A comparison of charcoal- and slag-based constructed wetlands for acid mine drainage remediation

Subsurface-flow constructed wetlands (CW) with charcoal- or slag-based bed matrices were investigated for their potential use in remediating acid mine drainage (AMD). A CW is effectively a reactor in which some components of the wastewater are broken down by the organisms occurring within the CW, whilst others may be degraded by physico-chemical processes or a combination thereof. Two 200 l small-scale CWs were built at the University. Commercially available charcoal and <19 mm basic oxygen furnace (BOF) slag were used as the bed matrices and the units were planted with a variety of plants. The units were exposed to an artificial AMD. The results showed that the systems removed almost all soluble iron and more than 75% of the sulphate. Both CWs were able to increase the pH of the AMD. Keywords: AMD, charcoal, slag, constructed wetlands, remediation

[1]  Sanja Potgieter-Vermaak,et al.  Comparison of limestone, dolomite and fly ash as pre-treatment agents for acid mine drainage , 2006 .

[2]  David W. Blowes,et al.  Selection of Reactive Mixtures for Use in Permeable Reactive Walls for Treatment of Mine Drainage , 1998 .

[3]  A. Peppas,et al.  Use of organic covers for acid mine drainage control , 2000 .

[4]  E. Cukrowska,et al.  The chemical characteristics of acid mine drainage with particular reference to sources, distribution and remediation: The Witwatersrand Basin, South Africa as a case study , 2008 .

[5]  L. Batty Wetland plants - more than just a pretty face? , 2003 .

[6]  Raimund Haberl,et al.  Constructed Wetlands for Pollution Control , 2001 .

[7]  R. Hedin,et al.  TREATMENT OF METAL-CONTAMINATED WATER USING BACTERIAL SULFATE REDUCTION: RESULTS FROM PILOT-SCALE REACTORS , 1991 .

[8]  Paul F. Ziemkiewicz,et al.  STEEL SLAG: APPLICATIONS FOR AMD CONTROL , 1998 .

[9]  Raimund Haberl,et al.  Constructed wetlands for pollution control: Processes, performance, design and operation , 2000 .

[10]  D. Blowes,et al.  Organic carbon amendments for passive in situ treatment of mine drainage: Field experiments , 2011 .

[11]  J. Megonigal,et al.  on the Roots of Wetland Plants Ferric Hydroxide Precipitates ( Fe-Plaque ) Iron-Oxidizing Bacteria Are Associated with , 1999 .

[12]  D. Blowes,et al.  Geochemistry of a Permeable Reactive Barrier for Metals and Acid Mine Drainage , 1999 .

[13]  D. Blowes,et al.  Microbial populations associated with the generation and treatment of acid mine drainage , 2000 .

[14]  Chris Aldrich,et al.  Removal of pollutants from acid mine wastewater using metallurgical by-product slags , 2004 .

[15]  J. H. Tuttle,et al.  Microbial Sulfate Reduction and Its Potential Utility as an Acid Mine Water Pollution Abatement Procedure , 1969, Applied microbiology.

[16]  Ata Akcil,et al.  Acid Mine Drainage (AMD): causes, treatment and case studies , 2006 .

[17]  Harry R. Diz Chemical and Biological Treatment of Acid Mine Drainage for the Removal of Heavy Metals and Acidity , 1997 .

[18]  T. Lien,et al.  Treatment of acid mine water by sulfate-reducing bacteria; results from a bench scale experiment , 1996 .

[19]  A. Sheoran,et al.  Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review , 2006 .

[20]  Ilya Raskin,et al.  Rhizofiltration: the use of plants to remove heavy metals from aqueous streams. , 1995, Environmental science & technology.

[21]  Paul L Younger,et al.  Growth of Phragmites australis (Cav.) Trin ex. Steudel in mine water treatment wetlands: effects of metal and nutrient uptake. , 2004, Environmental pollution.

[22]  S. Waara,et al.  Metal retention on pine bark and blast furnace slag--on-site experiment for treatment of low strength landfill leachate. , 2008, Bioresource technology.