Influences of CNT dispersion and pore characteristics on the electrical performance of cementitious composites

Abstract In the present study, cementitious composite incorporating a carbon nanotube (CNT) with highly improved electrical conductivity comparable to that of a semiconductor is developed and investigated. The CNT and pore characteristics within a cementitious matrix are considered as the most influential factors which determine the overall performance of the material, and these factors are artificially controlled by incorporating silica fume and a superplasticizer. Additionally, a micromechanics-based model is proposed to predict the electrical performance and percolation threshold of the composites. A parametric study based on the developed model is conducted, and the influences of the constituent properties on the overall electrical characteristics of composites are discussed. The effectiveness of the proposed hypothesis is demonstrated by comparing it to the experimental results in the present study and from the previous work.

[1]  Alexander H.-D. Cheng,et al.  Materials Genome for Graphene-Cement Nanocomposites , 2013 .

[2]  H. Lee,et al.  Effect of CNT Agglomeration on the Electrical Conductivity and Percolation Threshold of Nanocomposites: A Micromechanics-based Approach , 2014 .

[3]  Bodo Fiedler,et al.  FUNDAMENTAL ASPECTS OF NANO-REINFORCED COMPOSITES , 2006 .

[4]  Nemkumar Banthia,et al.  Cement-based sensors with carbon fibers and carbon nanotubes for piezoresistive sensing , 2012 .

[5]  Z. Zhong,et al.  A frequency-dependent theory of electrical conductivity and dielectric permittivity for graphene-polymer nanocomposites , 2017 .

[6]  H. Toutanji,et al.  The influence of silica fume on the compressive strength of cement paste and mortar , 1995 .

[7]  Jingyao Cao,et al.  ELECTRIC POLARIZATION AND DEPOLARIZATION IN CEMENT-BASED MATERIALS, STUDIED BY APPARENT ELECTRICAL RESISTANCE MEASUREMENT , 2004 .

[8]  Gangbing Song,et al.  Smart aggregates: multi-functional sensors for concrete structures—a tutorial and a review , 2008 .

[9]  C. Nan,et al.  Effective thermal conductivity of particulate composites with interfacial thermal resistance , 1997 .

[10]  Mustafa Şahmaran,et al.  Effect of mixing methods on the electrical properties of cementitious composites incorporating different carbon-based materials , 2016 .

[11]  J. Jang,et al.  Heavy Metal Leaching, CO2 Uptake and Mechanical Characteristics of Carbonated Porous Concrete with Alkali-Activated Slag and Bottom Ash , 2015, International Journal of Concrete Structures and Materials.

[12]  Jordi Payá,et al.  Use of sewage sludge ash(SSA)-cement admixtures in mortars , 1996 .

[13]  M. F. Kotkata,et al.  Electrical conductivity of concrete containing silica fume , 1995 .

[14]  T. Salem,et al.  Electrical conductivity of granulated slag–cement kiln dust–silica fume pastes at different porosities , 2001 .

[15]  U. Helbig,et al.  Amorphous silica in ultra-high performance concrete: First hour of hydration , 2014 .

[16]  A. Chaipanich,et al.  Compressive strength and microstructure of carbon nanotubes–fly ash cement composites , 2010 .

[17]  Yang Wang,et al.  A continuum model with a percolation threshold and tunneling-assisted interfacial conductivity for carbon nanotube-based nanocomposites , 2014 .

[18]  Rashid K. Abu Al-Rub,et al.  Carbon Nanotubes and Carbon Nanofibers for Enhancing the Mechanical Properties of Nanocomposite Cementitious Materials , 2011 .

[19]  Eil Kwon,et al.  Electrical characteristics and pressure-sensitive response measurements of carboxyl MWNT/cement composites , 2012 .

[20]  Yan‐Bing He,et al.  “Concrete” inspired construction of a silicon/carbon hybrid electrode for high performance lithium ion battery , 2015 .

[21]  Mohamed Lachemi,et al.  Electrical percolation threshold of cementitious composites possessing self-sensing functionality incorporating different carbon-based materials , 2016 .

[22]  C. Marsh,et al.  Effects of silica additives on fracture properties of carbon nanotube and carbon fiber reinforced Portland cement mortar , 2015 .

[23]  K. Tanaka,et al.  Average stress in matrix and average elastic energy of materials with misfitting inclusions , 1973 .

[24]  G. Weng,et al.  A theoretical treatment of graphene nanocomposites with percolation threshold, tunneling-assisted conductivity and microcapacitor effect in AC and DC electrical settings , 2016 .

[25]  S. Kim,et al.  A probabilistic micromechanical modeling for electrical properties of nanocomposites with multi-walled carbon nanotube morphology , 2017 .

[26]  B. Karihaloo,et al.  Effective thermal conductivities of heterogeneous media containing multiple imperfectly bonded inclusions , 2007 .

[27]  Haeng-Ki Lee,et al.  Enhanced effect of carbon nanotube on mechanical and electrical properties of cement composites by incorporation of silica fume , 2014 .

[28]  Jinping Ou,et al.  Review of nanocarbon-engineered multifunctional cementitious composites , 2015 .

[29]  Michael McDonald,et al.  Fundamentals of Modern Manufacturing: Materials, Processes and Systems , 2016 .

[30]  Govind,et al.  Multiwalled carbon nanotube/cement composites with exceptional electromagnetic interference shielding properties , 2013 .

[31]  A. Hamouda,et al.  Percolation threshold and electrical conductivity of a two-phase composite containing randomly oriented ellipsoidal inclusions , 2011 .

[32]  X. B. Zhang,et al.  Catalyst traces and other impurities in chemically purified carbon nanotubes grown by CVD , 2002 .

[33]  H. Wagner,et al.  The role of surfactants in dispersion of carbon nanotubes. , 2006, Advances in colloid and interface science.

[34]  Francis Gerard Collins,et al.  The influences of admixtures on the dispersion, workability, and strength of carbon nanotube-OPC paste mixtures , 2012 .

[35]  Vaclav Smil,et al.  Making the Modern World: Materials and Dematerialization , 2013 .

[36]  A. Chaipanich,et al.  Behavior of multi-walled carbon nanotubes on the porosity and microstructure of cement-based materials , 2011 .

[37]  J. Ju,et al.  Effects of CNT waviness on the effective elastic responses of CNT-reinforced polymer composites , 2013 .

[38]  Haeng-Ki Lee,et al.  Electromagnetic Characteristics of Cement Matrix Materials with Carbon Nanotubes , 2012 .

[39]  G. Weng A dynamical theory for the Mori–Tanaka and Ponte Castañeda–Willis estimates , 2010 .

[40]  H. Lee,et al.  The electrically conductive carbon nanotube (CNT)/cement composites for accelerated curing and thermal cracking reduction , 2016 .

[41]  J. Knowles,et al.  Effect of porosity reduction by compaction on compressive strength and microstructure of calcium phosphate cement. , 2002, Journal of biomedical materials research.

[42]  Habeom Lee,et al.  Heating and heat-dependent mechanical characteristics of CNT-embedded cementitious composites , 2016 .

[43]  R. Feldman,et al.  Properties of portland cement-silica fume pastes I. Porosity and surface properties , 1985 .

[44]  Seunghwa Ryu,et al.  An analytical model to predict curvature effects of the carbon nanotube on the overall behavior of nanocomposites , 2014 .