Evidence of double layer/capacitive charging in carbon nanomaterial-based solid contact polymeric ion-selective electrodes.

This paper presents the first direct spectroscopic evidence for double layer or capacitive charging of carbon nanomaterial-based solid contacts in all-solid-state polymeric ion-selective electrodes (ISEs). Here, we used synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and SR valence band (VB) spectroscopy in the elucidation of the charging mechanism of the SCs.

[1]  R. Cattrall,et al.  Potassium ion responsive coated wire electrode based on valinomycin. , 1974, Analytical chemistry.

[2]  P. López-Cornejo,et al.  Study of ionic surfactants interactions with carboxylated single-walled carbon nanotubes by using ion-selective electrodes , 2016 .

[3]  R. Hausbrand,et al.  Investigation of sodium insertion into tetracyanoquinodimethane (TCNQ): results for a TCNQ thin film obtained by a surface science approach. , 2016, Physical chemistry chemical physics : PCCP.

[4]  Róbert E. Gyurcsányi,et al.  Quality control criteria for solid-contact, solvent polymeric membrane ion-selective electrodes , 2009 .

[5]  P. Bühlmann,et al.  Solid contact ion-selective electrodes with a well-controlled Co(II)/Co(III) redox buffer layer. , 2013, Analytical chemistry.

[6]  Liyi Shi,et al.  Grafting sulfonic and amine functional groups on 3D graphene for improved capacitive deionization , 2016 .

[7]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[8]  F. Rius,et al.  Transduction mechanism of carbon nanotubes in solid-contact ion-selective electrodes. , 2009, Analytical chemistry.

[9]  F. Rius,et al.  Ion-selective electrodes using carbon nanotubes as ion-to-electron transducers. , 2008, Analytical chemistry.

[10]  Y. Kobayashi,et al.  Valence bands of poly(methylmethacrylate) and photoion emission in vacuum ultraviolet region , 1992 .

[11]  Eric Bakker,et al.  Thin Layer Ionophore-Based Membrane for Multianalyte Ion Activity Detection. , 2015, Analytical chemistry.

[12]  Andreas Stein,et al.  Ion-selective electrodes with colloid-imprinted mesoporous carbon as solid contact. , 2014, Analytical chemistry.

[13]  A. Bond,et al.  Applications of voltammetric ion selective electrodes to complex matrices , 2013 .

[14]  J. Heinze,et al.  Electrochemistry of conducting polymers--persistent models and new concepts. , 2010, Chemical reviews.

[15]  Tomàs Guinovart,et al.  Recognition and Sensing of Creatinine. , 2016, Angewandte Chemie.

[16]  F. Rius,et al.  Paper-based ion-selective potentiometric sensors. , 2012, Analytical chemistry.

[17]  Eric Bakker,et al.  Tandem electrochemical desalination-potentiometric nitrate sensing for seawater analysis. , 2015, Analytical chemistry.

[18]  Sam Emaminejad,et al.  Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis , 2016, Nature.

[19]  Yushin Kim,et al.  Stripping analysis of nanomolar perchlorate in drinking water with a voltammetric ion-selective electrode based on thin-layer liquid membrane. , 2008, Analytical chemistry.

[20]  Ernö Pretsch,et al.  Evidence for a surface confined ion-to-electron transduction reaction in solid-contact ion-selective electrodes based on poly(3-octylthiophene). , 2013, Analytical chemistry.

[21]  R. Marco,et al.  Understanding Complex Electrochemical Impedance Spectroscopy in Corrosion Systems Using in-situ Synchrotron Radiation Grazing Incidence X-ray Diffraction , 2016 .

[22]  J. Čechal,et al.  Deposition of stable amine coating onto polycaprolactone nanofibers by low pressure cyclopropylamine plasma polymerization , 2015 .

[23]  Joseph Wang,et al.  Portable electrochemical systems , 2002 .

[24]  J. Riu,et al.  Reduced Graphene Oxide Films as Solid Transducers in Potentiometric All-Solid-State Ion-Selective Electrodes , 2012 .

[25]  Jordi Riu,et al.  Disposable planar reference electrode based on carbon nanotubes and polyacrylate membrane. , 2011, Analytical chemistry.

[26]  G. Crespo,et al.  In Situ Ammonium Profiling Using Solid-Contact Ion-Selective Electrodes in Eutrophic Lakes. , 2015, Analytical chemistry.

[27]  D. Fairbrother,et al.  Quantification of Surface Oxides on Carbonaceous Materials , 2006 .

[28]  J. Bobacka,et al.  New Signal Readout Principle for Solid-Contact Ion-Selective Electrodes. , 2016, Analytical chemistry.

[29]  S. Vasudevan,et al.  Oxidized multiwalled carbon nanotubes as adsorbent for the removal of manganese from aqueous solution , 2013, Environmental Science and Pollution Research.

[30]  Eric Bakker,et al.  All-solid-state potentiometric sensors with a multiwalled carbon nanotube inner transducing layer for anion detection in environmental samples. , 2015, Analytical chemistry.

[31]  P. K. Sansanwal Effect of co-solutes on the physico-chemical properties of surfactant solutions , 2006 .

[32]  Eric Bakker,et al.  Electrochemical Ion Transfer with Thin Films of Poly(3-octylthiophene). , 2016, Analytical chemistry.

[33]  A. Stein,et al.  Ion-selective electrodes with three-dimensionally ordered macroporous carbon as the solid contact. , 2007, Analytical chemistry.

[34]  Wei Qin,et al.  All-solid-state polymeric membrane ion-selective miniaturized electrodes based on a nanoporous gold film as solid contact. , 2014, Analytical chemistry.

[35]  M. R. Kessler,et al.  Oxidation behavior of multiwalled carbon nanotubes fluidized with ozone. , 2014, ACS applied materials & interfaces.

[36]  Wolfgang Schuhmann,et al.  Intercalation Compounds as Inner Reference Electrodes for Reproducible and Robust Solid-Contact Ion-Selective Electrodes. , 2016, Angewandte Chemie.

[37]  D. S. Misra,et al.  Enhanced and stable field emission from in situ nitrogen-doped few-layered graphene nanoflakes , 2011 .

[38]  E. Jaworska,et al.  Gold nanoparticles solid contact for ion-selective electrodes of highly stable potential readings. , 2011, Talanta.

[39]  P. Si,et al.  Thin layer electrochemical extraction of non-redoxactive cations with an anion-exchanging conducting polymer overlaid with a selective membrane. , 2009, Chemical communications.

[40]  Dermot Diamond,et al.  All-solid-state sodium-selective electrode based on a calixarene ionophore in a poly(vinyl chloride) membrane with a polypyrrole solid contact , 1992 .

[41]  A. Ivaska,et al.  Potentiometric ion sensors. , 2008, Chemical reviews.

[42]  A. Ivaska Analytical applications of conducting polymers , 1991 .