Surface integrity of biodegradable Magnesium-Calcium orthopedic implant by burnishing.

Magnesium-Calcium (MgCa) alloy as an emerging biodegradable implant material has received considerable attention in orthopedic fixation applications. The biodegradable MgCa alloys avoid stress shielding and secondary surgery inherent with permanent metallic implant materials. They also provide sufficient mechanical strength in load carrying applications as opposed to biopolymers. However, the key issue facing a biodegradable MgCa implant is the fast corrosion in the human body environment. The ability to adjust the degradation rate of MgCa alloys is critical in the successful development of biodegradable orthopedic materials. Burnishing as a low plastic deformation process is a promising technique to tune surface integrity of MgCa implant surface for biodegradation control. However, the poor ductility of MgCa alloys imposes a great challenge for burnishing. This study focuses on the basic understanding of surface mechanical behavior of burnished biodegradable MgCa0.8 (wt%) alloy. The effects of burnishing parameters, i.e., pressure, feed, speed, number of path, and burnishing pattern on surface integrity factors such as surface topography, roughness, microhardness, microstructure, and residual stresses are investigated. The burnished surfaces are shinier and smoother than the as-machined ones. The MgCa alloy can be safely burnished at suitable burnishing conditions since no cracks are produced at the surface and in the subsurface. The microstructure including grain size does not show a noticeable change after burnishing. The machined surfaces are harder than the burnished ones down to the deep subsurface (∼200 μm) as opposed to the shallow hardened depth (∼50 μm) in cutting. Residual stresses are highly compressive especially at low burnishing pressure.

[1]  Helmut Sigel,et al.  Handbook on toxicity of inorganic compounds , 1990 .

[2]  B. Denkena,et al.  Influence of Different Surface Machining Treatments of Magnesium‐based Resorbable Implants on the Degradation Behavior in Rabbits , 2009 .

[3]  U. N. Kempaiah,et al.  Investigations on the Effect of Ball Burnishing Parameters on Surface Hardness and Wear Resistance of HSLA Dual-Phase Steels , 2008 .

[4]  L. N. López de Lacalle,et al.  The effect of ball burnishing on heat-treated steel and Inconel 718 milled surfaces , 2007 .

[5]  Yufeng Zheng,et al.  The development of binary Mg-Ca alloys for use as biodegradable materials within bone. , 2008, Biomaterials.

[6]  Yuebin Guo,et al.  Process mechanics and surface integrity by high-speed dry milling of biodegradable magnesium–calcium implant alloys , 2010 .

[7]  Berend Denkena,et al.  Degradable implants made of magnesium alloys , 2005 .

[8]  P. K. Brahmankar,et al.  Low Plasticity Burnishing: An Innovative Manufacturing Method for Biomedical Applications , 2008 .

[9]  H. Haferkamp,et al.  In vivo corrosion of four magnesium alloys and the associated bone response. , 2005, Biomaterials.

[10]  A. Gefen,et al.  Computational simulations of stress shielding and bone resorption around existing and computer-designed orthopaedic screws , 2002, Medical and Biological Engineering and Computing.

[11]  G. Song,et al.  The Effect of Pre‐Processing and Grain Structure on the Bio‐Corrosion and Fatigue Resistance of Magnesium Alloy AZ31 , 2007 .

[12]  I. Nikitin,et al.  Comparison of the fatigue behavior and residual stress stability of laser-shock peened and deep rolled austenitic stainless steel AISI 304 in the temperature range 25–600 °C , 2007 .

[13]  T. Takasugi,et al.  Effect of combined plasma-carburizing and deep-rolling on notch fatigue property of Ti-6Al-4V alloy , 2009 .

[14]  Berend Denkena,et al.  Development of Combined Manufacturing Technologies for High-Strength Structure Components , 2007 .

[15]  Douglas J. Hornbach,et al.  Safe Life Conversion of Aircraft Aluminum Structures via Low Plasticity Burnishing for Mitigation of Corrosion Related Failures , 2009 .

[16]  J. Kerstetter,et al.  Nutrition in Bone Health Revisited: A Story Beyond Calcium , 2000, Journal of the American College of Nutrition.

[17]  M. Besel,et al.  Residual stress relaxation of deep-rolled austenitic steel , 2008 .

[18]  Philip J. Withers,et al.  Shakedown of deep cold rolling residual stresses in titanium alloys , 2008 .

[19]  A Haverich,et al.  Left main coronary artery fistula exiting into the right atrium , 2003, Heart.

[20]  Ekkard Brinksmeier,et al.  Cold surface hardening , 2008 .

[21]  P. Prevéy,et al.  Controlled Plasticity Burnishing to Improve the Performance of Friction Stir Processed Ni-Al Bronze , 2007 .

[22]  Berend Denkena,et al.  Advancing Cutting Technology , 2003 .

[23]  I. Nikitin,et al.  Correlation between residual stress and plastic strain amplitude during low cycle fatigue of mechanically surface treated austenitic stainless steel AISI 304 and ferritic-pearlitic steel SAE 1045 , 2008 .

[24]  Paul S. Prevéy,et al.  Case Studies of Fatigue Life Improvement Using Low Plasticity Burnishing in Gas Turbine Engine Applications , 2005 .

[25]  Berend Denkena,et al.  Biocompatible Magnesium Alloys as Absorbable Implant Materials – Adjusted Surface and Subsurface Properties by Machining Processes , 2007 .

[26]  I. Altenberger,et al.  Effective boundary of deep-rolling treatment and its correlation with residual stress stability of Al–Mg–Mn and Al–Mg–Si–Cu alloys , 2007 .

[27]  Alexander Schuh,et al.  Deep rolling of titanium rods for application in modular total hip arthroplasty. , 2007, Journal of biomedical materials research. Part B, Applied biomaterials.

[28]  P. K. Brahmankar,et al.  Investigations on surface integrity of AISI 1045 using LPB tool , 2008 .

[29]  B. Aksakal,et al.  Bioceramic dip-coating on Ti–6Al–4V and 316L SS implant materials , 2008, Journal of materials science. Materials in medicine.

[30]  G. Tang,et al.  Influence of heat treatment on degradation behavior of bio-degradable die-cast AZ63 magnesium alloy in simulated body fluid , 2007 .

[31]  Guang-Ling Song,et al.  Control of biodegradation of biocompatable magnesium alloys , 2007 .

[32]  T. Takasugi,et al.  Evaluation of surface-modified Ti–6Al–4V alloy by combination of plasma-carburizing and deep-rolling , 2008 .

[33]  Shizhe Song,et al.  A Possible Biodegradable Magnesium Implant Material , 2007 .

[34]  Jochem Nagels,et al.  Stress shielding and bone resorption in shoulder arthroplasty. , 2003, Journal of shoulder and elbow surgery.

[35]  John T. Cammett,et al.  The Influence of Surface Enhancement by Low Plasticity Burnishing on the Corrosion Fatigue Performance of AA7075-T6 , 2004 .

[36]  J. Simões,et al.  Strain shielding in proximal tibia of stemmed knee prosthesis: experimental study. , 2008, Journal of biomechanics.

[37]  N. Gindy,et al.  Comparative experimental study on effects of conventional and ultrasonic deep cold rolling processes on Ti–6Al–4V , 2008 .

[38]  N. Jayaraman,et al.  Mitigation of Fatigue and Pre-Cracking Damage in Aircraft Structures Through Low Plasticity Burnishing (LPB) , 2007 .

[39]  A. Amirfazli,et al.  Contribution of loading conditions and material properties to stress shielding near the tibial component of total knee replacements. , 2007, Journal of biomechanics.