3-(3-Chlorobenzyl)-1H-isochromen-1-one

The asymmetric unit of the title compound, C16H11ClO2, a chemically synthesized isocoumarin, contains three independent molecules. The benzopyran and benzene rings are approximately perpendicular to each other, forming dihedral angles ranging from 83.08 (14) to 87.43 (11)°. In the crystal structure, molecules are linked by intermolecular C—H⋯O hydrogen-bonding interactions, forming chains running parallel to the a axis.

[1]  良二 上田 J. Appl. Cryst.の発刊に際して , 1970 .

[2]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.