Recent advances in chemical modifications of graphene

Graphene has attracted the interest of chemists, physicists, and materials scientists due to its extraordinary structural, mechanical, and electronic properties. While pristine graphene is desirable for applications that require a high electrical conductivity, many other applications require modified or functionalized forms of graphene, such as graphene oxide, reduced graphene, or other functionalized forms. Structurally modifying graphene through chemical functionalization reveals the numerous possibilities for tuning its structure; several chemical and physical functionalization methods have been explored to improve the stabilization and modification of graphene. In this review, we report recent progress towards the chemical modification of graphene, including both covalent and noncovalent methods, for use in various applications.

[1]  A. Varykhalov,et al.  Graphene grown on Co(0001) films and islands: Electronic structure and its precise magnetization dependence , 2009 .

[2]  Qing Hua Wang,et al.  Evolution of physical and electronic structures of bilayer graphene upon chemical functionalization. , 2013, Journal of the American Chemical Society.

[3]  T. Fukutsuka,et al.  Silylation of graphite oxide , 2004 .

[4]  R. Ruoff,et al.  Chemical methods for the production of graphenes. , 2009, Nature nanotechnology.

[5]  N. Peres,et al.  Fine Structure Constant Defines Visual Transparency of Graphene , 2008, Science.

[6]  R. Young,et al.  The real graphene oxide revealed: stripping the oxidative debris from the graphene-like sheets. , 2011, Angewandte Chemie.

[7]  Marco Cecchini,et al.  Adsorption of Aromatic and Anti-Aromatic Systems on Graphene through π−π Stacking , 2010 .

[8]  V. Dravid,et al.  Graphene oxide as an enzyme inhibitor: modulation of activity of α-chymotrypsin. , 2011, Journal of the American Chemical Society.

[9]  Jiali Zhang,et al.  Reduction of graphene oxide via L-ascorbic acid. , 2010, Chemical communications.

[10]  L. Dai,et al.  Polyaniline-grafted reduced graphene oxide for efficient electrochemical supercapacitors. , 2012, ACS nano.

[11]  Steven Nutt,et al.  Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites , 2009 .

[12]  J. Tour,et al.  Mechanically Assisted Exfoliation and Functionalization of Thermally Converted Graphene Sheets , 2009 .

[13]  Jae-Young Choi,et al.  Efficient Reduction of Graphite Oxide by Sodium Borohydride and Its Effect on Electrical Conductance , 2009 .

[14]  A. Bourlinos,et al.  Organic functionalisation of graphenes. , 2010, Chemical communications.

[15]  Pengyuan Yang,et al.  Immobilization of trypsin on graphene oxide for microwave-assisted on-plate proteolysis combined with MALDI-MS analysis. , 2012, The Analyst.

[16]  Ashok Kumar,et al.  Comparative Study of Single-, Few-, and Multilayered Graphene toward Enzyme Conjugation and Electrochemical Response , 2012 .

[17]  L. Dai,et al.  Soluble P3HT-grafted graphene for efficient bilayer-heterojunction photovoltaic devices. , 2010, ACS nano.

[18]  Hao‐Bin Zhang,et al.  In situ chemical reduction and functionalization of graphene oxide for electrically conductive phenol formaldehyde composites , 2014 .

[19]  Jingyan Zhang,et al.  Assembly of graphene oxide-enzyme conjugates through hydrophobic interaction. , 2012, Small.

[20]  P. Bai,et al.  The Potential of Graphene as an ITO Replacement in Organic Solar Cells: An Optical Perspective , 2014, IEEE Journal of Selected Topics in Quantum Electronics.

[21]  Matteo Pasquali,et al.  Covalently interconnected three-dimensional graphene oxide solids. , 2013, ACS nano.

[22]  Gordon G. Wallace,et al.  Covalently linked biocompatible graphene/polycaprolactone composites for tissue engineering , 2013 .

[23]  Jianguo Tian,et al.  Porphyrin and fullerene covalently functionalized graphene hybrid materials with large nonlinear optical properties. , 2009, The journal of physical chemistry. B.

[24]  A. Hirsch,et al.  Wet chemical functionalization of graphene. , 2013, Accounts of chemical research.

[25]  Hui‐Ming Cheng,et al.  The Fabrication, Properties, and Uses of Graphene/Polymer Composites , 2012 .

