A study on the photoresponse of three-dimensional reduced graphene oxide foams based field effect transistors

Graphene is a new type of two-dimensional (2D) nanomaterial composed of single-layer carbon atoms. It has high carrier mobility, good optical performance, good mechanical performance and thermal conductivity. Three-dimensional (3D) reduce graphene oxide (rGO) foam integrates the structure of 2D graphene with three-dimensional network connected structure of carbon nanomaterials, which is in a seamless connection possessing better optical and electrical properties. 3D GF has achieved some results in solar cells and supercapacitors, however, field effect transistors are rarely studied. In this paper, a kind of field effect transistor (FET) based on 3D rGO foam has been fabricated and its photoelectric response characteristics have been studied. The results show that an obvious photocurrent could be measured when the laser irradiate on the 3D rGO foams channel. The magnitude of the photocurrent can be effectively modulated by the back-gate voltage. The device exhibits a “V” shape transfer curves and stabile and reproducible photocurrent cycles. Particularly, a high photoresponsivity of 7.8 mA W-1 is achieved, which reveals 3D rGO foams a good candidate for photodetectors.

[1]  N. G. Tassi,et al.  High performance transparent conductor of graphene wrapped copper/nickel microgrids , 2014 .

[2]  Won Chul Lee,et al.  Graphene-templated directional growth of an inorganic nanowire. , 2015, Nature nanotechnology.

[3]  Yi Shi,et al.  Planar carbon nanotube–graphene hybrid films for high-performance broadband photodetectors , 2015, Nature Communications.

[4]  F. Guinea,et al.  The electronic properties of graphene , 2007, Reviews of Modern Physics.

[5]  Qi-Ye Wen,et al.  High-speed and broadband terahertz wave modulators based on large-area graphene field-effect transistors. , 2014, Optics letters.

[6]  Francisco del Monte,et al.  Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene: synthesis and applications. , 2013, Chemical Society reviews.

[7]  Harald Schneider,et al.  Ultrafast graphene-based broadband THz detector , 2013 .

[8]  F. Xia,et al.  Ultrafast graphene photodetector , 2009, CLEO/QELS: 2010 Laser Science to Photonic Applications.

[9]  P. Avouris,et al.  Increased responsivity of suspended graphene photodetectors. , 2013, Nano letters.

[10]  J. Viljas,et al.  Electron-phonon heat transfer in monolayer and bilayer graphene , 2010, 1002.3502.

[11]  Zhang Zhang,et al.  Broadband Phototransistor Based on CH3NH3PbI3 Perovskite and PbSe Quantum Dot Heterojunction. , 2017, The journal of physical chemistry letters.

[12]  Yongsheng Chen,et al.  Three-dimensional graphene networks: synthesis, properties and applications , 2015 .

[13]  Aaron M. Jones,et al.  Ultrafast hot-carrier-dominated photocurrent in graphene. , 2012, Nature nanotechnology.

[14]  Z. Yin,et al.  Three-dimensional graphene materials: preparation, structures and application in supercapacitors , 2014 .

[15]  S. B. Krupanidhi,et al.  Infrared Photodetectors Based on Reduced Graphene Oxide and Graphene Nanoribbons , 2011, Advanced materials.

[16]  Ke Xu,et al.  High-responsivity graphene/silicon-heterostructure waveguide photodetectors , 2013, Nature Photonics.

[17]  R. Ruoff,et al.  Graphene and Graphene Oxide: Synthesis, Properties, and Applications , 2010, Advanced materials.

[18]  Jianquan Yao,et al.  Highly Photosensitive Vertical Phototransistors Based on a Poly(3-hexylthiophene) and PbS Quantum Dot Layered Heterojunction , 2017 .

[19]  P. Avouris,et al.  Photodetectors based on graphene, other two-dimensional materials and hybrid systems. , 2014, Nature nanotechnology.

[20]  Tengfei Zhang,et al.  Broadband and Tunable High‐Performance Microwave Absorption of an Ultralight and Highly Compressible Graphene Foam , 2015, Advanced materials.

[21]  Zhang Chunyu,et al.  Highly Selective and Sensitive Determination of Dopamine in the Presence of Ascorbic Acid Using a 3D Graphene Foam Electrode , 2014 .

[22]  H. Miura,et al.  Fabrication of 3D graphene foam for a highly conducting electrode , 2017 .

[23]  P. Ajayan,et al.  Graphene-Based Standalone Solar Energy Converter for Water Desalination and Purification. , 2018, ACS nano.

[24]  Xingcheng Xiao,et al.  A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment , 2014 .

[25]  Jianquan Yao,et al.  PbS-Decorated WS2 Phototransistors with Fast Response , 2017 .