Fabricating optical fiber imaging sensors using ink jet printing technology: a pH sensor proof-of-concept.

We demonstrate the feasibility of using Drop-on-Demand microjet printing technology for fabricating imaging sensors by reproducibly printing an array of photo-polymerizable sensing elements, containing a pH sensitive indicator, on the surface of an optical fiber image guide. The reproducibility of the microjet printing process is excellent for microdot (i.e. micrometer-sized polymer) sensor diameter (92.2+/-2.2 microm), height (35.0+/-1.0 microm), and roundness (0.00072+/-0.00023). pH sensors were evaluated in terms of pH sensing ability (< or =2% sensor variation), response time, and hysteresis using a custom fluorescence imaging system. In addition, the microjet technique has distinct advantages over other fabrication methods, which are discussed in detail.

[1]  S. Michael Angel,et al.  Fiber optic imaging for in-situ chemical measurements , 1999, Other Conferences.

[2]  Donald J. Hayes,et al.  Microjet printing of high-precision microlens array for packaging of fiber optic components , 2002, SPIE OPTO.

[3]  O. Wolfbeis Fiber-optic chemical sensors and biosensors. , 2000, Analytical chemistry.

[4]  Donald J. Hayes,et al.  Direct Write Using Ink-Jet Techniques , 2002 .

[5]  Delana A. Nivens,et al.  A fiber-optic pH sensor prepared using a base-catalyzed organo-silica sol–gel , 1998 .

[6]  S R Goldstein,et al.  Fiber optic pH probe for physiological use. , 1980, Analytical chemistry.

[7]  D R Walt,et al.  Fast temporal response fiber-optic chemical sensors based on the photodeposition of micrometer-scale polymer arrays. , 1997, Analytical chemistry.

[8]  M. V. Schiza,et al.  Use of a 2D to 1D Dimension Reduction Fiber-Optic Array for Multiwavelength Imaging Sensors , 2001 .

[9]  David R. Walt,et al.  Simultaneous monitoring of pH, CO2 and O2 using an optical imaging fiber , 1997 .

[10]  D R Walt,et al.  Photodeposition of micrometer-scale polymer patterns on optical imaging fibers , 1995, Science.

[11]  N. Opitz,et al.  Optical Fluorescence and Its Application to an Intravascular Blood Gas Monitoring System , 1986, IEEE Transactions on Biomedical Engineering.

[12]  Gary D. Christian,et al.  Single fibre optic fluorescence pH probe , 1987 .

[13]  W. Rudolf Seitz,et al.  pH sensor based on immobilized fluoresceinamine , 1982 .

[14]  D. Walt,et al.  A fibre-optic chemical sensor with discrete sensing sites , 1991, Nature.

[15]  Duncan L. MacFarlane,et al.  Fabrication of micro-optics by microjet printing , 1995, Photonics West.

[16]  David R. Walt,et al.  Polymer Modification of Fiber Optic Chemical Sensors as a Method of Enhancing Fluorescence Signal for pH Measurement , 1986 .

[17]  W. Rudolf Seitz,et al.  A fluorescence sensor for quantifying pH in the range from 6.5 to 8.5 , 1984 .

[18]  David R. Walt,et al.  Physiological pH fiber-optic chemical sensor based on energy transfer , 1987 .

[19]  Delana A. Nivens,et al.  Multilayer sol-gel membranes for optical sensing applications: single layer pH and dual layer CO(2) and NH(3) sensors. , 2002, Talanta.

[20]  Duncan L. MacFarlane,et al.  Microjetted lenslet triplet fibers , 1996 .