Effect of Sulfur Content on the Inclusion and Mechanical Properties in Ce-Mg Treated Resulfurized SCr420H Steel

To clarify the effect of sulfur on inclusions and mechanical properties of Ce-Mg treated resulfurized SCr420H steel. Laboratory experiments were conducted to prepare steels with sulfur contents as 0.01%, 0.06%, and 0.132%. Inclusion evolution in liquid steel, MnS precipitation during solidification, and tensile test results of steel after quenching and tempering were investigated. The results showed that due to the limitation of mass transfer in molten steel, composite inclusion that Ce-O-S wrapped by Ce-Ca-Mg-Al-Si-O, which was named transition state inclusions, can form quickly after adding Ce-Mg lump to the molten steel. As the homogenization of molten steel, the difference of sulfur content in steel can lead to the transition state inclusions transformed into different inclusions. With the increase of sulfur content, the quantity of MnS increased significantly, and the morphology of MnS transformed from “stick” to “dendritic + fishbone”, and then to “fishbone”. Tensile test results and fracture analysis indicate that the decline of inclusion spacing as the increase of sulfur content leads to a shorter physical path of crack propagation in steel. Therefore, the increase of sulfur content can bring about a decrease in the strength and plasticity of the steel. From the perspective of inclusion control, making the MnS inclusion precipitate more dispersive and increasing the distance between inclusions can be considered as a method for preventing the decline of mechanical properties in steel with high sulfur content.

[1]  G. Cheng,et al.  Refinement of Solidification Structure of H13 Steel by Rare Earth Sulfide , 2021, steel research international.

[2]  Wanlin Wang,et al.  In Situ Observation of the MnS Precipitation Behavior in High-Sulfur Microalloyed Steel Under Different Cooling Rates , 2020, Metallurgical and Materials Transactions B.

[3]  Zhao-dong Wang,et al.  Effect of Preheat Treatment on Microstructure and Properties of a Gear Steel for High‐Temperature Carburizing , 2020, steel research international.

[4]  Lifeng Zhang,et al.  Effect of Cerium Content on Inclusions in an Ultra-Low-Carbon Aluminum-Killed Steel , 2020, Metallurgical and Materials Transactions B.

[5]  M. X. Zhang,et al.  Grain Refinement Mechanism of the δ-Ferrite in Steels Through Cerium Addition , 2020, Metallurgical and Materials Transactions A.

[6]  Yin Zhang,et al.  Inclusion Characteristics in 95CrMo Steels with Different Calcium and Sulfur Contents , 2020, Materials.

[7]  B. Song,et al.  Effect of Mg on the Evolution of Inclusions and Formation of Acicular Ferrite in La–Ti‐Treated Steels , 2020, steel research international.

[8]  J. Xie,et al.  Inclusions modification and improvement of machinability in a non-quenched and tempered steel with Mg treatment , 2020, Metallurgical Research & Technology.

[9]  L. Xing,et al.  Evolution Mechanism of Inclusions in H13 Steel with Rare Earth Magnesium Alloy Addition , 2019, ISIJ International.

[10]  Zhou-hua Jiang,et al.  Effect of Ultra-high Magnesium on SKS51 Liquid Steel Cleanliness and Microstructure , 2019, ISIJ International.

[11]  Zhao-dong Wang,et al.  Suppression of Austenite Grain Coarsening by Using Nb–Ti Microalloying in High Temperature Carburizing of a Gear Steel , 2019, Advanced Engineering Materials.

[12]  Zhou-hua Jiang,et al.  Effect of Rare Earth–Magnesium Alloy on Inclusion Evolution in Industrial Production of Die Steel , 2019, steel research international.

[13]  Jian-xun Fu,et al.  Morphology Study on Inclusion Modifications Using Mg–Ca Treatment in Resulfurized Special Steel , 2019, Materials.

[14]  Yiyi Li,et al.  Very high cycle fatigue properties of bearing steel with different aluminum and sulfur content , 2018, International Journal of Fatigue.

[15]  Mingxing Zhang,et al.  Roles of Lanthanum and Cerium in Grain Refinement of Steels during Solidification , 2018, Metals.

[16]  G. Cheng,et al.  Effect of Cerium on the Behavior of Inclusions in H13 Steel , 2018, steel research international.

[17]  Jian-xun Fu,et al.  Exploration of morphology evolution of the inclusions in Mg-treated 16MnCrS5 steel , 2018, Ironmaking & Steelmaking.

[18]  Lijun Wang,et al.  The Formation and Growth of Sulfides in Free‐Cutting Stainless Steel , 2018, steel research international.

