LOW-TEMPERATURE ALTERATION AND SUBSEQUENT REHEATING OF SHALLOW OCEANIC CRUST AT HOLE 765 D , ARGO ABYSSAL

Volcanic basement recovered at Hole 765D is characterized by nonpervasive, oxidative alteration, typical of seafloor weathering. Chilled margins and the mesostasis of the lavas are variably altered to assemblages of celadonite, Fe-oxyhydroxides, zeolites, and calcite with trace saponite. Plagioclase is partially altered to Ca-Na zeolites and/or albite. Well-developed alteration halos parallel fracture surfaces and extend several centimeters into the surrounding rock. These clay-rich halos are enriched in K2O and Fe2θ3 relative to the adjacent clay-poor rock. The halos and adjacent rock are characterized by δ 1 8 θ values 2%0-3‰ higher than those of fresh MORB. The "freshness" of the samples and the scarcity of saponite suggest that the duration of seawater circulation was short-lived. Albitization of plagioclase indicates that the volcanic rocks were altered initially at low temperatures and were subsequently reheated off-axis in a closed environment. Reheating did not result in significant modification of the bulk composition of the crust.

[1]  Jeuns R. Bor COMPOSITION , OPTICAL PROPERTIES , CELL DIMENSIONS , AND THERMAL STABILITY OF SOME HEULANDITE GROUP ZEOLITES , 2007 .

[2]  H. Staudigel DATING OF OCEAN CRUST HYDROTHERMAL ALTERATION : STRONTIUM ISOTOPE RATIOS FROM HOLE 504 B CARBONATES AND A REINTERPRETATION OF Sr ISOTOPE DATA FROM DEEP SEA DRILLING PROJECT , 2006 .

[3]  C. Langmuir,et al.  Geochemistry of basalts from the southeast Indian Ridge, 115°E–138°E , 1991 .

[4]  H. G. Richards,et al.  14. LOW-TEMPERATURE ALTERATION OF VERY YOUNG BASALTS FROM ODP HOLE 648B: SEROCKI VOLCANO, MID-ATLANTIC RIDGE 1 , 1990 .

[5]  W. Sager,et al.  Late Jurassic-Early Cretaceous evolution of the eastern Indian Ocean adjacent to northwest Australia , 1989 .

[6]  J. Cann,et al.  Mineralogical zonation and metasomatism of the alteration pipes of Cyprus sulfide deposits , 1989 .

[7]  P. Robinson,et al.  Distribution of alteration zones in the upper oceanic crust , 1988 .

[8]  H. Sakai,et al.  Site 504: Costa Rica Rift , 1988 .

[9]  C. Langmuir,et al.  Global correlations of ocean ridge basalt chemistry with axial depth and crustal thickness , 1987 .

[10]  J. Alt,et al.  An oxygen isotopic profile through the upper kilometer of the oceanic crust, DSDP hole 504B , 1986 .

[11]  J. Alt,et al.  Hydrothermal alteration of a 1 km section through the upper oceanic crust, Deep Sea Drilling Project Hole 504B: Mineralogy, chemistry and evolution of seawater‐basalt interactions , 1986 .

[12]  S. Hart,et al.  Dating of Ocean Crust Hydrothermal Alteration: Strontium Isotope Ratios from Hole 504B Carbonates and Reinterpretation of Sr Isotope Data from Deep Sea Drilling Project Sites 105, 332, 417, and 418 , 1985 .

[13]  J. Alt,et al.  Alteration of the upper oceanic crust, DSDP site 417: mineralogy and chemistry , 1984 .

[14]  J. Böhlke,et al.  Oxygen isotope–water relations in altered deep-sea basalts: low-temperature mineralogical controls , 1984 .

[15]  D. Stakes,et al.  Mineralogy and stable isotope geochemistry of hydrothermally altered oceanic rocks , 1982 .

[16]  S. H. Richardson,et al.  Alteration of the oceanic crust: Processes and timing , 1981 .

[17]  A. Andrews Saponite and celadonite in layer 2 basalts, DSDP Leg 37 , 1980 .

[18]  J. Böhlke,et al.  Alteration of basalts from site 396 B, DSDP: Petrographic and mineralogic studies , 1980 .

[19]  Katherine J. Barrows Zeolitization of Miocene volcaniclastic rocks, southern Desatoya Mountains, Nevada , 1980 .

[20]  K. Muehlenbachs The Alteration and Aging of the Basaltic Layer of Sea Floor: Oxygen Isotope Evidence from DSDP/IPOD Legs 51, 52, and 53 , 1980 .

[21]  H. Puchelt,et al.  The Aging of Oceanic Crust: Synthesis of the Mineralogical and Chemical Results of Deep Sea Drilling Project Legs 51 through 53 , 1980 .

[22]  W. Seyfried,et al.  Clay mineral formation in DSDP Leg 34 basalt , 1978 .

[23]  J. Liou,et al.  Burial metamorphism of the Karmutsen volcanic rocks, northeastern Vancouver Island, British Columbia , 1976 .

[24]  M. N. Bass Secondary Minerals in Oceanic Basalts, with Special Reference to Leg 34, Deep Sea Drilling Project , 1976 .

[25]  H. Kristmannsdóttir Zeolite zones in geothermal areas in Iceland , 1976 .

[26]  R. L. Hay Zeolites and zeolitic reactions in sedimentary rocks , 1966 .

[27]  R. Clayton,et al.  The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis , 1963 .

[28]  S. Hendricks,et al.  Minerals of the montmorillonite group, their origin and relation to soils and clays , 1945 .