Triallyl monomer bearing adamantane‐like core derived from naturally occurring myo‐inositol: Synthesis and polyaddition with dithiols

This paper deals with a triallyl monomer bearing a rigid adamantane-like core derived from myo-inositol, a naturally occurring cyclic hexaol. The core structure of the monomer can be readily constructed by orthoesterification of myo-inositol. The polyaddition of the triallyl monomer with dithiols based on the thermally induced radical thiol-ene reaction gives the corresponding networked polymers. These networked polymers exhibit much higher thermal stability than the comparative networked polymers obtained from a triallyl monomer bearing less rigid cyclohexyl core. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1193–1199

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