Permeability-porosity relationships in seafloor vent deposits: Dependence on pore evolution processes

[1] Systematic laboratory measurements of permeability and porosity were conducted on three large vent structures from the Mothra Hydrothermal vent field on the Endeavor segment of the Juan de Fuca Ridge. Geometric means of permeability values obtained from a probe permeameter are 5.9 × 10−15 m2 for Phang, a tall sulfide-dominated spire that was not actively venting when sampled; 1.4 × 10−14 m2 for Roane, a lower-temperature spire with dense macrofaunal communities growing on its sides that was venting diffuse fluid of <300°C; and 1.6 × 10−14 m2 for Finn, an active black smoker with a well-defined inner conduit that was venting 302°C fluids prior to recovery. Twenty-three cylindrical cores were then taken from these vent structures. Permeability and porosity of the drill cores were determined on the basis of Darcy's law and Boyle's law, respectively. Permeability values range from ∼10−15 to 10−13 m2 for core samples from Phang, from ∼10−15 to 10−12 m2 for cores from Roane, and from ∼10−15 to 3 × 10−13 m2 for cores from Finn, in good agreement with the probe permeability measurements. Permeability and porosity relationships are best described by two different power law relationships with exponents of ∼9 (group I) and ∼3 (group II). Microstructural analyses reveal that the difference in the two permeability-porosity relationships reflects different mineral precipitation processes as pore space evolves within different parts of the vent structures, either with angular sulfide grains depositing as aggregates that block fluid paths very efficiently (group I), or by late stage amorphous silica that coats existing grains and reduces fluid paths more gradually (group II). The results suggest that quantification of permeability and porosity relationships leads to a better understanding of pore evolution processes. Correctly identifying permeability and porosity relationships is an important first step toward accurately estimating fluid distribution, flow rate, and environmental conditions within seafloor vent deposits, which has important consequences for chimney growth and biological communities that reside within and on vent structures.

[1]  D. Prior,et al.  Quartz Cement in the Fontainebleau Sandstone, Paris Basin, France: Crystallography and Implications for Mechanisms of Cement Growth , 2006 .

[2]  Brian Evans,et al.  Permeability-porosity Relationships in Rocks Subjected to Various Evolution Processes , 2003 .

[3]  T. J. Wolery,et al.  EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3 , 1992 .

[4]  E. Shock,et al.  Geochemical Energy Sources that Support the Subsurface Biosphere , 2013 .

[5]  D. Sverjensky,et al.  Thermodynamic assessment of hydrothermal alkali feldspar-mica-aluminosilicate equilibria , 1991 .

[6]  B. Evans,et al.  Densification and permeability reduction in hot‐pressed calcite: A kinetic model , 1999 .

[7]  M. Hannington,et al.  Mineralogy and geochemistry of a hydrothermal silica-sulfide-sulfate spire in the caldera of Axial Seamount, Juan De Fuca Ridge , 1988 .

[8]  M. Hannington,et al.  Deducing patterns of fluid flow and mixing within the TAG active hydrothermal mound using mineralogical and geochemical data , 1995 .

[9]  I. Jonasson,et al.  Two zinc-rich chimneys from the plume site, southern Juan de Fuca Ridge , 1988 .

[10]  R. Koski Sulfide Deposits on the Sea Floor: Geological Models and Resource Perspectives Based on Studies in Ophiolite Sequences , 1987 .

[11]  E. Oelkers,et al.  SUPCRT92: a software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000 ° C , 1992 .

[12]  B. Zinszner,et al.  Hydraulic and acoustic properties as a function of porosity in Fontainebleau Sandstone , 1985 .

[13]  D. Kadko,et al.  Compositions, growth mechanisms, and temporal relations of hydrothermal sulfide-sulfate-silica chimneys at the northern Cleft segment, Juan de Fuca Ridge , 1994 .

[14]  M. Lilley,et al.  Anomalous CH4 and NH4+ concentrations at an unsedimented mid-ocean-ridge hydrothermal system , 1993, Nature.

[15]  J. B. Walsh The effect of cracks on the compressibility of rock , 1965 .

[16]  T. J. Wolery,et al.  EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) , 1992 .

[17]  S. Petersen,et al.  A model for growth of steep-sided vent structures on the Endeavour Segment of the Juan de Fuca Ridge: Results of a petrologic and geochemical study (Paper 1999JB900107) , 1999 .

[18]  W. Seyfried,et al.  Formation of massive sulfide deposits on oceanic ridge crests: Incremental reaction models for mixing between hydrothermal solutions and seawater , 1984 .

[19]  Timothy M. Shank,et al.  Chemical speciation drives hydrothermal vent ecology , 2001, Nature.

[20]  E. Shock,et al.  Geochemical constraints on chemolithoautotrophic metabolism by microorganisms in seafloor hydrothermal systems. , 1997, Geochimica et cosmochimica acta.

[21]  W. Seyfried,et al.  Determination of Fe-Cl complexing in the low pressure supercritical region (NaCl fluid): Iron solubility constraints on pH of subseafloor hydrothermal fluids , 1992 .

