Photoreactive 3D microporous lanthanide MOFs: formation of a strained ladderane in a partial single crystal-to-single crystal manner.

The assembly of Er(3+) and Y(3+) cations with trans,trans-muconic acid affords a photoreactive 3D microporous MOF that, upon UV irradiation, undergoes a cycloaddition reaction (SCSC up to 55%), with in situ formation of a strained ladderane.

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