SILICON DERIVATIVES OF THE METALS OF GROUPS 1 AND 2

[1]  D. Stalke,et al.  Doubly Lithiated Oligosilanes: Synthesis and Structure of the First Vicinal Dilithiodisilane , 1995 .

[2]  H. Reinke,et al.  The Formation and an Unusual Dimerization of 2‐Mesityl‐1,1‐bis(trimethylsilyl)silene , 1994 .

[3]  S. Castellino,et al.  Synthesis and Characterization of Two Aromatic Silicon-Containing Dianions:The 2,3,4,5-Tetraphenylsilole Dianion and the 1,1'-Disila-2,2',3,3',4,4',5,5'-Octaphenylfulvalene Dianion , 1994 .

[4]  J. Ohshita,et al.  Photolysis of Organopolysilanes. Photochemical Behavior of Branched Polysilanes , 1994 .

[5]  G. Hakimelahi,et al.  Interconversions among .alpha.-(Trimethylsilyl)alkoxides, .alpha.-Trimethylsiloxy Carbanions, and Carbonyl Compounds Accompanied by the Trimethylsilyl Anion , 1994 .

[6]  J. Arnold,et al.  Synthesis and Characterization of Divalent Lanthanide Selenolates and Tellurolates. X-ray Crystal Structures of Yb[SeSi(SiMe3)3]2(TMEDA)2 and {Eu[TeSi(SiMe3)3]2(DMPE)2}2(.mu.-DMPE) , 1994 .

[7]  W. Schwarz,et al.  Tetrakis(hypersilyl)dithallium(TlTl): A Divalent Thallium Compound , 1994 .

[8]  K. Hassler,et al.  Synthese, schwingungsspektren und normalkoordinatenanalyse von 1,2-Di-tert-butyltetrahalogendisilanen , 1994 .

[9]  S. Mallela,et al.  New cyclic and acyclic silicon-germanium and silicon-germanium-Tin derivatives , 1994 .

[10]  Z. Xue,et al.  Early-Transition-Metal Silyl Complexes Free from Anionic .pi.-Ligands. A New Family of Alkyl, Alkylidene, and Alkylidyne Compounds , 1994 .

[11]  A. Heine,et al.  Synthesis and Structure of the Disilagermirane R2Ge(SiR2)2 and the Solvent‐Separated Ion Pair [Li([12]crown‐4)2][GeR3]; (R = SiMe3) , 1994 .

[12]  H. Oehme,et al.  Bildung und Umwandlung des instabilen 2-tert-Butyl-1,1-bis(trimethylsilyl)-silens , 1994 .

[13]  K. Polborn,et al.  Zur Chemie der Galliumverbindungen, II. Darstellung und Struktur von Bis(2,2,6,6-tetramethylpiperidino)-[tris(trimethylsilyl)silyl]gallium — ein erstes Beispiel für ein monomeres Bis(amino)gallan mit Gallium-Silicium-Bindung , 1994 .

[14]  I. Fleming,et al.  Synthesis of acylsilanes from amides and esters, and the selective oxidation of α-silyl alcohols to aldehydes , 1994 .

[15]  W. Uhlig Zur reaktivität aminosubstituierter disilane und germylsilane gegenüber trifluormethansulfonsäure , 1993 .

[16]  H. V. Rasika Dias,et al.  The X-ray crystal structures of the mononuclear silyllithium species Li(THF)3SiPh3 and Li(THF)3Si(SiMe3)3 , 1993 .

[17]  T. Tilley,et al.  A Stable η5‐Germacyclopentadienyl Complex: [(η5 C5Me5)Ru{η5‐C4Me4GeSi(SiMe3)3}] , 1993 .

[18]  I. Fleming,et al.  The 2-methylbut-2-enyl(diphenyl)silyl group: A silyl group easily converted to hydroxyl in the presence of a 1,2-disubstituted CC double bond , 1993 .

[19]  W. Schwarz,et al.  Über die Synthese von Tris(trimethylsilyl)silyl-kalium, -rubidium und -caesium und die Molekülstrukturen zweier Toluolsolvate , 1993 .

[20]  W. Massa,et al.  Metallderivate von Molekülverbindungen. V: Synthese und Struktur von Hexakis{lithium-[tris(trimethylsilyl)silyl]tellanid}-Cyclopentan (1/1)) , 1993 .

[21]  K. Polborn,et al.  Tetrakis(tri‐tert‐butylsilyl)‐tetrahedro‐tetrasilane (tBu3Si)4Si4: The First Molecular Silicon Compound with a Si4 Tetrahedron , 1993 .

[22]  R. Heyn,et al.  Synthesis and reactions of silyl and germyl derivatives of scandocene. Structure of Cp2Sc[Si(SiMe3)3](THF) , 1993 .

[23]  W. Uhlig Zur Synthese des 1,2-Diphenyldecamethylcyclohexasilans , 1993 .

[24]  D. Stalke,et al.  Strukturuntersuchungen an den Produkten aus der Reaktion des Tris(trimethylsilyl)silyllithiums mit Aceton , 1993 .

[25]  P. Boudjouk,et al.  A stable aromatic species containing silicon. Synthesis and characterization of the 1-tert-butyl-2,3,4,5-tetraphenyl-1-silacyclopentadienide anion , 1993 .

[26]  A. Heine,et al.  Structural characterization of two modifications of tris(tetrahydrofuran)(tris(trimethylsilyl)silyl)lithium: a compound with a silicon-29-lithium-7 NMR coupling , 1993 .

[27]  A. Kunai,et al.  Polymeric organosilicon systems. 15. Thermal- and radical-induced polymerization of 1,2,5,6-tetrasilacycloocta-3,7-diynes , 1993 .

[28]  Harald Stüger,et al.  Darstellung und spektroskopische charakterisierung verzweigter funktioneller hexasilangerüste , 1993 .