[22]  T. Wong,et al.  Network modeling of permeability evolution during cementation and hot isostatic pressing , 1995 .

[23]  J. B. Walsh,et al.  The effect of pressure on porosity and the transport properties of rock , 1984 .

[24]  R. Haymon Growth history of hydrothermal black smoker chimneys , 1983, Nature.

[25]  Paul F. Worthington,et al.  Recommended practice for probe permeametry , 1993 .

[26]  E. Bruce Watson,et al.  Grain-scale permeabilities of texturally equilibrated, monomineralic rocks , 1998 .

[27]  V. Tunnicliffe,et al.  Influence of a tube-building polychaete on hydrothermal chimney mineralization , 1992 .

[28]  J. Edmond,et al.  The Genesis of Hot Spring Deposits on the East Pacific Rise, 21°N , 1983 .

[29]  J. Sarrazin,et al.  Mosaic community dynamics on Juan de Fuca Ridge sulphide edifices : substratum, temperature and implications for trophic structure , 2002 .

[30]  John R. Delaney,et al.  Geology of a vigorous hydrothermal system on the Endeavour segment, Juan de Fuca Ridge , 1992 .

[31]  M. S. Paterson,et al.  The equivalent channel model for permeability and resistivity in fluid-saturated rock—A re-appraisal , 1983 .

[32]  T. Wong,et al.  Laboratory measurement of compaction-induced permeability change in porous rocks: Implications for the generation and maintenance of pore pressure excess in the crust , 1994 .

[33]  R. Haymon,et al.  Fossils of Hydrothermal Vent Worms from Cretaceous Sulfide Ores of the Samail Ophiolite, Oman , 1984, Science.

[34]  D. Janecky,et al.  Computational modeling of chemical and sulfur isotopic reaction processes in sea-floor hydrothermal systems; chimneys, massive sulfide, and subjacent alteration zones , 1988 .

[35]  Palmer,et al.  Time series studies of vent fluids from the TAG and MARK sites (1986, 1990) Mid-Atlantic Ridge and a mechanism for Cn/Zn zonation in massive sulphide core bodies , 1995 .

[36]  J. Delaney,et al.  The heat and fluid transfer associated with the flanges on hydrothermal venting structures , 1992 .

[37]  D. Clague,et al.  Mineralogy and chemistry of massive sulfide deposits from the Juan de Fuca Ridge , 1984 .

[38]  D. Yoerger,et al.  Geology and venting characteristics of the Mothra hydrothermal field, Endeavour segment, Juan de Fuca Ridge , 2001 .

[39]  M. Zbinden,et al.  Processes controlling the physico-chemical micro-environments associated with Pompeii worms , 2005 .

[40]  D. Hannington,et al.  MINERALOGY AND GEOCHEMISTRY OF A HYDROTHERMAL SILICA-SULFIDE _ SULFATE SPIRE IN THE CALDERA OF AXIAL SEAMOUNT , 2006 .

[41]  G. Massoth,et al.  Gradients in the composition of hydrothermal fluids from the Endeavour segment vent field: Phase separation and brine loss , 1994 .

[42]  P. Gente,et al.  Tectonic setting and mineralogical and geochemical zonation in the Snake Pit sulfide deposit (Mid-Atlantic Ridge at 23 degrees N) , 1993 .

[43]  J. Delaney,et al.  Large massive sulfide deposits in a newly discovered active hydrothermal system, The High-Rise Field, Endeavour Segment, Juan De Fuca Ridge , 1993 .

[44]  R. Haymon,et al.  Hot spring deposits on the East Pacific Rise at 21°N: preliminary description of mineralogy and genesis , 1981 .

[45]  M. Tivey,et al.  Mineral precipitation in the walls of black smoker chimneys: A quantitative model of transport and chemical reaction , 1990 .

[46]  G. Constantinou,et al.  Black smoker chimney fragments in Cyprus sulphide deposits , 1984, Nature.

[47]  K. V. Damm,et al.  Chemical evolution of mid-ocean ridge hot springs☆ , 1985 .

[48]  J. Delaney,et al.  Growth of large sulfide structures on the endeavour segment of the Juan de Fuca ridge , 1986 .

[49]  M. Tivey The influence of hydrothermal fluid composition and advection rates on black smoker chimney mineralogy: Insights from modeling transport and reaction , 1995 .

[50]  Dana R. Yoerger,et al.  “Edifice Rex” Sulfide Recovery Project: Analysis of submarine hydrothermal, microbial habitat , 2001 .

[51]  M. Hannington,et al.  Growth history of a diffusely venting sulfide structure from the Juan de Fuca Ridge: A petrological and geochemical study , 2006 .

[52]  T. Shank,et al.  Worms bask in extreme temperatures , 1998, Nature.

[53]  Reis Jc,et al.  PERMEABILITY REDUCTION MODELS FOR THE PRECIPITATION OF INORGANIC SOLIDS IN BEREA SANDSTONE , 1994 .

[54]  T. J. Wolery,et al.  EQ6, a computer program for reaction path modeling of aqueous geochemical systems: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 4 , 1992 .