[26]  Xuejiao Zhou,et al.  Individual nanocomposite sheets of chemically reduced graphene oxide and poly(N-vinyl pyrrolidone): preparation and humidity sensing characteristics , 2010 .

[27]  Yong Liu,et al.  Functionalization of Graphene Oxide with Polyhedral Oligomeric Silsesquioxane (POSS) for Multifunctional Applications. , 2012, The journal of physical chemistry letters.

[28]  Roberto Car,et al.  Functionalized single graphene sheets derived from splitting graphite oxide. , 2006, The journal of physical chemistry. B.

[29]  A. Reina,et al.  Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. , 2009, Nano letters.

[30]  F. Viñes,et al.  On the interaction of polycyclic aromatic compounds with graphene , 2012 .

[31]  Andre K. Geim,et al.  Electric Field Effect in Atomically Thin Carbon Films , 2004, Science.

[32]  K. Novoselov,et al.  A roadmap for graphene , 2012, Nature.

[33]  Colin L. Raston,et al.  Non-covalently modified graphene supported ultrafine nanoparticles of palladium for hydrogen gas sensing , 2013 .

[34]  Hanchang Shi,et al.  Hapten-grafted graphene as a transducer for homogeneous competitive immunoassay of small molecules. , 2014, Analytical chemistry.

[35]  M. Skaf,et al.  Noncovalent Interaction with Graphene Oxide: The Crucial Role of Oxidative Debris , 2014 .

[36]  Lei Chen,et al.  A design of gradient interphase reinforced by silanized graphene oxide and its effect on carbon fiber/epoxy interface , 2014 .

[37]  Nikhil K. Kothurkar,et al.  Synthesis, characterization and photoluminescence properties of graphene oxide functionalized with azo molecules , 2014, Journal of Chemical Sciences.

[38]  Sergey V. Morozov,et al.  Electronic properties of graphene , 2007 .

[39]  M. Prato,et al.  Functionalisation of carbon nanohorns. , 2006, Chemical communications.

[40]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[41]  William R. Dichtel,et al.  Multivalent binding motifs for the noncovalent functionalization of graphene. , 2011, Journal of the American Chemical Society.

[42]  Chongwu Zhou,et al.  Review of chemical vapor deposition of graphene and related applications. , 2013, Accounts of chemical research.

[43]  M. Chhowalla,et al.  A review of chemical vapour deposition of graphene on copper , 2011 .

[44]  Shangfeng Yang,et al.  Noncovalent functionalization of graphene attaching [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and application as electron extraction layer of polymer solar cells. , 2013, ACS nano.

[45]  S. Bose,et al.  Recent advances in graphene-based biosensors. , 2011, Biosensors & bioelectronics.

[46]  Huafeng Yang,et al.  Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement , 2009 .

[47]  Uday Narayan Maiti,et al.  Three‐Dimensional Shape Engineered, Interfacial Gelation of Reduced Graphene Oxide for High Rate, Large Capacity Supercapacitors , 2014, Advanced materials.

[48]  Yanli Zhao,et al.  Water-Soluble Pillararene-Functionalized Graphene Oxide for In Vitro Raman and Fluorescence Dual-Mode Imaging. , 2014, ChemPlusChem.

[49]  Yingyan Zhang,et al.  Mechanical properties of graphene : effects of layer number, temperature and isotope , 2013 .

[50]  J. Kysar,et al.  Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene , 2008, Science.

[51]  H. Salavagione,et al.  Graphene functionalisation with a conjugated poly(fluorene) by click coupling: striking electronic properties in solution. , 2012, Chemistry.

[52]  Zhiwei Xu,et al.  A facile method to produce graphene oxide-g-poly(L-lactic acid) as an promising reinforcement for PLLA nanocomposites , 2014 .

[53]  A. Bourlinos,et al.  Liquid-phase exfoliation of graphite towards solubilized graphenes. , 2009, Small.

[54]  Chun Li,et al.  Chemically converted graphene induced molecular flattening of 5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin and its application for optical detection of cadmium(II) ions. , 2009, Journal of the American Chemical Society.

[55]  S. Stankovich,et al.  Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide , 2007 .

[56]  Alexander A. Balandin,et al.  Heat conduction in graphene: experimental study and theoretical interpretation , 2009 .

