The mechanical and physical properties of nylon 6/glass fiber-reinforced hybrid composites manufactured by thermal and ultraviolet-cured pultrusion methods

In this study, the effect of hybridizing glass fiber-reinforced polymer composites with nylon 6 fibers on the physical and mechanical properties of composites was investigated experimentally. The ultraviolet-cured and thermal pultrusion methods were employed for manufacturing the glass fiber-reinforced polymer and hybrid composite rods containing different volume percentages of nylon 6 fibers at low and high temperatures. The effects of the nylon 6 fibers and the pultrusion methods were investigated on the curing degree, the void content, the diameter expansion, the surface characteristics, and the quasi-static tensile and Charpy impact properties of the composite rods. The ultraviolet-cured hybrid composites showed superior mechanical properties than the thermally cured samples indicating the sensitivity of nylon 6 fibers to high-temperature curing. Moreover, the curing speed of ultraviolet-cured pultrusion was significantly higher than the thermal pultrusion. Delamination and fiber pull-out were the dominant damage mechanisms in the hybrid composites due to the low interfacial strength between the nylon 6 fibers and matrix.

[1]  M. Jia,et al.  Thermoplastic Reaction Injection Pultrusion for Continuous Glass Fiber-Reinforced Polyamide-6 Composites , 2019, Materials.

[2]  A. Liverani,et al.  Mechanical and impact characterization of hybrid composite laminates with carbon, basalt and flax fibres , 2017 .

[3]  Liu Yang,et al.  Vibratory behaviour of glass fibre reinforced polymer (GFRP) interleaved with nylon nanofibers , 2017 .

[4]  M. Joshi,et al.  Glass/epoxy structural composites with interleaved nylon 6/6 nanofibers , 2017 .

[5]  Xiao-jie Li,et al.  Mechanical, thermal and interfacial performances of carbon fiber reinforced composites flavored by carbon nanotube in matrix/interface , 2017 .

[6]  R. Palazzetti Flexural behavior of carbon and glass fiber composite laminates reinforced with Nylon 6,6 electrospun nanofibers , 2015 .

[7]  I. Ulacia,et al.  Out of die ultraviolet cured pultrusion for automotive crash structures , 2015 .

[8]  R. Velmurugan,et al.  Influence of void microstructure on the effective elastic properties of discontinuous fiber-reinforced composites , 2015 .

[9]  K. Fancey,et al.  Performance enhancement of nylon/kevlar fiber composites through viscoelastically generated pre-stress , 2014 .

[10]  A. Pegoretti,et al.  Flexural and impact behaviour of carbon/basalt fibers hybrid laminates , 2014 .

[11]  G. Ben,et al.  Mechanical properties of kenaf composites coated with several nanofibers , 2013 .

[12]  Abdulkarim S. Ahmed,et al.  Effect of fiber type and combinations on the mechanical, physical and thermal stability properties of polyester hybrid composites , 2013 .

[13]  D. R. Palikhel,et al.  Die-Attached Versus Die-Detached Resin Injection Chamber for Pultrusion , 2013, Applied Composite Materials.

[14]  Constantinos Soutis,et al.  Modelling damage evolution in composite laminates subjected to low velocity impact , 2012 .

[15]  Hamidreza Abdolvand,et al.  Three-dimensional modeling and experimental validation of heat transfer in polymer matrix composites exposed to fire , 2011 .

[16]  K. Shivakumar,et al.  Effect of Nylon-66 nano-fiber interleaving on impact damage resistance of epoxy/carbon fiber composite laminates , 2009 .

[17]  Tarun Kant,et al.  Application of polymer composites in civil construction : A general review , 2008 .

[18]  Mingshu Yang,et al.  The thermal conductivity of Nylon 6/clay nanocomposites , 2008 .

[19]  Xu Guo,et al.  Tensile, impact and dielectric properties of three dimensional orthogonal aramid/glass fiber hybrid composites , 2007 .

[20]  Larry Lessard,et al.  Cure shrinkage characterization and modeling of a polyester resin containing low profile additives , 2007 .

[21]  Nick Tucker,et al.  Bent pultrusion—a method for the manufacture of pultrudate with controlled variation in curvature , 2003 .

[22]  Sabu Thomas,et al.  Thermal conductivity and thermal diffusivity analyses of low-density polyethylene composites reinforced with sisal, glass and intimately mixed sisal/glass fibres , 2000 .

[23]  D. Lee,et al.  Measurement of the Degree of Cure of Carbon Fiber Epoxy Composite Materials , 1996 .

[24]  Wenfang Shi,et al.  UV curing of composites based on modified unsaturated polyester , 1994 .

[25]  P. H. Thornton The Crush Behavior of Pultruded Tubes at High Strain Rates , 1990 .

[26]  M. Williams,et al.  Fracture behavior in nylon 6 fibers , 1972 .