[29]  E. Hengge,et al.  Über α,ω-übergangsmetallsubstituierte Oligosilane , 1993 .

[30]  C. Krüger,et al.  Synthese und Charakterisierung neuer Cyclischer und acyclischer Silachalkogenane mit Disilanyleinheiten , 1993 .

[31]  Gennaro J. Gama,et al.  Synthesis and characterization of M2(EPh3)2(NMe2)4 compounds (E = C, Si, Ge, Sn; M = Mo, W) , 1993 .

[32]  S. Mallela,et al.  Tris(trimethylsilyl)silyl)lead(IV) derivatives , 1993 .

[33]  W. Sundermeyer,et al.  Über die‐Synthese und Molekülstruktur von CH3M(SiH3)3 (MSi, Ge) , 1993 .

[34]  M. Dräger,et al.  Über gemischte gruppe 14-gruppe 14-bindungen: V. Sechs perphenylierte propan-analoga Ph3MM′Ph2M″Ph3 (M, M′, M″ = Si/Ge): ein beitrag zum elektronegativitätsunterschied zwischen silicium und germanium☆ , 1993 .

[35]  P. Hitchcock,et al.  Crystal structure of [Li(tmen)2][Li{C(SiMe3)3}2]. A multinuclear magnetic resonance study of tris(trimethylsilyl)methyllithium–tetrahydrofuran(1/2) and –N,N,N′,N′-tetramethylethylenediamine (1/1)(tmen) , 1993 .

[36]  A. Heine,et al.  Preparation and Structure of Two Highly Reactive Intermediates: [Li(thf)4][Cu5Cl4R2] and [Li(thf)4][AlCl3R], R Si(SiMe3)3 , 1993 .

[37]  A. Heine,et al.  [Cu2R2BrLi(thf)3], R = Si(SiMe3)3–a complex containing five-coordinate silicon in a three-centre two-electron bond (thf = tetrahydrofuran) , 1993 .

[38]  S. Mallela,et al.  Synthesis and studies of new tris(trimethylsilyl)silyl derivatives of germanium and tin , 1992 .

[39]  A. Allred,et al.  Cleavage of carbon-silicon bonds in the presence of silicon-silicon bonds by electron-transfer reagents , 1992 .

[40]  D. Comins,et al.  Stereoselective addition of (triphenylsilyl)magnesium bromide to chiral 1-acyl-4-methoxypyridinium salts. Synthesis and reactions of enantiopure 1-acyl-2-(triphenylsilyl)-2,3-dihydro-4-pyridones , 1992 .

[41]  T. Sham,et al.  Tetrakis(trimethylgermyl)silane and tris(trimethylgermyl)silyllithium , 1992 .

[42]  T. Edlund,et al.  Carbanion mechanisms: XVIII. Generation of silyl anions by nucleophilic cleavage of disilanes , 1992 .

[43]  R. Heyn,et al.  .sigma.-Bond metathesis reactions for d0 metal-silicon bonds that produce zirconocene and hafnocene hydrosilyl complexes , 1992 .

[44]  G. Becker,et al.  Metallderivate von Molekülverbindungen. IV. Synthese, Struktur und Reaktivität des Lithium‐[tris‐(trimethylsilyl)silyl]tellanids · DME , 1992 .

[45]  B. Dabbousi,et al.  New reagents for the synthesis of compounds containing metal-tellurium bonds: sterically hindered silyltellurolate derivatives and the x-ray crystal structures of [(THF)2LiTeSi(SiMe3)3]2 and [(12-crown-4)2Li][TeSi(SiMe3)3] , 1992 .

[46]  K. Tamao,et al.  The first stable functional silyl anions : (aminosilyl)lithiums , 1992 .

[47]  S. Mallela,et al.  Novel synthesis of 1,1,1,4,4,4-hexamethyl-2,2,3,3-tetrakis(trimethylsilyl)tetrasilane , 1992 .

[48]  B. Jiang,et al.  Trifluoroacetyltriphenylsilane as a potentially useful fluorine-containing building block. Preparation and its transformation into 2,2-difluoro enol silyl ethers , 1992 .

[49]  K. Matyjaszewski,et al.  Anionic intermediates in the reductive coupling of 1-chloro-2-phenyltetramethyldisilane with lithium and subsequent redistribution processes , 1992 .

[50]  A. Lough,et al.  Silacupration of oxabicyclic compounds. An interrupted ring opening reaction , 1992 .

[51]  A. K. Sarkar,et al.  A regiocontrolled and stereocontrolled synthesis of allylsilanes from β-silyl enolates , 1992 .

[52]  A. Barrett,et al.  Stereoselective alkene synthesis via (.alpha.-chloroalkyl)(dimethyl)phenylsilanes and .alpha.-(dimethyl)phenylsilyl ketones , 1992 .

[53]  W. Uhlig Zum gezielten Aufbau oligomerer Strukturen der Elemente der 14. Gruppe mittels ihrer Triflatderivate , 1991 .

[54]  J. Buynak,et al.  Thermal rearrangements of .alpha.-(acyloxy)silanes: formation of chiral precursors and migratory preference of silicon-based groups , 1991 .

[55]  F. Fehér,et al.  Beiträge zur Chemie des Siliciums und Germaniums. XL. Die Bildung von Alkalimetallsilanylen, MSinH2n+1 (M = Na, K), – eine neue Methode zur Knüpfung von Silicium–Silicium‐Bindungen ausgehend von SiH4 und Natrium oder Kalium , 1991 .

[56]  M. Murakami,et al.  Palladium-catalyzed insertion of isocyanides into the silicon-silicon linkages of oligosilanes , 1991 .

[57]  W. Uhlig Alkinylsubstituierte Silyltriflate—Synthese und Reaktivität , 1991 .