[57]  S. Vasudevan,et al.  Covalently linked, water-dispersible, cyclodextrin: reduced-graphene oxide sheets. , 2012, Langmuir : the ACS journal of surfaces and colloids.

[58]  Klaus Müllen,et al.  Composites of Graphene with Large Aromatic Molecules , 2009 .

[59]  Anthony C. Coleman,et al.  One-pot functionalization of graphene with porphyrin through cycloaddition reactions. , 2011, Chemistry.

[60]  Hee‐Tae Jung,et al.  Porphyrin Functionalized Graphene Sheets in Aqueous Suspensions: From the Preparation of Graphene Sheets to Highly Conductive Graphene Films , 2010 .

[61]  W. Lu,et al.  Improved synthesis of graphene oxide. , 2010, ACS nano.

[62]  Sandip Niyogi,et al.  Solution properties of graphite and graphene. , 2006, Journal of the American Chemical Society.

[63]  P. Dubois,et al.  A supramolecular approach toward organo-dispersible graphene and its straightforward polymer nanocomposites , 2012 .

[64]  Martin Pumera,et al.  Graphene-based nanomaterials for energy storage , 2011 .

[65]  T. Ando The electronic properties of graphene and carbon nanotubes , 2009 .

[66]  M. Pumera Graphene‐Based Nanomaterials and Their Electrochemistry , 2011 .

[67]  H. García,et al.  Photochemistry of covalently functionalized graphene oxide with phenothiazinyl units , 2014 .

[68]  D. Jia,et al.  Noncovalently functionalized pristine graphene/metal nanoparticle hybrid for conductive composites , 2014 .

[69]  N. Pu,et al.  Dispersion of graphene in aqueous solutions with different types of surfactants and the production of graphene films by spray or drop coating , 2012 .

[70]  F. Kanoufi,et al.  Localized reduction of graphene oxide by electrogenerated naphthalene radical anions and subsequent diazonium electrografting. , 2014, Journal of the American Chemical Society.

[71]  Peng Zhou,et al.  Evolution of the band-gap and optical properties of graphene oxide with controllable reduction level , 2013 .

[72]  Yuancheng Feng,et al.  Immobilisation of acid pectinase on graphene oxide nanosheets , 2014, Chemical Papers.

[73]  Qun Xu,et al.  High-throughput, direct exfoliation of graphite to graphene via a cooperation of supercritical CO2 and pyrene-polymers , 2012 .

[74]  Xingfa Gao,et al.  Hydrazine and Thermal Reduction of Graphene Oxide: Reaction Mechanisms, Product Structures, and Reaction Design , 2010 .

[75]  William R. Dichtel,et al.  Preservation of antibody selectivity on graphene by conjugation to a tripod monolayer. , 2013, Angewandte Chemie.

[76]  M. Peressi,et al.  First-Principle Study of Hydroxyl Functional Groups on Pristine, Defected Graphene, and Graphene Epoxide , 2010 .

[77]  Khalil Amine,et al.  Chemically active reduced graphene oxide with tunable C/O ratios. , 2011, ACS nano.

[78]  K. Yoshino,et al.  Covalent functionalization of graphene by azobenzene with molecular hydrogen bonds for long-term solar thermal storage , 2013, Scientific Reports.

[79]  T. Michely,et al.  Structural coherency of graphene on Ir(111). , 2008, Nano letters.

[80]  Dan Wu,et al.  Graphene-Based Optical and Electrochemical Biosensors: A Review , 2013 .

[81]  Prashant V Kamat,et al.  Graphitic design: prospects of graphene-based nanocomposites for solar energy conversion, storage, and sensing. , 2013, Accounts of chemical research.

[82]  E. Pop,et al.  Thermal properties of graphene: Fundamentals and applications , 2012, 1301.6181.

[83]  A. Barron,et al.  Nitrene addition to exfoliated graphene: a one-step route to highly functionalized graphene. , 2010, Chemical communications.

[84]  M. Steigerwald,et al.  Photochemical reactivity of graphene. , 2009, Journal of the American Chemical Society.

[85]  C Berger,et al.  Electronic structure of epitaxial graphene layers on SiC: effect of the substrate. , 2007, Physical review letters.

