ZnO-Loaded Graphene for NO2 Gas Sensing

This paper investigates the effect of decorating graphene with zinc oxide (ZnO) nanoparticles (NPs) for the detection of NO2. In this regard, two graphene sensors with different ZnO loadings of 5 wt.% and 20 wt.% were prepared, and their responses towards NO2 at room temperature and different conditions were compared. The experimental results demonstrate that the graphene loaded with 5 wt.% ZnO NPs (G95/5) shows better performance at detecting low concentrations of the target gas than the one loaded with 20 wt.% ZnO NPs (G80/20). Moreover, measurements under dry and humid conditions of the G95/5 sensor revealed that the material is very sensitive to ambient moisture, showing an almost eight-fold increase in NO2 sensitivity when the background changes from dry to 70% relative humidity. Regarding sensor selectivity, it presents a significant selectivity towards NO2 compared to other gas compounds.

[1]  Dingfeng Jin,et al.  Engineering of ZnO/rGO towards NO2 Gas Detection: Ratio Modulated Sensing Type and Heterojunction Determined Response , 2023, Nanomaterials.

[2]  Zhi Yang,et al.  Fully Flexible MXene-based Gas Sensor on Paper for Highly Sensitive Room-Temperature Nitrogen Dioxide Detection. , 2023, ACS sensors.

[3]  Jianfeng Tan,et al.  Bismuth doped SnS2 nanoflower for real-time NO2 monitoring at room-temperature , 2023, Materials Letters.

[4]  N. Jayababu,et al.  Boron doped g-C3N4 quantum dots based highly sensitive surface acoustic wave NO2 sensor with faster gas kinetics under UV light illumination , 2022, Sensors and Actuators B: Chemical.

[5]  W. Hsiao,et al.  Laser surface modification on rGO/ZnO composite materials for NO2 gas sensing , 2022, Materials Chemistry and Physics.

[6]  T. Pustelny,et al.  Mechanisms of NO2 Detection in Hybrid Structures Containing Reduced Graphene Oxide: A Review , 2022, Sensors.

[7]  Bingsheng Du,et al.  Snse Nanosheet Arrays Film for Trace No2 Detection at Room Temperature , 2022, SSRN Electronic Journal.

[8]  Chaoliang Tan,et al.  Edge‐Enriched Mo2TiC2Tx/MoS2 Heterostructure with Coupling Interface for Selective NO2 Monitoring , 2022, Advanced Functional Materials.

[9]  Y. Choa,et al.  Tuning the sensing responses towards room-temperature hypersensitive methanol gas sensor using exfoliated graphene-enhanced ZnO quantum dot nanostructures. , 2022, Journal of hazardous materials.

[10]  Honglang Li,et al.  Facile Fabrication of MoS2 Nanoflowers/SnO2 Colloidal Quantum Dots Nanocomposite for Enhanced NO2 Sensing at Room Temperature , 2022, IEEE Sensors Journal.

[11]  S. S. Chougule,et al.  High performance langasite based SAW NO2 gas sensor using 2D g-C3N4@TiO2 hybrid nanocomposite. , 2021, Journal of hazardous materials.

[12]  Paulina R. Martínez-Alanis,et al.  Influence of Colloidal Au on the Growth of ZnO Nanostructures , 2021, Nanomaterials.

[13]  D. A. Edwards,et al.  Metal Oxides , 2020, Metals.

[14]  S. Noor,et al.  Graphene-based Materials in Gas Sensor Applications: A Review , 2020 .

[15]  Sungwook Jung,et al.  ZnO decorated flexible and strong graphene fibers for sensing NO2 and H2S at room temperature , 2020 .

[16]  E. Massera,et al.  Improvement of NO2 Detection: Graphene Decorated With ZnO Nanoparticles , 2019, IEEE Sensors Journal.

[17]  Paulina R. Martínez-Alanis,et al.  Tailoring the Green, Yellow and Red defect emission bands in ZnO nanowires via the growth parameters , 2019, Journal of Luminescence.

