BEOL compatible high tunnel magneto resistance perpendicular magnetic tunnel junctions using a sacrificial Mg layer as CoFeB free layer cap

Perpendicularly magnetized MgO-based tunnel junctions are envisaged for future generation spin-torque transfer magnetoresistive random access memory devices. Achieving a high tunnel magneto resistance and preserving it together with the perpendicular magnetic anisotropy during BEOL CMOS processing are key challenges to overcome. The industry standard technique to deposit the CoFeB/MgO/CoFeB tunnel junctions is physical vapor deposition. In this letter, we report on the use of an ultrathin Mg layer as free layer cap to protect the CoFeB free layer from sputtering induced damage during the Ta electrode deposition. When Ta is deposited directly on CoFeB, a fraction of the surface of the CoFeB is sputtered even when Ta is deposited with very low deposition rates. When depositing a thin Mg layer prior to Ta deposition, the sputtering of CoFeB is prevented. The ultra-thin Mg layer is sputtered completely after Ta deposition. Therefore, the Mg acts as a sacrificial layer that protects the CoFeB from sputter-indu...

[1]  J. Nowak,et al.  Spin torque switching of perpendicular Ta∣CoFeB∣MgO-based magnetic tunnel junctions , 2011 .

[2]  K. Tsunekawa,et al.  Crystallization of Amorphous CoFeB Ferromagnetic Layers in CoFeB/MgO/CoFeB Magnetic Tunnel Junctions , 2007 .

[3]  T. Liu,et al.  Thermally robust Mo/CoFeB/MgO trilayers with strong perpendicular magnetic anisotropy , 2014, Scientific Reports.

[4]  Seung H. Kang,et al.  Scalable and thermally robust perpendicular magnetic tunnel junctions for STT-MRAM , 2015 .

[5]  Y. Suzuki,et al.  Future prospects of MRAM technologies , 2013, 2013 IEEE International Electron Devices Meeting.

[6]  H. Ohno,et al.  Dependence of magnetic properties of MgO/CoFeB/Ta stacks on CoFeB and Ta thicknesses , 2015 .

[7]  T. Schulthess,et al.  Spin-dependent tunneling conductance of Fe | MgO | Fe sandwiches , 2001 .

[8]  S. Le,et al.  Perpendicular spin transfer torque magnetic random access memories with high spin torque efficiency and thermal stability for embedded applications (invited) , 2014 .

[9]  T. Devolder,et al.  Effect of Ta Insertion in Reference Layers of MTJs With Perpendicular Anisotropy , 2014, IEEE Transactions on Magnetics.

[10]  K. Tsunekawa,et al.  Influence of Chemical Composition of CoFeB on Tunneling Magnetoresistance and Microstructure in Polycrystalline CoFeB/MgO/CoFeB Magnetic Tunnel Junctions , 2006 .

[11]  G. Kar,et al.  Co/Ni based p-MTJ stack for sub-20nm high density stand alone and high performance embedded memory application , 2014, 2014 IEEE International Electron Devices Meeting.

[12]  P. L. Trouilloud,et al.  Magnetoresistance measurement of unpatterned magnetic tunnel junction wafers by current-in-plane tunneling , 2003 .