[86]  Xiaobin Fan,et al.  Primary and tertiary amines bifunctional graphene oxide for cooperative catalysis. , 2013, Nanoscale.

[87]  L. Brinson,et al.  Functionalized graphene sheets for polymer nanocomposites. , 2008, Nature nanotechnology.

[88]  Hongkun He,et al.  General Approach to Individually Dispersed, Highly Soluble, and Conductive Graphene Nanosheets Functionalized by Nitrene Chemistry , 2010 .

[89]  Huafeng Yang,et al.  Nanoscale insight into the exfoliation mechanism of graphene with organic dyes: effect of charge, dipole and molecular structure. , 2013, Nanoscale.

[90]  Mingdi Yan,et al.  Derivitization of pristine graphene with well-defined chemical functionalities. , 2010, Nano letters.

[91]  S. Sarma,et al.  Acoustic phonon scattering limited carrier mobility in two-dimensional extrinsic graphene , 2007, 0711.0754.

[92]  Shuangfeng Wang,et al.  Non-covalently modified reduced graphene oxide/polyurethane nanocomposites with good mechanical and thermal properties , 2013, Journal of Materials Science.

[93]  A. Mahmood,et al.  Production, properties and potential of graphene , 2010, 1002.0370.

[94]  Maurizio Prato,et al.  Multipurpose organically modified carbon nanotubes: from functionalization to nanotube composites. , 2008, Journal of the American Chemical Society.

[95]  K. Müllen,et al.  Graphene as Transparent Electrode Material for Organic Electronics , 2011, Advanced materials.

[96]  Jin Ok Hwang,et al.  Chemical structures of hydrazine-treated graphene oxide and generation of aromatic nitrogen doping , 2012, Nature Communications.

[97]  W. Blau,et al.  Graphene oxide covalently functionalized with zinc phthalocyanine for broadband optical limiting , 2011 .

[98]  Haoyuan Lu,et al.  Nanoscale ionic materials based on hydroxyl-functionalized graphene , 2014 .

[99]  Roland G. S. Goh,et al.  Band‐like Transport in Surface‐Functionalized Highly Solution‐Processable Graphene Nanosheets , 2008 .

[100]  Micah J. Green,et al.  Graphene non-covalently tethered with magnetic nanoparticles , 2014 .

[101]  S. Bose,et al.  Preparation of non-covalently functionalized graphene using 9-anthracene carboxylic acid , 2011, Nanotechnology.

[102]  Yan Wang,et al.  A Graphene Hybrid Material Covalently Functionalized with Porphyrin: Synthesis and Optical Limiting Property , 2009 .

[103]  R. Sundaram,et al.  Electrochemical Modification of Graphene , 2008 .

[104]  Jianguo Tang,et al.  Strategies for chemical modification of graphene and applications of chemically modified graphene , 2012 .

[105]  Xuping Sun,et al.  Synthesis of Au nanoparticles decorated graphene oxide nanosheets: noncovalent functionalization by TWEEN 20 in situ reduction of aqueous chloroaurate ions for hydrazine detection and catalytic reduction of 4-nitrophenol. , 2011, Journal of hazardous materials.

[106]  R. Misra,et al.  The synergistic effect of a hybrid graphene oxide-chitosan system and biomimetic mineralization on osteoblast functions. , 2014, Biomaterials science.

[107]  Ye Xu,et al.  Casein Phosphopeptide-Biofunctionalized Graphene Biocomposite for Hydroxyapatite Biomimetic Mineralization , 2013 .

[108]  F. T. Vasko,et al.  Voltage and temperature dependencies of conductivity in gated graphene , 2007, 0708.2976.

[109]  K. M. Carroll,et al.  Nonperturbative chemical modification of graphene for protein micropatterning. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[110]  E. Bekyarova,et al.  Chemical modification of epitaxial graphene: spontaneous grafting of aryl groups. , 2009, Journal of the American Chemical Society.

[111]  Yihong Wu,et al.  Two-dimensional carbon nanostructures: Fundamental properties, synthesis, characterization, and potential applications , 2010 .

[112]  Shaojun Dong,et al.  Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets. , 2010, ACS nano.

[113]  Markus J Buehler,et al.  Mechanics and molecular filtration performance of graphyne nanoweb membranes for selective water purification. , 2013, Nanoscale.