[19]  W. Hwang,et al.  Effects of Mg-Al-O-Mn-S inclusion on the nucleation of acicular ferrite in magnesium-containing low-carbon steel , 2018, Materials Characterization.

[20]  G. Cheng,et al.  Modification Mechanism of Cerium on the Inclusions in Drill Steel , 2018 .

[21]  J. Shin,et al.  Formation Mechanism of Oxide-Sulfide Complex Inclusions in High-Sulfur-Containing Steel Melts , 2018, Metallurgical and Materials Transactions B.

[22]  Cheng-bin Shi,et al.  Effect of Magnesium Addition on Behavior of Collision and Agglomeration between Solid Inclusion Particles on H13 Steel Melts , 2017 .

[23]  H. Wang,et al.  Evolution of Al2O3 inclusions by magnesium treatment in H13 hot work die steel , 2017 .

[24]  A. Karasev,et al.  The Influence of Microstructure and Non‐Metallic Inclusions on the Machinability of Clean Steels , 2017 .

[25]  Xinhua Wang,et al.  The Effect of Refining Slag and Refractory on Inclusion Transformation in Extra Low Oxygen Steels , 2016, Metallurgical and Materials Transactions B.

[26]  P. Jönsson,et al.  Effect of Si and Ce Contents on the Nozzle Clogging in a REM Alloyed Stainless Steel , 2015 .

[27]  Hong Wang,et al.  Evolution of inclusions and change of as-cast microstructure with Mg addition in high carbon and high chromium die steel , 2015 .

[28]  D. Z. Li,et al.  Effects of Rare Earth on the Microstructure and Impact Toughness of H13 Steel , 2015 .

[29]  J. Maciejewski The Effects of Sulfide Inclusions on Mechanical Properties and Failures of Steel Components , 2015, Journal of Failure Analysis and Prevention.

[30]  A. Karasev,et al.  The Effect of Different Non-Metallic Inclusions on the Machinability of Steels , 2015, Materials.

[31]  S. Song,et al.  Enhanced hot ductility of a Cr–Mo low alloy steel by rare earth cerium , 2014 .

[32]  N. Heo,et al.  Correlation Between MnS Precipitation, Sulfur Segregation Kinetics, and Hot Ductility in C-Mn Steel , 2014, Metallurgical and Materials Transactions A.

[33]  A. Saatchi,et al.  Effect of cerium and lanthanum on the microstructure and mechanical properties of AISI D2 tool steel , 2013 .

[34]  Miao‐yong Zhu,et al.  Evolution Mechanism of Non-metallic Inclusions in Al-Killed Alloyed Steel during Secondary Refining Process , 2013 .

[35]  Ken-ichi Yamamoto,et al.  Behavior of Non-metallic Inclusions in Steel during Hot Deformation and the Effects of Deformed Inclusions on Local Ductility , 2011 .

[36]  B. Song,et al.  Effect of austenitizing temperature on microstructure in 16Mn steel treated by cerium , 2011 .

[37]  S. Hang,et al.  STUDY OF THE EFFECT OF SULFUR CONTENTS ON FRACTURE TOUGHNESS OF RAILWAY WHEEL STEELS FOR HIGH SPEED TRAIN , 2011 .

[38]  Xinhua Wang,et al.  Laboratory Study on Evolution Mechanisms of Non-metallic Inclusions in High Strength Alloyed Steel Refined by High Basicity Slag , 2010 .

[39]  W. Garrison,et al.  The effect of sulfide type on the fracture behavior of HY180 steel , 2005 .

[40]  H. Todoroki,et al.  Effects of Al and Ca in ferrosilicon alloys for deoxidation on inclusion composition in type 304 stainless steel , 2001 .

[41]  O. Wijk,et al.  The Purity of Ferrosilicon and Its Influence on Inclusion Cleanliness of Steel , 1996 .

[42]  K. Ishida,et al.  The Control of the Morphology of MnS Inclusions in Steel during Solidification , 1995 .

[43]  Neville Reid Moody,et al.  A comparison of the fracture behavior of two heats of the secondary hardening steel AF1410 , 1989 .

[44]  T. Gladman,et al.  Sulphide shape control , 1979 .

[45]  W. Dahl,et al.  Einfluß sehr niedriger Schwefelgehalte auf die mechanischen Eigenschaften des Stahles St 52-3 , 1973 .

[46]  A. Mclean,et al.  Sulfide shape control in high strength low alloy steels , 1970, Metallurgical and Materials Transactions B.

[47]  J. Mathews Upon the constitution of binary alloys , 1902 .