[58]  W. Uhlig Di-tert.-butylsilyl-bis-(trifluormethansulfonat) – ein vielseitig nutzbarer Synthesebaustein zur Darstellung bifunktioneller Silane† , 1991 .

[59]  K. Pannell,et al.  Photochemical transformations of digermyl and isomeric silylgermyl and germylsilyl complexes of the (η5-C5H5)Fe(CO)2 system. Significant stability of germylene versus silylene intermediates , 1991 .

[60]  P. D. Lickiss,et al.  Preparation and reactions of tris(trimethylsilyl)silyl silicon derivatives and related tetrasilylsilanes , 1991 .

[61]  S. Mallela,et al.  Preparation and structural characterization of new derivatives of digermane bearing tris(trimethylsilyl)silyl substituents , 1991 .

[62]  B. Dabbousi,et al.  Tris(trimethylsilyl)silanetellurol: preparation, characterization, and synthetic utility of a remarkably stable tellurol , 1991 .

[63]  J. Maxka,et al.  Synthesis and NMR spectroscopy of permethylpolysilane oligomers Me(SiMe2)10Me, Me(SiMe2)16Me, and Me(Me2Si)22Me , 1991 .

[64]  K. Burgess,et al.  Optically active building blocks from the SPAC reaction: a completely asymmetric synthesis of (4S-cis)-5-(cyclohexylmethyl)-4-hydroxy-2-pyrrolidinone, a statine analog , 1991 .

[65]  M. A. North,et al.  REARRANGEMENTS OF ALPHA-SILYLSILYLENES TO BETA-SILYLSILYLENES: A MECHANISTIC CONUNDRUM , 1991 .

[66]  S. Sharma,et al.  Synthetic and mechanistic implications of ligand mixing in higher order mixed (trialkylsilyl)- and (trialkylstannyl)cuprates , 1991 .

[67]  I. Fleming,et al.  The reaction of tert-butyldiphenylsilylcuprates with allenes , 1991 .

[68]  Herbert Wagner,et al.  Übergangsmetall-Silyl-Komplexe, 36 Zur Frage von Gold-Gold-Wechselwirkungen bei Ph2P[CH2]1(2) PPh2 verbrückten zweikernigen Gold-Silyl-Komplexen , 1991 .

[69]  D. A. Armitage,et al.  The Silicon-heteroatom bond , 1991 .

[70]  R. Boese,et al.  A 1 ‐Silyl‐1H‐phosphirene/1, 2‐Dihydro‐1,2‐phosphasilete Rearrangement—The Decisive Step in the Synthesis of Heterocycles Containing 2‐Phospha‐1,3‐diene Units , 1990 .

[71]  C. Eaborn Henry Gilman, 9 May 1893 - 7 November 1986 , 1990, Biographical Memoirs of Fellows of the Royal Society.

[72]  U. Flörke,et al.  Silyl-, stannyl- and plumbyl-copper compounds containing chelating and monodentate phosphine ligands , 1990 .

[73]  R. Lagow,et al.  SYNTHESIS OF THE FIRST ORGANODILITHIOSILANE BY THERMAL REARRANGEMENT , 1990 .

[74]  Herbert Wagner,et al.  Übergangsmetall-Silyl-Komplexe, 35. Silber(I)-Silyl-Komplexe (R3P)nAgSiR'3 (n = 1-3) , 1990 .

[75]  R. Heyn,et al.  Preparation and properties of tris(trimethylstannyl)silyl complexes of chromium, molybdenum, and tungsten. X-ray structure of [NEt4][(CO)5WSi(SnMe3)3] , 1990 .

[76]  R. West,et al.  Synthesis of an ordered structurally periodic polysilane, (Me2Si-n-Hex2SiMe2Si)n , 1990 .

[77]  S. Mallela,et al.  Preparation and characterization of tris(trimethylsilyl)silyl derivatives of tin. X-ray crystal structure of Cl2Sn[Si(Si(CH3)3)3]2 , 1990 .

[78]  F. Hahn,et al.  Metallorganische verbindungen der lanthanoide LVIII. Zur struktur des dicyclopentadienyl-bis(trimethylsilyl)lutetat-anions☆ , 1990 .

[79]  C. Bolm,et al.  Acylsilane chemistry. Synthesis of regio- and stereoisomerically defined enol silyl ethers using acylsilanes , 1990 .

[80]  M. Pöschl,et al.  Schwingungsspektren und Synthese einiger Phenyl- undp-Tolyldisilane , 1990 .

[81]  M. Pöschl,et al.  Synthese einiger phenylbrom- und phenyliod-disilane und -trisilane , 1990 .

[82]  V. Fülöp,et al.  Concerning the silicon-germanium bond. The structures of isomeric Ph3EE′Me3, E = Ge, E′ = Si and E = Si, E′ = Ge , 1990 .

[83]  R. Heyn,et al.  Reactivity of a scandium-silicon bond toward carbon monoxide and CN(2,6-Me2C6H3). Generation and reactivity of an apparent silene intermediate resulting from isocyanide coupling at scandium , 1990 .

[84]  M. Layh,et al.  Synthesis and molecular structure of a bis[di(alkyl)alanyl]methane; R2ALCH2AIR2 [R = CH(SiMe3)2] , 1990 .

[85]  T. Tokoroyama,et al.  Convenient Stereoselective Syntheses of (6E)- and (6Z)-5,6-Dimethyl-8-silyl-octenals , 1990 .

[86]  S. Koo,et al.  1,2-Addition of dimethyl(phenyl)silyllithium to cyclic α,β-unsaturated ketones and regiospecific generation of cyclic silyl enol ethers through brook rearrangement of the 1,2-addition products , 1990 .

[87]  V. D. Mel,et al.  Preparation and structure of aluminum derivatives of the extremely bulky tris(trimethylsilyl)silyl group. The molecular structure of the (Me3Si)3SiAl(C6H5)2.cntdot.THF adduct , 1989 .