[114]  Micah J. Green,et al.  Dispersions of non-covalently functionalized graphene with minimal stabilizer. , 2012, ACS nano.

[115]  R. Car,et al.  Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite , 2007 .

[116]  K. Müllen,et al.  Transparent, conductive graphene electrodes for dye-sensitized solar cells. , 2008, Nano letters.

[117]  Zheng Xu,et al.  Flexible magnetic nanoparticles-reduced graphene oxide composite membranes formed by self-assembly in solution. , 2010, Chemphyschem : a European journal of chemical physics and physical chemistry.

[118]  K. Krishnamoorthy,et al.  Graphene nanosheets: Ultrasound assisted synthesis and characterization. , 2013, Ultrasonics sonochemistry.

[119]  Sung-Hoon Ahn,et al.  Graphene-ionic liquid based hybrid nanomaterials as novel lubricant for low friction and wear. , 2013, ACS applied materials & interfaces.

[120]  Huafeng Yang,et al.  Water-soluble graphene covalently functionalized by biocompatible poly-L-lysine. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[121]  J. Zink,et al.  Integration of molecular and enzymatic catalysts on graphene for biomimetic generation of antithrombotic species , 2014, Nature Communications.

[122]  Chun Li,et al.  Non-covalent functionalization of graphene sheets by sulfonated polyaniline. , 2009, Chemical communications.

[123]  William R. Dichtel,et al.  Noncovalent Functionalization of Graphene by Molecular and Polymeric Adsorbates , 2013 .

[124]  Jie Jin,et al.  Preparation and characterisation of covalent polymer functionalized graphene oxide , 2011 .

[125]  Klaus Kern,et al.  Electronic transport properties of individual chemically reduced graphene oxide sheets. , 2007, Nano letters.

[126]  Yong‐Lai Zhang,et al.  Photoreduction of Graphene Oxides: Methods, Properties, and Applications , 2014 .

[127]  C. N. Lau,et al.  Superior thermal conductivity of single-layer graphene. , 2008, Nano letters.

[128]  L. Staudenmaier,et al.  Verfahren zur Darstellung der Graphitsäure , 1898 .

[129]  Chun Li,et al.  Flexible graphene films via the filtration of water-soluble noncovalent functionalized graphene sheets. , 2008, Journal of the American Chemical Society.

[130]  L. Qu,et al.  Dimension-tailored functional graphene structures for energy conversion and storage. , 2013, Nanoscale.

[131]  K. Neoh,et al.  Cyclodextrin-functionalized graphene nanosheets, and their host-guest polymer nanohybrids , 2013 .

[132]  Atula S. D. Sandanayaka,et al.  Graphene oxide with covalently linked porphyrin antennae: Synthesis, characterization and photophysical properties , 2011 .

[133]  Haixia Wu,et al.  Reducing Graphene Oxide via Hydroxylamine: A Simple and Efficient Route to Graphene , 2011 .

[134]  Yiu-Wing Mai,et al.  Non-covalently modified graphene sheets by imidazolium ionic liquids for multifunctional polymer nanocomposites , 2012 .

[135]  A. Iwan,et al.  Perspectives of applied graphene: Polymer solar cells , 2012 .

[136]  Dongqing Wu,et al.  Dispersion of Graphene Sheets in Organic Solvent Supported by Ionic Interactions , 2009 .

[137]  Zhuang Liu,et al.  PEGylated nanographene oxide for delivery of water-insoluble cancer drugs. , 2008, Journal of the American Chemical Society.

[138]  M. I. Katsnelson,et al.  Chemical functionalization of graphene with defects. , 2008, Nano letters.

[139]  James M Tour,et al.  Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets. , 2008, Journal of the American Chemical Society.

[140]  M. Liberatore,et al.  Effect of solvent on the uncatalyzed synthesis of aminosilane-functionalized graphene , 2014 .

[141]  Z. Yao,et al.  Fabrication and mechanical properties of phenolic foam reinforced with graphene oxide , 2014 .

[142]  M. Prato,et al.  Functionalization of graphene via 1,3-dipolar cycloaddition. , 2010, ACS nano.

[143]  Yizhe Hu,et al.  Covalent synthesis of organophilic chemically functionalized graphene sheets. , 2010, Journal of colloid and interface science.