[18]  Chao Zhang,et al.  Room temperature conductive type metal oxide semiconductor gas sensors for NO2 detection , 2019, Sensors and Actuators A: Physical.

[19]  A. Watanabe,et al.  Recent Advances in Graphene-Based Humidity Sensors , 2019, Nanomaterials.

[20]  Qiliang Li,et al.  Recent Advances in Electrochemical Sensors for Detecting Toxic Gases: NO2, SO2 and H2S , 2019, Sensors.

[21]  Eduard Llobet,et al.  Gas Sensing with Iridium Oxide Nanoparticle Decorated Carbon Nanotubes , 2018, Sensors.

[22]  Sean C. Smith,et al.  On the mechanism of gas adsorption for pristine, defective and functionalized graphene. , 2016, Physical chemistry chemical physics : PCCP.

[23]  Xianghong Liu,et al.  Nanostructured Materials for Room‐Temperature Gas Sensors , 2016, Advanced materials.

[24]  Adisorn Tuantranont,et al.  Ultrasensitive NO2 Sensor Based on Ohmic Metal-Semiconductor Interfaces of Electrolytically Exfoliated Graphene/Flame-Spray-Made SnO2 Nanoparticles Composite Operating at Low Temperatures. , 2015, ACS applied materials & interfaces.

[25]  Jianbo Sun,et al.  Novel 3D graphene aerogel–ZnO composites as efficient detection for NO2 at room temperature , 2015 .

[26]  M. Seong,et al.  Polarized Raman spectroscopy with differing angles of laser incidence on single-layer graphene , 2015, Nanoscale Research Letters.

[27]  Hao Zhang,et al.  Enhancing NO2 gas sensing performances at room temperature based on reduced graphene oxide-ZnO nanoparticles hybrids , 2014 .

[28]  Toshio Itoh,et al.  Calorimetric Thermoelectric Gas Sensor for the Detection of Hydrogen, Methane and Mixed Gases , 2014, Sensors.

[29]  G. Shi,et al.  Graphene-based gas sensors , 2013 .

[30]  Zhen Jin,et al.  Metal Oxide Nanostructures and Their Gas Sensing Properties: A Review , 2012, Sensors.

[31]  F. Zamborini,et al.  Chemiresistive sensing with chemically modified metal and alloy nanoparticles. , 2012, Small.

[32]  V. Zólyomi,et al.  Resonance Raman spectroscopy of graphite and graphene , 2011 .

[33]  M. R. Wagner,et al.  Recombination dynamics in ZnO nanowires: Surfaces states versus mode quality factor , 2010 .

[34]  Gregory P. Harmer,et al.  Semiconducting metal oxide sensor array for the selective detection of combustion gases , 2003 .

[35]  U. Lampe,et al.  Metal Oxide Sensors , 1995, Proceedings of the International Solid-State Sensors and Actuators Conference - TRANSDUCERS '95.

[36]  J. W. Drummond,et al.  Gas Chromatographic Detector for Selective and Sensitive Detection of Atmospheric Organic Nitrates , 1994 .

[37]  Visweswara Rao Pasupuleti,et al.  UV Light Enhanced Room Temperature NO2 Gas Sensing Performances Based on Sulfur-doped Graphitic Carbon Nitride Nanoflakes , 2022, New Journal of Chemistry.

[38]  Jianbo Sun,et al.  One step solvothermal synthesis of urchin-like ZnO nanorods/graphene hollow spheres and their NO2 gas sensing properties , 2016 .

[39]  V. K. Rao,et al.  Chemiresistive gas sensor for the sensitive detection of nitrogen dioxide based on nitrogen doped graphene nanosheets , 2016 .

[40]  Aurangzeb Khan Raman Spectroscopic Study of the ZnO Nanostructures , 2011 .

[41]  A. C. Ferrari,et al.  Raman spectroscopy of graphene and related materials , 2022 .