[88]  S. Sharma,et al.  Chemistry and composition of (trialkylsilyl)cuprates derived from cuprous halides , 1989 .

[89]  H. Schumann,et al.  Organometallarsine. X: Carbonyl-dinitrosyl-organometallarsin-eisen und Dicarbonyl-nitrosyl-organometallarsin-cobalt Komplexe , 1989 .

[90]  C. Guérin,et al.  Hypervalent silicon hydrides: evidence of their intermediacy in the reaction of optically active 1-NpPhMeSiH(D) with hydrides , 1989 .

[91]  K. Pannell,et al.  Organometalloidal derivatives of transition metals. Part XXI. Synthesis and photochemical deoligomerizations of a series of isomeric disilyl iron complexes: (.eta.5-C5H5)Fe(CO)2Si2Ph3-nMe2+n) , 1989 .

[92]  M. Fink,et al.  Polysilyl complexes of platinum - synthesis and thermochemistry , 1989 .

[93]  W. Schwarz,et al.  Metallderivate von Molekülverbindungen. II: Darstellung und Struktur des β-Kaliumsilanids , 1989 .

[94]  R. Heyn,et al.  Tris(trimethylsilyl)silyl derivatives of tri-tert-butoxyzirconium and tri-tert-butoxyhafnium. X-ray crystal structure of (Me3CO)3ZrSi(SiMe3)3 , 1989 .

[95]  G. Becker,et al.  Molekül- und Kristallstruktur des 1,4-Bis[tris(tetrahydrofuran)lithium]-octaphenyltetrasilans , 1989 .

[96]  A. Saxena,et al.  Photochemical rearrangements of stable silenes , 1989 .

[97]  Herbert Wagner,et al.  Übergangsmetall-Silyl-Komplexe: XXX. Silber-Silyl-Komplexe , 1989 .

[98]  U. Schubert,et al.  Übergangsmetall-Silyl-Komplexe, 26. Gold(I)-Silyl-Komplexe , 1989 .

[99]  D. Roddick,et al.  Dimesitylsilyl derivatives of zirconium , 1989 .

[100]  Yitzhak Apeloig,et al.  The chemistry of organic silicon compounds , 1989 .

[101]  G. Rossetto,et al.  Tri(η-cyclopentadienyl)uranium(IV) silyl and siloxide compounds. Crystal structure of [U(η5-C5H5)3(OSiPh3)]. Insertion of lsocyanide into a uranium–silicon bond , 1989 .

[102]  F. J. Pulido,et al.  t-Butyldiphenylsilyl-Lithium and Lithium Bis(t-Butyldiphenylsilyl)Cuprate. New Silylating Reagents , 1989 .

[103]  A. Oehlschlager,et al.  Chemical and spectroscopic investigations of trialkylsilylcuprates derived from CuCN , 1989 .

[104]  K. Takaki,et al.  Stereochemistry in the Michael addition of silylcuprate to .alpha.,.beta.-unsaturated sulfoxide , 1989 .

[105]  B. Trost,et al.  Synthesis of 4-(dimethylphenylsilyl)buta-2,3-dien-1-ol and its use in alkylation , 1989 .

[106]  S. Geib,et al.  Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl , 1988 .

[107]  H. Goff,et al.  Synthesis and reactivity of silyliron porphyrin complexes , 1988 .

[108]  A. Fürstner,et al.  Efficient formation and cleavage of disilanes by potassium-graphite. Silylation with silyl metal reagents , 1988 .

[109]  D. Roddick,et al.  Preparation and characterization of tris(trimethylsilyl)silyl and tris(trimethylsilyl)germyl derivatives of zirconium and hafnium. X-ray crystal structures of (.eta.5-C5Me5)Cl2HfSi(SiMe3)3 and (.eta.5-C5Me5)Cl2HfGe(SiMe3)3 , 1988 .

[110]  C. M. Nunn,et al.  Phosphane‐Stabilized CuI and AgI Silanes , 1988 .

[111]  K. Hassler Synthese und Eigenschaften einigerp-tolyl-phenylsubstituierter Di- und Trisilane und von 1,1,1,3,3,3-Hexaphenyltrisilan , 1988 .

[112]  C. A. Grob,et al.  The mild bromination of adamantane and (trimethylsilyl) adamantanes , 1988 .

[113]  H. Schumann,et al.  Organometallic compounds of the lanthanides. 42. Bis(dimethoxyethane)lithium bis(cyclopentadienyl)bis(trimethylsilyl)lanthanide complexes , 1988 .

[114]  M. Ochiai,et al.  Hypervalent alkenyliodonium tetrafluoroborates. Evidence for generation of alkylidenecarbenes via base-induced .alpha.-elimination , 1988 .

[115]  H. Yamashita,et al.  Reductive elimination of sym-diphenyltetramethyldisilane from cis-bis(phenyldimethylsilyl)bis(phosphine)platinum(II) complexes , 1988 .

[116]  A. Degl'innocenti,et al.  Easy one-step general synthesis of acylsilanes , 1988 .

[117]  U. Schubert,et al.  Übergangsmetall-Silyl-Komplexe, 23. Versuche zum Mechanismus der Bildung von [C5H4Si(SiMe3)3]2 WH2 aus (C5H5)2 WCl2 und Li[Si(SiMe3)3] , 1988 .

[118]  Y. Izumi,et al.  A regiodefined synthesis of α-trimethylsilyl ketones catalyzed by rhodium(I) hydride complex , 1988 .

[119]  N. Wibeŕg,et al.  Zur Kenntnis des stabilen Silanimins tBu2SiN ? SitBu3 und seiner Donoraddukte , 1988 .

[120]  N. Wibeŕg,et al.  Donoraddukte des Silanimins Me2SiNSitBu3: Darstellung, Stabilität, Reaktivität☆ , 1988 .