[144]  M. Strano,et al.  Anomalously large reactivity of single graphene layers and edges toward electron transfer chemistries. , 2010, Nano letters.

[145]  Hangil Lee,et al.  Covalent Functionalization of Epitaxial Graphene by Azidotrimethylsilane , 2009 .

[146]  S. Xiao,et al.  Intrinsic and extrinsic performance limits of graphene devices on SiO2. , 2007, Nature nanotechnology.

[147]  Samia Subrina,et al.  Dimensional crossover of thermal transport in few-layer graphene. , 2010, Nature materials.

[148]  Ming Zhou,et al.  Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films. , 2009, Chemistry.

[149]  Zhongfan Liu,et al.  Production of graphene sheets by direct dispersion with aromatic healing agents. , 2010, Small.

[150]  Hui Liu,et al.  Graphene oxide as a matrix for enzyme immobilization. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[151]  Yang Wu,et al.  Measurement of the optical conductivity of graphene. , 2008, Physical review letters.

[152]  E. Williams,et al.  Printed Graphene Circuits , 2007, 0809.1634.

[153]  Scott S. Verbridge,et al.  Electromechanical Resonators from Graphene Sheets , 2007, Science.

[154]  V. Basiuk,et al.  Noncovalent functionalization of graphene with a Ni(II) tetraaza[14]annulene complex. , 2014, Dalton transactions.

[155]  Xiaogong Wang,et al.  Graphene Functionalized with Azo Polymer Brushes: Surface‐Initiated Polymerization and Photoresponsive Properties , 2011, Advanced materials.

[156]  O. Nur,et al.  Polycation stabilization of graphene suspensions , 2011, Nanoscale research letters.

[157]  S. Sheshmani,et al.  Suitable chemical methods for preparation of graphene oxide, graphene and surface functionalized graphene nanosheets. , 2013, Acta chimica Slovenica.

[158]  Lin Li,et al.  Poly(vinyl alcohol) nanocomposites filled with poly(vinyl alcohol)-grafted graphene oxide. , 2012, ACS applied materials & interfaces.

[159]  Ming‐bo Yang,et al.  Surperhydrophobic polyurethane foam modified by graphene oxide , 2013 .

[160]  Maurizio Prato,et al.  Organic functionalization of graphene in dispersions. , 2013, Accounts of chemical research.

[161]  Jun Jin,et al.  Aryne cycloaddition: highly efficient chemical modification of graphene. , 2010, Chemical communications.

[162]  Guoliang Zhang,et al.  Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation , 2008 .

[163]  Paul L. McEuen,et al.  Mechanical properties of suspended graphene sheets , 2007 .

[164]  Jaeho Kim,et al.  Low-temperature graphene synthesis using microwave plasma CVD , 2013 .

[165]  S. Kim,et al.  25th Anniversary Article: Chemically Modified/Doped Carbon Nanotubes & Graphene for Optimized Nanostructures & Nanodevices , 2014, Advanced materials.

[166]  J. Coleman,et al.  Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions , 2008, 0809.2690.

[167]  E. Bekyarova,et al.  Diels-Alder chemistry of graphite and graphene: graphene as diene and dienophile. , 2011, Journal of the American Chemical Society.

[168]  Hongrui Jiang,et al.  An infrared-light responsive graphene-oxide incorporated poly(N-isopropylacrylamide) hydrogel nanocomposite , 2011 .

[169]  Kai Yang,et al.  Graphene in mice: ultrahigh in vivo tumor uptake and efficient photothermal therapy. , 2010, Nano letters.

[170]  Xing Ma,et al.  Graphene oxide wrapped gold nanoparticles for intracellular Raman imaging and drug delivery. , 2013, Journal of materials chemistry. B.

[171]  Peter Sutter,et al.  Epitaxial graphene: How silicon leaves the scene. , 2009, Nature materials.

[172]  Kazuhito Tsukagoshi,et al.  Low operating bias and matched input-output characteristics in graphene logic inverters. , 2010, Nano letters.

[173]  Inhwa Jung,et al.  Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. , 2009, Nano letters.

[174]  Qiang Yang,et al.  Fabrication of High-Concentration and Stable Aqueous Suspensions of Graphene Nanosheets by Noncovalent Functionalization with Lignin and Cellulose Derivatives , 2010 .

