Heavy oil upgrading: Unlocking the future fuel supply

ABSTRACT Currently, more than half of the oil reserves (53.3%) in the world are in the form of restorable oils such as heavy oil, extra heavy oil, oil sand, tar sands, oil shale, and bitumen. Heavy oil is one of the petroleum oil varieties that contain long chain hydrocarbons. All types of heavy oils contain asphaltenes and thus are considered very dense substances. The asphaltenes are one of the most complex and heavy organic compounds present in the heavy oil. The heavy oil is defined as one having an American Petroleum Institute scale index equal or smaller than 20°. In conventional refining procedures, heavy oil poses many challenges. Recycling and re-refining are applied techniques for the processing of petroleum based heavy oils into reusable light oils such as gasoline and diesel fuel. In this regard, catalytic pyrolysis and thermal cracking are promising technologies for light oil production. The authors review the heavy oil upgrading processes and their associated challenges with ambition to find cost-effective ways to ensure a constant future fuel supply.

[1]  J. Speight,et al.  Desulfurization of heavy oils and residua , 1981 .

[2]  A. Demirbaş Pyrolytic Distillation of No. 4 Fuel Oil , 2015 .

[3]  Sharangouda J. Patil,et al.  A New Modified Compositional Viscosity Model for Medium-heavy Oils , 2013 .

[4]  M. Emadi,et al.  Foamy Oil Behavior of an Iranian Heavy Oil Reservoir , 2015 .

[5]  James G. Speight,et al.  Petroleum refining processes , 2002 .

[6]  J. G. Meijer,et al.  Influence of Temperature and Pressure on Asphaltene Flocculation , 1984 .

[7]  J. Speight The Chemistry and Technology of Petroleum , 1980 .

[8]  R. Wang,et al.  The Treatment of Refinery Heavy Oil Sludge , 2013 .

[9]  A. Demirbas,et al.  API Gravity, Sulfur Content, and Desulfurization of Crude Oil , 2015 .

[10]  Toshimitsu Suzuki,et al.  Chemical structure of tar-sand bitumens by 13C and 1H n.m.r. spectroscopic methods , 1982 .

[11]  Qinglin Chen,et al.  MODELING FOR PRODUCT DISTRIBUTION IN THERMAL CONVERSION OF HEAVY OIL , 2002 .

[12]  Ayban Demirbas RECOVERY OF ASPHALTENES FROM TAR SAND BY SUPERCRITICAL FLUID EXTRACTION , 2000 .

[13]  O. V. Trevisan,et al.  Brazilian Journal of Chemical Engineering AN OVERVIEW OF HEAVY OIL PROPERTIES AND ITS RECOVERY AND TRANSPORTATION METHODS , 2014 .

[14]  D. K. Sharma,et al.  Emerging Role of Biorefining of Heavier Crude Oils and Integration of Biorefining with Petroleum Refineries in the Future , 2006 .

[15]  H. Shui,et al.  STUDY ON THE STRUCTURE OF HEAVY OILS , 1997 .

[17]  G. Jensen,et al.  A review of the chemistry for catalytic cracking of heavy oils , 1999 .

[18]  James G. Speight,et al.  Handbook of Petroleum Analysis , 2001 .

[19]  E. Behrens Investigation of loss of surfactants during enhanced oil recovery applications - adsorption of surfactants onto clay materials , 2013 .

[20]  A. Demirbaş Asphaltene yields from five types of fuels via different methods , 2002 .

[21]  K. F. Chasib,et al.  An Investigation on the Feasibility of Simulating the Distillation Curves and ASTM Distillation Temperature , 2017 .

[22]  L. Zhou,et al.  Kinetic Model of Heavy Paraffins Dehydrogenation , 2015 .

[23]  B. Shen,et al.  Refining Tahe Heavy Crude Oil to Increase Light Product Yield , 2015 .

[24]  I. Wiehe TWO-DIMENSIONAL SOLUBILITY PARAMETER MAPPING OF HEAVY OILS , 1996 .

[25]  Jinsen Gao,et al.  Production of Light Olefins by Catalytic Pyrolysis of Heavy Oil , 2006 .

[26]  Biological Treatment of Wastewater from Heavy Oil Recovery , 2014 .

[27]  H. Weng,et al.  Molecular Reconstruction of Crude Oil , 2013 .

[29]  G. Mansoori,et al.  An analysis of methods for determination of onsets of asphaltene phase separations , 2004 .

[30]  P. M. Spiecker,et al.  Effects of petroleum resins on asphaltene aggregation and water-in-oil emulsion formation , 2003 .

[31]  M. Yuan,et al.  Upgrading Heavy Oil Using Syngas as the Hydrogen Source with Dispersed Catalysts , 2009 .

[32]  Amir Naser Akhavan,et al.  A Design Integrated Model in Strategy Management for Upgrading Heavy Oils , 2014 .

[33]  S. A. Mousavi-Dehghania,et al.  An analysis of methods for determination of onsets of asphaltene phase separations , 2004 .

[34]  Z. Wu,et al.  Characteristics and Evaluation of Extremely Shallow Oil Sand in a Heavy Oil Reservoir , 2015 .