A Multipurpose Portable Instrument for Determining Ripeness in Wine Grapes Using NIR Spectroscopy

This paper describes the development of a noninvasive instrument that is designed to measure three parameters of ripeness in wine grapes, i.e., sugar (Brix), pH, and anthocyanin concentration. The instrument is based on near-infrared spectroscopy, and it comes in contact with the berry in the cluster without altering its ripening process. A thorough description of the calibration process for the instrument is done for the different grape varieties, e.g., Cabernet Sauvignon, Carmenere, Merlot, Pinot Noir, and Chardonnay. Samples from vineyards located in the Maipo Valley (Chile) taken during the 2003 season were processed to develop calibration models using partial least squares techniques. The models were validated in terms of root mean square error of validation and R2 indices. The results show the great potential of this technique regarding Brix and pH measurements. For the anthocyanin concentration measurements, the results are promising but require an accurate procedure to obtain reference values for model calibration. The instrument can be useful for sampling strategies that look for optimum harvest schedules according to grape maturity in terms of not only sugar content but also pH and anthocyanin concentration.

[1]  Andrés Guesalaga,et al.  Shortwave–near infrared spectroscopy for non-destructive determination of maturity of wine grapes , 2003 .

[2]  T. Fearn,et al.  Near infrared spectroscopy in food analysis , 1986 .

[3]  J. Guthrie,et al.  Robustness of NIR Calibrations for Soluble Solids in Intact Melon and Pineapple , 1998 .

[4]  V. Ferreira,et al.  Evolution of Five Anthocyanidin-3-Glucosides in the Skin of the Tempranillo, Moristel, and Garnacha Grape Varieties and Influence of Climatological Variables , 1992 .

[5]  Shyam Narayan Jha,et al.  Non‐destructive determination of acid–brix ratio of tomato juice using near infrared spectroscopy , 2004 .

[6]  S. Kawano,et al.  Nondestructive Determination of Sugar Content in Satsuma Mandarin using Near Infrared (NIR) Transmittance , 1993 .

[7]  Rainer Künnemeyer,et al.  Internal Quality Assessment of Mandarin Fruit by vis/NIR Spectroscopy , 2003 .

[8]  R. Boulton,et al.  Principles and Practices of Winemaking , 1995 .

[9]  Fujitoshi Shinoki,et al.  Development of a Portable near Infrared Sugar-Measuring Instrument , 2002 .

[10]  Sumio Kawano,et al.  Improvement of PLS Calibration for Brix Value and Dry Matter of Mango Using Information from MLR Calibration , 2001 .

[11]  S. Kawano,et al.  Development of a Calibration Equation with Temperature Compensation for Determining the Brix Value in Intact Peaches , 1995 .

[12]  J. Rivas-Gonzalo,et al.  Comparisons of Methods for the Determination of Anthocyanins in Red Wines , 1992, American Journal of Enology and Viticulture.

[13]  Kerry B. Walsh,et al.  Non-invasive assessment of pineapple and mango fruit quality using near infra-red spectroscopy , 1997 .

[14]  S. Kawano,et al.  Determination of Sugar Content in Intact Peaches by Near Infrared Spectroscopy with Fiber Optics in Interactance Mode , 1992 .