Stringent upper limit of CH4 on Mars based on SOFIA/EXES observations

Discovery of CH4 in the Martian atmosphere has led to much discussion since it could be a signature of biological and/or geological activities on Mars. However, the presence of CH4 and its temporal and spatial variations are still under discussion because of the large uncertainties embedded in the previous observations. We performed sensitive measurements of Martian CH4 by using the Echelon-Cross-Echelle Spectrograph (EXES) onboard the Stratospheric Observatory for Infrared Astronomy (SOFIA) on 16 March 2016, which corresponds to summer (Ls = 123.2∘) in the northern hemisphere on Mars. The high altitude of SOFIA (~13.7 km) enables us to significantly reduce the effects of terrestrial atmosphere. Thanks to this, SOFIA/EXES improves our chances of detecting Martian CH4 lines because it reduces the impact of telluric CH4 on Martian CH4, and allows us to use CH4 lines in the 7.5 μm band which has less contamination. However, our results show no unambiguous detection of Martian CH4. The Martian disk was spatially resolved into 3 × 3 areas, and the upper limits on the CH4 volume mixing ratio range from 1 to 9 ppb across the Martian atmosphere, which is significantly less than detections in several other studies. These results emphasize that release of CH4 on Mars is sporadic and/or localized if the process is present.

[1]  D. Chris Benner,et al.  Methane Line Parameters in HITRAN , 2003 .

[2]  P. Mahaffy,et al.  Low Upper Limit to Methane Abundance on Mars , 2013, Science.

[3]  V. Krasnopolsky,et al.  Search for methane and upper limits to ethane and SO2 on Mars , 2012 .

[4]  T. Roush,et al.  Revisiting the identification of methane on Mars using TES data , 2015 .

[5]  F. Muller‐Karger,et al.  Phytoplankton Response to Intrusions of Slope Water on the West Florida Shelf: Models and Observations , 2003 .

[6]  Wim Ruyten,et al.  Comment on ''A new implementation of the Humlicek algorithm for the calculation of the Voigt profile function'' by M. Kuntz [JQSRT 57(6) (1997) 819-824] [rapid communication] , 2004 .

[7]  M. Kuntz,et al.  A new implementation of the Humlicek algorithm for the calculation of the Voigt profile function , 1997 .

[8]  Paul R. Mahaffy,et al.  Methane and related trace species on Mars: Origin, loss, implications for life, and habitability , 2007 .

[9]  V. Formisano,et al.  Methane in Martian atmosphere: Average spatial, diurnal, and seasonal behaviour , 2008 .

[10]  W. Wiscombe Improved Mie scattering algorithms. , 1980, Applied optics.

[11]  V. Formisano,et al.  Mapping methane in Martian atmosphere with PFS-MEX data , 2011 .

[12]  S. Warren,et al.  Optical constants of ice from the ultraviolet to the microwave. , 1984, Applied optics.

[13]  D. Jaffe,et al.  TEXES: A Sensitive High-Resolution Grating Spectrograph for the Mid-Infrared , 2001, astro-ph/0110521.

[14]  Tobias Owen,et al.  Detection of methane in the martian atmosphere: evidence for life? , 2004 .

[15]  R. Todd Clancy,et al.  Constraints on the size of Martian aerosols from Thermal Emission Spectrometer observations , 2003 .

[16]  Nikolay Ignatiev,et al.  Planetary Fourier spectrometer data analysis: Fast radiative transfer models , 2005 .

[17]  P. Mahaffy,et al.  Cometary origin of atmospheric methane variations on Mars unlikely , 2016 .

[18]  S. Fonti,et al.  Mapping the methane on Mars , 2010 .

[19]  Franck Lefèvre,et al.  Observed variations of methane on Mars unexplained by known atmospheric chemistry and physics , 2009, Nature.

[20]  Franck Lefèvre,et al.  Infrared imaging spectroscopy of Mars : H2O mapping and determination of CO2 isotopic ratios , 2005 .

[21]  Andrew Steele,et al.  Mars methane detection and variability at Gale crater , 2015, Science.

[22]  A. Treiman,et al.  A cometary origin for martian atmospheric methane , 2016 .

[23]  T. Encrenaz,et al.  A sensitive search for organics (CH4, CH3OH, H2CO, C2H6, C2H2, C2H4), hydroperoxyl (HO2), nitrogen compounds (N2O, NH3, HCN) and chlorine species (HCl, CH3Cl) on Mars using ground-based high-resolution infrared spectroscopy , 2013 .

[24]  Erin C. Smith,et al.  EARLY SCIENCE WITH SOFIA, THE STRATOSPHERIC OBSERVATORY FOR INFRARED ASTRONOMY , 2012, 1205.0791.

[25]  Marco Giuranna,et al.  Detection of Methane in the Atmosphere of Mars , 2004, Science.

[26]  Michael D. Smith,et al.  Strong Release of Methane on Mars in Northern Summer 2003 , 2009, Science.

[27]  Gang Li,et al.  The HITRAN 2008 molecular spectroscopic database , 2005 .

[28]  Y. Kasaba,et al.  Seasonal variation of the HDO/H2O ratio in the atmosphere of Mars at the middle of northern spring and beginning of northern summer , 2015 .

[29]  J. Schofield,et al.  Mars Climate Sounder limb profile retrieval of atmospheric temperature, pressure, and dust and water ice opacity , 2009 .