[175]  C. T. White,et al.  Building blocks for integrated graphene circuits. , 2007, Nano letters.

[176]  Junhong Chen,et al.  Facile, noncovalent decoration of graphene oxide sheets with nanocrystals , 2009 .

[177]  Klaus Kern,et al.  Elastic properties of chemically derived single graphene sheets. , 2008, Nano letters.

[178]  Myongsoo Lee,et al.  An amphiphilic pyrene sheet for selective functionalization of graphene. , 2011, Chemical communications.

[179]  W. S. Hummers,et al.  Preparation of Graphitic Oxide , 1958 .

[180]  M. Hersam,et al.  Scanning tunneling microscopy, spectroscopy, and nanolithography of epitaxial graphene chemically modified with aryl moieties. , 2010, Journal of the American Chemical Society.

[181]  Hui Liu,et al.  Horseradish Peroxidase Immobilized on Graphene Oxide: Physical Properties and Applications in Phenolic Compound Removal , 2010 .

[182]  D. Losic,et al.  Graphene and graphene oxide as new nanocarriers for drug delivery applications. , 2013, Acta biomaterialia.

[183]  Shifeng Hou,et al.  Formation of highly stable dispersions of silane-functionalized reduced graphene oxide , 2010 .

[184]  D. A. Corley,et al.  Kinetics of diazonium functionalization of chemically converted graphene nanoribbons. , 2010, ACS nano.

[185]  Ming-Yu Yen,et al.  Preparation of covalently functionalized graphene using residual oxygen-containing functional groups. , 2010, ACS applied materials & interfaces.

[186]  E. Morallón,et al.  Investigating the influence of surfactants on the stabilization of aqueous reduced graphene oxide dispersions and the characteristics of their composite films , 2012 .

[187]  Bon-Cheol Ku,et al.  In situ synthesis of the reduced graphene oxide–polyethyleneimine composite and its gas barrier properties , 2013 .

[188]  Abdullah M. Asiri,et al.  Graphene based materials for biomedical applications , 2013 .

[189]  J. Coleman,et al.  High-yield production of graphene by liquid-phase exfoliation of graphite. , 2008, Nature nanotechnology.

[190]  K. Novoselov,et al.  Graphene-based liquid crystal device. , 2008, Nano letters (Print).

[191]  A. Green,et al.  Solution phase production of graphene with controlled thickness via density differentiation. , 2009, Nano letters.

[192]  F. Schwierz Graphene transistors. , 2010, Nature nanotechnology.

[193]  Mingdi Yan,et al.  Covalent functionalization of graphene with reactive intermediates. , 2013, Accounts of chemical research.

[194]  J. Figueiredo,et al.  Understanding the silylation reaction of multi-walled carbon nanotubes , 2011 .

[195]  G. Han,et al.  Ionic liquid-functionalized graphene for fabricating an amperometric acetylcholinesterase biosensor. , 2012, The Analyst.

[196]  I. In,et al.  Blood compatible graphene/heparin conjugate through noncovalent chemistry. , 2011, Biomacromolecules.

[197]  T. Pal,et al.  Silver nanoparticle decorated reduced graphene oxide (rGO) nanosheet: a platform for SERS based low-level detection of uranyl ion. , 2013, ACS applied materials & interfaces.

[198]  K. C. Kemp,et al.  Noncovalent Functionalization of Graphene , 2014 .

[199]  S. Hur,et al.  One-step synthesis of superior dispersion of chemically converted graphene in organic solvents. , 2010, Chemical communications.

[200]  A. Abdolmaleki,et al.  Covalently functionalized graphene sheets with biocompatible natural amino acids , 2014 .

[201]  K. M. Liew,et al.  Equilibrium configuration and continuum elastic properties of finite sized graphene , 2006 .

[202]  R. Kaner,et al.  Photothermal Deoxygenation of Graphene Oxide for Patterning and Distributed Ignition Applications , 2010, Advanced materials.

[203]  T. Yildirim,et al.  Porous graphene oxide frameworks: Synthesis and gas sorption properties , 2011 .

[204]  S. Bose,et al.  Recent advances in graphene based polymer composites , 2010 .

[205]  C. Rao,et al.  A study of the synthetic methods and properties of graphenes , 2010, Science and technology of advanced materials.