[121]  R. West,et al.  Generation of silanimines by photolysis of hindered azidosilanes , 1988 .

[122]  M. A. Waugh,et al.  Synthesis of β-silyl ketones via reaction of trimethylsilyllthium with unsaturated hydrazones. Application to the synthesis of brevicomin , 1988 .

[123]  M. Veith,et al.  Darstellung und Strukturen der Silyltriazene tBu3Si-N=N-NR-SitBu3 (R = Na, H, Me, SnMe3) , 1988 .

[124]  T. Hiyama,et al.  Fluoride ion-catalyzed generation and carbonyl addition of α-halo carbanions derived from α-halo organosilicon compounds , 1988 .

[125]  K. Oshima,et al.  Organic synthesis with reagents derived from 3R3SiMgMe and MnCl2 , 1988 .

[126]  T. Tilley,et al.  Preparation of the first stable formylsilane, (Me3Si)3SiCHO, from a zirconium .eta.2-silaacyl complex , 1988 .

[127]  W. Kitching,et al.  Silylcuprate Routes to Cyclohex-2-enylsilanes , 1988 .

[128]  Masaaki Suzuki,et al.  Prostaglandin synthesis. 14. A controlled synthesis of isocarbacyclin , 1987 .

[129]  S. Matsubara,et al.  Facile stereoselective synthesis of internal conjugated (E,E)-dienes including 2,4-alkadienyl amines, silanes, and stannanes , 1987 .

[130]  U. Edlund,et al.  Lithium-7, silicon-29, tin-119, and lead-207 NMR studies of phenyl-substituted Group 4 anions , 1987 .

[131]  M. Fink,et al.  Photochemical generation of cyclopropenylsilylenes , 1987 .

[132]  S. Geib,et al.  Preparation and characterization of tris(trimethylsilyl)silyl derivatives of zinc, cadmium, and mercury. X-ray crystal structure of Zn[Si(SiMe3)3]2 , 1987 .

[133]  A. Arif,et al.  A bulky silyl derivative of tin(II) , 1987 .

[134]  D. Roddick,et al.  Coordinatively unsaturated tris(trimethylsilyl)silyl complexes of chromium, manganese, and iron , 1987 .

[135]  K. Hassler,et al.  Synthese, Infrarot- und Raman-Spektren der Heptamethyltrisilane XMe2Si-SiMe2-SiMe3, X=H, F, Cl, Br, I, OMe, Ph , 1987 .

[136]  Paul von Ragué Schleyer,et al.  Sodium, Potassium, Rubidium, and Cesium: X-Ray Structurai Analysis of Their Organic Compounds1 , 1987 .

[137]  J. Oliver,et al.  Silylcupration of acetylenes , 1986 .

[138]  W. Oppolzer,et al.  Preparation of Enantiomerically Pure β-Silylcarboxyl Derivatives by Asymmetric 1,4-Addition to N-Enoyl-sultams. Preliminary Communication† , 1986 .

[139]  E. Hengge,et al.  Bicyclic silanes from cyclosilane-metal derivatives , 1986 .

[140]  U. Edlund,et al.  Concerning the Si—Li bonding in phenylsilyllithiums as studied by variable temperature Li nuclear magnetic resonance , 1986 .

[141]  K. Oshima,et al.  SILYLMANGANATION OF 1,3-DIENES. A FACILE SYNTHESIS OF FUNCTIONALIZED VINYLSILANES , 1986 .

[142]  R. Schmutzler,et al.  A PHOSPHORANE WITH A (λ5)-PHOSPHORUS-SILICON BOND , 1986 .

[143]  K. Oshima,et al.  1,4‐Addition of triorganozincates and silyldiorganozincates to α,β‐unsaturated ketones , 1986 .

[144]  R. Boese,et al.  Stabilisierung und Reaktionen von Iminoboranen — Kristallstruktur von (tert-Butylimino)[tris(trimethylsilyl)-silyl]boran , 1986 .

[145]  E. Vedejs,et al.  Hyperconjugative effects of allylic substituents are not important in osmylations , 1986 .

[146]  E. Hengge,et al.  Darstellung und charakterisierung der phenylfluordisilane Si2Ph6-nFn , 1986 .

[147]  J. Smith Some highly sterically hindered organosilicon compounds , 1986 .

[148]  Richard A. Jones,et al.  Synthesis and structural characterisation of compounds with gallium−silicon and indium−silicon bonds , 1986 .

[149]  K. Peters,et al.  Hexa‐tert‐butyldisilane–the Molecule with the Longest Si ? Si Bond , 1986 .

[150]  G. Müller,et al.  Preparation and structure of a stable molecule containing a silicon nitrogen double bond and of its tetrahydrofuran adduct , 1986 .

[151]  K. Oshima,et al.  Transition-metal catalyzed silylzincation and silylalumination of acetylenic compounds , 1986 .

[152]  I. Fleming,et al.  Effect of a β-silyl group on the regiochemistry of enolisation of ketones , 1986 .

[153]  G. Becker,et al.  Synthese und Struktur von Lithium-tris(trimethylsilyl)-silanid · 1,5 DME , 1985 .

[154]  U. Edlund,et al.  Evidence on covalency and monomeric structure of phenyl silyl lithiums in ethereal solutions from scalar 29Si-6(7)Li couplings , 1985 .

[155]  U. Schubert,et al.  Übergangsmetall-silyl-komplexe: IV. Bildung eines ring-substituierten wolframocen dihydrid derivats durch reaktion von Cp2WCl2 MIT Li[Si(SiMe3)3] , 1985 .

[156]  J. Michl,et al.  Dimethylsilylene: a trisilane and a geminal diazide as new photochemical precursors. Evidence for an absorption maximum near 450 nm , 1985 .

[157]  U. Schubert,et al.  Transition metal silyl complexes, part iii. reaction of tris(trimethylsilyl)silyllithium with cyclopentadienyliron bromides , 1985 .

