Material flow analysis of polyethylene terephthalate in the US, 1996-2007

Abstract We present a material flow analysis (MFA) for polyethylene terephthalate (PET), a synthetic polymer, in the United States for the years 1996–2007. We model the industrial metabolism of PET as a network of flows linking stocks and processes. The most common worldwide use of PET is in textile production, but in the US it is increasingly used to make disposable beverage containers for transporting water, carbonated soda, and other beverages. Bottles made from PET are the most-recycled plastic product in the US by mass and by recovery rate, and thus the PET material flow system constitutes an ideal case study of polymer recycling. We find that total consumption of PET resin grew at 2.7% per year over the period of the study, reaching 5.01 million metric tons in 2007. This growth was driven largely by the beverage packaging market, which accounted for 55% of consumption in 2007. About a quarter of PET bottles are collected for recycling, a number that has fluctuated widely but kept pace with consumption. However, domestic capacity for reclamation of post-consumer PET has not grown as quickly, leading recyclers to export increasing amounts of post-consumer material. Manufacturers have also imported secondary PET in increasing amounts. Reclaimed PET accounted for 6–9% of total resin demand throughout the study. While polymer recycling appears to be viable, efforts to improve material efficiency are confounded by low collection rates and a lack of reclamation infrastructure.

[1]  Paul S Phillips,et al.  Life cycle assessment for reuse/recycling of donated waste textiles compared to use of virgin material: An UK energy saving perspective , 2006 .

[2]  Shuya A. Chang,et al.  Solid‐state polymerization of poly(ethylene terephthalate) , 1983 .

[3]  Tanya Domina,et al.  The Textile Waste Lifecycle , 1997 .

[4]  F. Hasan,et al.  Biological degradation of plastics: a comprehensive review. , 2008, Biotechnology advances.

[5]  Mariano Pracella,et al.  Characterization of scrap poly(ethylene terephthalate) , 2000 .

[6]  Prashant Chandran,et al.  Biaxial orientation of poly(ethylene terephthalate). Part I: Nature of the stress—strain curves , 1993 .

[7]  C. Moore Synthetic polymers in the marine environment: a rapidly increasing, long-term threat. , 2008, Environmental research.

[8]  Martin Kumar Patel,et al.  Plastics materials flow analysis for India , 2006 .

[9]  Sally K Francis,et al.  Market Applications for Recycled Postconsumer Fibers , 1999 .

[10]  Robert U. Ayres,et al.  accounting for resources, 1 , 1998 .

[11]  Ernst Worrell,et al.  Recycling of plastics in Germany , 2000 .

[12]  Paul H. Brunner,et al.  Setting priorities in plastic waste management : lessons learned from material flow analysis in Austria and Poland , 2006 .

[13]  J. E. Mark,et al.  Physical properties of polymers handbook , 2007 .

[14]  Roland Clift,et al.  Time-dependent material flow analysis of iron and steel in the UK: Part 1: Production and consumption trends 1970-2000 , 2007 .

[15]  E. M. Aizenshtein Polyester fibres continue to dominate on the world textile raw materials balance sheet , 2009 .

[16]  T. Spychaj,et al.  Chemical Recycling of Poly(ethylene terephthalate) , 1997 .

[17]  Bernard Boutevin,et al.  Study of thermal and mechanical properties of virgin and recycled poly(ethylene terephthalate) before and after injection molding , 2000 .

[18]  A. Mamizadeh,et al.  Recycling PET beverage bottles and improving properties , 2004 .

[19]  Edward Kosior,et al.  Recycled poly(ethylene terephthalate) chain extension by a reactive extrusion process , 2004 .

[20]  Firas Awaja,et al.  Recycling of PET , 2005 .

[21]  B. Culbert,et al.  Continuous Solid‐State Polycondensation of Polyesters , 2004 .

[22]  Ernst Worrell,et al.  Plastics streams in Germany : an analysis of production, consumption and waste generation , 1998 .

[23]  Timothy E. Long,et al.  Modern polyesters : chemistry and technology of polyesters and copolyesters , 2004 .

[24]  Laxmikant S. Jawale,et al.  Recycling of waste PET into useful textile auxiliaries. , 2008, Waste management.

[25]  Loredana Incarnato,et al.  Structure and rheology of recycled PET modified by reactive extrusion , 2000 .

[26]  Robert A. Bubeck,et al.  Injection Blow Molding Technology for Polyethylene Terephthalate , 2000 .

[27]  J. Derraik The pollution of the marine environment by plastic debris: a review. , 2002, Marine pollution bulletin.

[28]  Saleh A. Jabarin,et al.  Solid-state polymerization of poly(ethylene terephthalate). I. Experimental study of the reaction kinetics and properties , 2003 .

[29]  Ernst Worrell,et al.  Assessment of the plastic flows in The Netherlands using STREAMS , 2000 .

[30]  P. M Subramanian,et al.  Plastics recycling and waste management in the US , 2000 .

[31]  R. Kleijn,et al.  Dynamic substance flow analysis: the delaying mechanism of stocks, with the case of PVC in Sweden , 2000 .

[32]  G. Reese Polyester Fibers: Fiber Formation and End‐Use Applications , 2004 .