2005 .

[28]  Brian Culshaw,et al.  Distributed pH and water detection using fiber-optic sensors and hydrogels , 1995 .

[29]  Ludger Wöste,et al.  PCF-Based Cavity Enhanced Spectroscopic Sensors for Simultaneous Multicomponent Trace Gas Analysis , 2011, Sensors.

[30]  O. Wolfbeis Fiber-optic chemical sensors and biosensors. , 2004, Analytical chemistry.

[31]  H. El-Nasser,et al.  Effects of methyl red acidity and UV illumination on absorption coefficient of MR/PVA thin films , 2011 .

[32]  Mehdi Shadaram,et al.  Modeling and performance evaluation of ferrocene-based polymer clad tapered optical fiber gas sensors , 1998 .

[33]  F. Arregui,et al.  Sensitivity optimization of tapered optical fiber humidity sensors by means of tuning the thickness of nanostructured sensitive coatings , 2007 .

[34]  Kazimierz Jędrzejewski Biconical fused taper : a universal fibre devices technology , 2000 .

[35]  Gang Zhang,et al.  An optical fiber sensor based on absorption spectroscopy for carbon monoxide detection , 2010, 2010 International Conference On Computer Design and Applications.

[36]  C F Kaminski,et al.  Cavity enhanced absorption spectroscopy of multiple trace gas species using a supercontinuum radiation source. , 2008, Optics express.

[37]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[38]  Issa M El Nahhal,et al.  Thin film optical BTB pH sensors using sol–gel method in presence of surfactants , 2012, International Nano Letters.

[39]  Akira Tani,et al.  Comparison of the Characteristics of Small Commercial NDIR CO2 Sensor Models and Development of a Portable CO2 Measurement Device , 2012, Sensors.

[40]  Mohd. Hanif Yaacob,et al.  Dynamic Response of Tapered Optical Multimode Fiber Coated with Carbon Nanotubes for Ethanol Sensing Application , 2015, Sensors.

[41]  Colette McDonagh,et al.  Optical chemical sensors. , 2008, Chemical reviews.

[42]  W. Rudolf Seitz,et al.  Poly(vinyl alcohol) as a substrate for indicator immobilization for fiber-optic chemical sensors , 1989 .

[43]  Abliz Yimit,et al.  Detection of ammonia in the ppt range based on a composite optical waveguide pH sensor , 2003 .

[44]  Yasuhiko Arai,et al.  Sensitivity of fiber-optic carbon dioxide sensors utilizing indicator dye , 2003 .

[45]  A. Rojas-Hernández,et al.  Determination of pK(a)'s for thymol blue in aqueous medium: evidence of dimer formation. , 1998, Talanta.

[46]  S. Pispas,et al.  Optical fiber long-period grating humidity sensor with poly(ethylene oxide)/cobalt chloride coating. , 2006, Applied optics.

[47]  Y. Amao,et al.  Optical CO2 sensor with the combination of colorimetric change of α-naphtholphthalein and internal reference fluorescent porphyrin dye , 2004 .

[48]  Zengcai Wang,et al.  Fibre optic sensors for mine hazard detection , 2009 .

[49]  R. Claus,et al.  Optical fiber humidity sensor using a nano Fabry–Perot cavity formed by the ionic self-assembly method , 1999 .

[50]  Otto S. Wolfbeis,et al.  Fiber-optic fluorosensor for oxygen and carbon dioxide , 1988 .

[51]  Elfed Lewis,et al.  A mid-infrared optical fibre sensor for the detection of carbon monoxide exhaust emissions , 2008 .

[52]  Yu-Lung Lo,et al.  Review on recent developments of fluorescent oxygen and carbon dioxide optical fiber sensors , 2011 .