[158]  U. Edlund,et al.  NMR studies of phenylsilyl anions. Evaluation of ion pairing and charge distribution , 1985 .

[159]  U. Klingebiel,et al.  Halogen‐ und aminofunktionelle Tris(trimethylsilyl)silyl‐silane , 1985 .

[160]  M. Weidenbruch,et al.  Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, XX [1] 1,1-Di-tert-butyl-2,2-dimesityldisilane: Synthese, Molekülstruktur, Radikale / Silicon Compounds with Strong Intramolecular Steric Interactions, XX [1] 1,1-Di-tert-butyl-2,2-dimesityldisilanes: Synthesis, Molecular , 1985 .

[161]  U. Dzhemilev,et al.  Some novelties in olefin carbometallation assisted by alkyl-magnesium and -aluminium derivatives and catalyzed by zirconium and titanium complexes , 1985 .

[162]  M. Haase,et al.  Simple Synthesis of Stable Iminoboranes , 1985 .

[163]  M. J. Heeg,et al.  Organometallic compounds of the lanthanides. 24. Synthesis and x-ray crystallographic characterization of the first organolanthanide derivative with a lanthanide-silicon bond , 1985 .

[164]  K. Oshima,et al.  Copper catalyzed silylzincation of acetylenes , 1985 .

[165]  Y. Ban,et al.  Syntheses of (±)-pyrenophorin and (±)-colletallol , 1985 .

[166]  Paul von Ragué Schleyer,et al.  X-ray structural analyses of organolithium compounds , 1985 .

[167]  N. S. Vyazankin,et al.  2-Triethylsilyl- and 2-triethylgermyl-1,3-di-t-butyl-1,3,2-diazaphosphorinanes: Synthesis, structure and chemical properties , 1984 .

[168]  N. Quinn,et al.  Regioselective synthesis of allyltrimethylsilanes from allylic halides and allylic sulfonates. Application to the synthesis of 2,3-bis(trimethylsilyl)alk-1-enes , 1984 .

[169]  H. Chiu,et al.  The molybdenum-molybdenum triple bond. 15. Compounds with chains of metal atoms having M-M single and triple bonds: M2(M'(M'Me3)3)2(NMe2)4 (M.tplbond.M) where M = Mo and W and M' = Si and Sn , 1984 .

[170]  Laval Yau,et al.  Attempted preparation of silaethylenes from silanecarboxylate esters , 1984 .

[171]  W. Weber,et al.  Preparation of 1-silyl- and 1,3-disilyl-adamantanes , 1984 .

[172]  A. Maercker,et al.  Darstellung und Kristallstruktur von 3-(Lithiomethyl)- 1,1,2,2-tetramethylcyclopropan, einer stabilen Cyclopropylmethyllithium-Verbindung , 1984 .

[173]  J. Chruściel,et al.  A new anion rearrangement involving silyl migration to oxygen , 1984 .

[174]  K. Mochida,et al.  INSERTION REACTIONS OF CALCIUM ATOM INTO Si–Cl AND Ge–Cl BONDS , 1984 .

[175]  Dietmar Seyferth,et al.  Comprehensive Organometallic Chemistry , 1984 .

[176]  G. Fischer,et al.  1,3‐Bis(tri‐tert‐butylsilyl)triazen , 1984 .

[177]  U. Edlund,et al.  N.M.R. studies of phenyl-substituted group 4 anions. Ion-pairing and charge delocalization vs. π-polarization effects , 1984 .

[178]  I. Fleming,et al.  Observations on various silyl-cuprate reagents , 1984 .

[179]  Y. Morizawa,et al.  Transition-metal catalyzed silylmetalation of allenes , 1984 .

[180]  Y. Morizawa,et al.  Intramolecular cyclization mediated by silylmetalation of acetylenes with PhMe2SiMgMe/CuI and radical nature of the reagent , 1984 .

[181]  C. Eaborn Silicon Reagents in Organic Synthesis , 1983 .

[182]  N. Quinn,et al.  Regioselective Synthesis of Allyl Trimethylsilanes from Allylic Halides , 1983 .

[183]  L. Rösch,et al.  Tetrakis(trimethylsilyl)plumbane, The First Organosilicon‐Lead Compound , 1983 .

[184]  E. Weiss,et al.  (PhCCLi)4(tmhda)2, A Polymeric Organolithium Compound with cubic Li4C4 Structural Units , 1983 .

[185]  J. Oliver,et al.  Silicon-metal bonded compounds. 17. The synthesis and crystal structure of bis[tris(trimethylsilyl)aluminum]-tetramethylethylenediamine and of bis(trimethylsilyl)magnesium-tetramethylethylenediamine , 1983 .

[186]  Joseph B. Paperman,et al.  Reactivity of Kel-F polymers with organolithium and organomagnesium compounds , 1983 .

[187]  Y. Morizawa,et al.  Transition-metal-catalyzed silylmetalation of acetylenes and its application to the stereoselective synthesis of steroidal side chains , 1983 .

[188]  U. Schubert,et al.  Übergangsmetall-carben-komplexe: CXXVIII. Neuartige carboethoxy(silyl)alkyliden-und silylketenyl-verbrückte dirhenium-komplexe als nebenprodukte einer silylcarben-komplex-synthese , 1983 .

[189]  H. Chiu,et al.  Incorporating metal-metal multiple bonds into heterometallic chains: bis[tris(trimethylstanyl)tin]tetrakis(dimethylamido)dimolybdenum and -ditungsten and related compounds , 1983 .

[190]  M. Kumada,et al.  CHEMISTRY OF SILOLES. 1-METHYLDIBENZOSILACYCLOPENTADIENIDE ANION , 1983 .

[191]  W. Weber Silicon Reagents for Organic Synthesis , 1983 .

