Complexes of main-group elements containing stereochemically active lone pairs: the crystal structures of [Tl(TpAn)] {TpAn=tris[3-(2-methoxyphenyl)pyrazol-1-yl]hydroborate} and [Pb(TpPy)(NO3)]·0.5Et2O {TpPy = tris[3,-(2-pyrdyl)pyrazol-1-yl]hydroborate}