[192]  K. Oshima,et al.  New synthesis of allylsilanes and vinylsilanes by means of PhMe2Si-AlEt2 , 1983 .

[193]  J. K. Sutherland,et al.  A synthesis of (±)-pregn-4-en-20-one , 1983 .

[194]  J. Baldwin,et al.  Deoxygenation of isocyanates to isonitriles : A mechanistic study by nuclear magnetic resonance , 1983 .

[195]  J. Baldwin,et al.  A new method for the reduction of isocyanates to isocyanides , 1983 .

[196]  Kang-Wook Lee,et al.  Reaction of (triphenylmethyl)-, (triphenylsilyl)-, (triphenylgermyl)- and (triphenylstannyl)lithium with optically active 2-octyl tosylate, chloride and bromide , 1982 .

[197]  M. Kumada,et al.  PALLADIUM-CATALYZED FORMATION OF 1,4-DISILA-2,5-CYCLOHEXADIENES FROM 1-SILACYCLOPROPENES , 1982 .

[198]  W. Ilsley,et al.  Metal-silicon bonded compounds. 16. The structure of (LiSiMe3)2.(Me2NCH2CH2NMe2)3, a highly reactive silylating agent , 1982 .

[199]  H. Nöth,et al.  Beiträge zur Chemie des Bors, 123. (Trimethylsilyl)borate aus Alkoxyboranen und Trimethylsilyllithium , 1982 .

[200]  G. Gutekunst,et al.  Tris(trimethylsilyl)silyllithium · 3 THF: a stable crystalline silyllithium reagent , 1982 .

[201]  J. Majoral,et al.  A new route to bis(2,4,6-tri-tert-butylphenyl)diphosphene via silylated compound , 1982 .

[202]  M. Kumada,et al.  Stereochemistry in the reaction of an optically active secondary alkyl chloride with triphenylsilyl-lithium , 1982 .

[203]  W. Kitching,et al.  Concerning the formation, reduction and conformations of .beta.-(trimethylsilyl)- and .beta.-(trimethylstannyl)cyclohexanones , 1982 .

[204]  A. Cowley,et al.  Reaction of (tris(trimethylsilyl)silyl)lithium with halophosphines. A novel silicon-halogen exchange reaction , 1982 .

[205]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 84 [1]. Synthese und thermische Umlagerung von verschieden substituierten linearen und cyclischen Silanen† , 1981 .

[206]  H. Nöth,et al.  Beiträge zur Chemie des Bors, 124 [1] Tris(trimethylsilyl)silyl-borane und Tris(trimethylsilyl)silyl-borate / Contributions to the Chemistry of Boron, 124 [1] Tris(trimethylsilyl)silyl Boranes and Tris(trimethylsilyl)silyl Borates , 1981 .

[207]  T. J. Anderson,et al.  Metal-silicon-bonded compounds. 11. Crystal and molecular structures of Li2Hg(SiMe2Ph)4 and Li2Hg(SiMe3)4, novel chain and caged lithium metallates , 1980 .

[208]  G. Olah,et al.  Organometallic chemistry. 17. Silicon-29 and carbon-13 NMR spectroscopic study of phenylsilyl anions. The question of silicon-carbon p.pi.-p.pi.-electron delocalization and comparison with related carbanions , 1980 .

[209]  R. Balasubramanian,et al.  Metalsilicon bonded compounds , 1980 .

[210]  M. D. Glick,et al.  Metal-silicon bonded compounds. 12. Crystal and molecular structure of hexameric trimethylsilyllithium, [LiSiMe3]6 , 1980 .

[211]  C. Guérin,et al.  Alkali metal hydrides: new metallating reagents at silicon , 1980 .

[212]  H. Nöth,et al.  Stabilization of Diborane(4) Derivatives by tert‐Butyl Groups: The First Tetraalkyldiborane(4) , 1980 .

[213]  James S. Johnson,et al.  Carboxy-silanes and -germanes , 1979 .

[214]  E. W. Colvin,et al.  Silicon in organic synthesis , 1978 .

[215]  P. Müller,et al.  Nickel(O)‐Komplexe mit anionischen Liganden des Typs E(C6H5) 3− (E = Si, Ge, Sn) , 1978 .

[216]  I. Fleming,et al.  A silicon-based protecting group for the αβ-unsaturation of αβ-unsaturated ketones , 1978 .

[217]  J. B. Lambert,et al.  Diastereotopic groups in silyllithium and germyllithium compounds. Slow inversion about silicon and germanium , 1978 .

[218]  D. Seyferth Houben-Weyl methoden der organischen chemie , 1978 .

[219]  I. Fleming,et al.  ?-Silylketones as masked ??-unsaturated ketones , 1978 .

[220]  W. Ollis,et al.  Comprehensive organic chemistry : the synthesis and reactions of organic compounds , 1978 .

[221]  H. Sakurai,et al.  Silyl anions. VII. Electron transfer from trimethylsilylpotassium to benzophenone and naphthalene. Generation of anion radicals in nonpolar solvents such as n-hexane. , 1977 .

[222]  R. Lagow,et al.  Chemistry of polylithiated species; reactions of polylithiated silanes and germanes , 1977 .

[223]  L. Rösch Bis(trimethylsilyl)magnesium—The First Organosilyl-magnesium Compound Isolated† , 1977 .

[224]  T. J. Anderson,et al.  Metal-silicon bonded compounds. 9. The synthesis and structure of bis(trimethylsilyl)magnesium 1,2-dimethoxyethane adduct , 1977 .

[225]  W. C. Still,et al.  Conjugate addition of trimethysilyllithium. A preparation of 3-silyl ketones , 1976 .

[226]  P. Dervan,et al.  Trimethylsilylpotassium. Deoxygenation of epoxides with inversion of stereochemistry , 1976 .

[227]  W. Robinson,et al.  Polysilane derivatives of the transition metals , 1976 .

[228]  R. Corriu,et al.  Optically active silylanions. Evidence for the formation of analogues of silyl Grignard reagents , 1976 .

[229]  M. Reetz,et al.  trans-Stereospezifische Desoxygenierung voe Epoxiden mittels Dimethylphenylsilyllithium , 1976 .

[230]  H. Sakurai,et al.  Chemistry of organosilicon compounds : LXXX. Useful modifications in the preparation of trimethylsilylsodium and trimethylsilylpotassium , 1975 .

[231]  W. Butler,et al.  Structure of hexameric trimethylsilyllithium, a folded chair , 1974 .

[232]  J. Simpson,et al.  Polysilane derivatives of the transition metals III. Preparations and spectra of manganese and iron derivatives , 1974 .

[233]  A. Brook Molecular Rearrangements of Organosilicon Compounds , 1974 .

[234]  B. Wakefield The Chemistry of Organolithium Compounds , 1974 .

[235]  A. Okada,et al.  Silyl anions. IV. New convenient method of producing radical anions involving one-electron transfer from trimethylsilylsodium , 1973 .

[236]  J. J. Brooks,et al.  .pi.-Groups in ion pair bonding. Triphenylmethyllithium tetramethylethylenediamine , 1972 .

[237]  A. Okada,et al.  Trimethylsilylsodium. A new preparation and some reactions involving a facile electron transfer from trimethylsilyl anion to naphthalene , 1971 .

[238]  E. Weiss,et al.  Kristallstrukturen und kernmagnetische Breitlinienresonanz der Alkalisilyle SiH3M (M = K, Rb, Cs) , 1970 .

[239]  P. Kapoor,et al.  Preparation and properties of compounds containing platinum–silicon bonds , 1970 .

[240]  F. Fehér,et al.  Beiträge zur chemie des siliziums und germaniums XIV über die umsetzung von kaliumsilyl mit phenylbromsilanen und phenylbromgermanen darstellung von phenylsilylkalium , 1970 .

[241]  P. N. Preston,et al.  Nitroso-derivatives of fourth main group elements , 1969 .

[242]  E. Amberger,et al.  Reaktionen der hydrylanionen VIII. Synthese von πC5H5Fe(CO)2SiH3 , 1969 .

[243]  U. Klose,et al.  The Coordination Behavior of Triphenylsilanide , 1968 .

[244]  E. Hengger,et al.  Darstellung unsymmetrischer disilane mittels trimethylsilyllithium , 1968 .

[245]  H. Gilman,et al.  Hexakis(trimethylsilyl)disilane: A highly branched and symmetrical organopolysilane , 1967 .

[246]  N. S. Vyazankin,et al.  The synthesis of triethylsilyllithium and triethylgermyllithium and the investigation of some of their reactions , 1967 .

[247]  H. Gilman,et al.  The preparation of tetrakis(dimethylphenylsilyl)silane , 1966 .

[248]  H. Gilman,et al.  Some improved preparations of silylmetallic compounds , 1966 .

[249]  E. Staude,et al.  Recent Developments in the Chemistry of Metal Silyls of the Type M(SiR3)n , 1963 .

[250]  J. Eisch Chemistry of Alkali Metal-unsaturated Hydrocarbon Adducts. III. Cleavage Reactions by Lithium-Biphenyl Solutions in Tetrahydrofuran , 1963 .

[251]  D. Seyferth,et al.  Notes- The Triphenylsilyltriphenylborate Anion and Its Germination Analog , 1961 .

[252]  D. Ritter,et al.  Preparation and Reactions of Potassium Silyl1 , 1961 .

[253]  D. Ritter,et al.  CRYSTAL STRUCTURE OF POTASSIUM SILYL , 1961 .

[254]  H. Gilman,et al.  Preparation of Silyl- and Germylmetallic Compounds , 1960 .

[255]  P. Fleetwood,et al.  Notes- Effect of Sodium in the Preparation of n-Butyl-lithium , 1959 .

[256]  H. Gilman,et al.  Cleavage reactions of some organopolysilanes , 1959 .

[257]  H. Gilman,et al.  Oxygen oxidation of triphenylsilyllithium , 1959 .

[258]  R. West,et al.  The reductive coupling of triphenylchlorosilane: Evidence for the triphenylsilyl Grignard reagent☆ , 1959 .

[259]  H. Gilman,et al.  Some Reactions of Silyllithium Compounds with Ethers , 1958 .

[260]  H. Gilman,et al.  An Intramolecular Cleavage-Cyclization Reaction of Silicon-containing Organolithium Compounds , 1958 .

[261]  H. Gilman,et al.  Cleavage of Symmetrically Substituted Disilanes by Lithium in Tetrahydrofuran , 1958 .

[262]  H. Gilman,et al.  Analogs of Hexaphenylethane. III. Triphenylmethyltriphenylgermane, Triphenylgermanecarboxylic Acid and Some of Its Derivatives1 , 1954 .

[263]  H. Gilman,et al.  The Preparation and Cleavage Studies of some Organosilicon Compounds , 1953 .

[264]  H. Gilman,et al.  Analogs of Hexaphenylethane. I. Hexaaryldisilanes Containing Phenyl and p-Tolyl Groups , 1953 .

[265]  H. Gilman,et al.  Preparation of Organopolysilanes , 1952 .

[266]  H. Gilman,et al.  Preparation and Properties of Hexaaryldisilanes , 1951 .

[267]  H. Gilman,et al.  Cleavage of the Silicon-Silicon Bond in Hexa-phenyldisilane , 1951 .

[268]  C. A. Kraus,et al.  Chemistry of the Tris-(triphenylgermanyl)-silyl Group1 , 1950 .

[269]  H. Gilman,et al.  The Preparation of n-Butyllithium , 1949 .

[270]  C. A. Kraus,et al.  The Chemistry of the Triethylsilicyl Group , 1934 .