Photocatalytic Process for CO2 Emission Reduction from Industrial Flue Gas Streams

At present, carbon dioxide (CO2) is the largest contributor among greenhouse gases. This article addresses the potential application of photocatalysis to the reduction of CO2 emissions from industrial flue gas streams. Not only does this process remove CO2, but it can also convert CO2 into other chemical commodities such as methane, methanol, and ethanol. In addition, the photocatalytic process can consume less energy than conventional methods by harnessing solar energy. Given these advantages, photocatalysis is an attractive alternative for CO2 capture. This article reviews the principle of photocatalysis; existing literature related to photocatalytic CO2 reduction; and the effects of important parameters on process performance, including light wavelength and intensity, type of reductant, metal-modified surface, temperature, and pressure. Finally, we discuss various system configurations for UV and solar photocatalytic reactors. The advances in photocatalysis technology indicate a promising application p...

[1]  S. McEvoy,et al.  A comparison of 254 nm and 350 nm excitation of TiO2 in simple photocatalytic reactors , 1992 .

[2]  Nick Serpone,et al.  Photocatalyzed destruction of water contaminants , 1991 .

[3]  H. Yoneyama Photoreduction of carbon dioxide on quantized semiconductor nanoparticles in solution , 1997 .

[4]  K. Al-Jubori,et al.  Photoreduction of CO2 by metal sulphide semiconductors in presence of H2S , 1989 .

[5]  O. Ishitani,et al.  Efficient photocatalytic CO2 reduction using [Re(bpy) (CO)3{P(OEt)3}]+ , 1996 .

[6]  A. Fujishima,et al.  Electrochemical Reduction of CO2 with High Current Density in a CO2-Methanol Medium , 1995 .

[7]  Yuichi Ichihashi,et al.  Photocatalytic reduction of CO2 with H2O on various titanium oxide catalysts , 1995 .

[8]  Andrew Mills,et al.  WATER-PURIFICATION BY SEMICONDUCTOR PHOTOCATALYSIS , 1993 .

[9]  Edward J. Daniels,et al.  CO2 capture from the flue gas of conventional fossil‐fuel‐fired power plants , 1994 .

[10]  Peter Harriott,et al.  Unit Operations of Chemical Engineering , 2004 .

[11]  A. Alexiadis,et al.  Design guidelines for fixed-bed photocatalytic reactors , 2005 .

[12]  F. Saladin,et al.  Temperature dependence of the photochemical reduction of CO2in the presence of H2Oat the solid/gas interface of TiO2 , 1997 .

[13]  H. Yoneyama,et al.  Photocatalytic reduction of carbon dioxide in the presence of nitrate using TiO2 nanocrystal photocatalyst embedded in SiO2 matrices , 1998 .

[14]  K. Hara,et al.  Electrochemical reduction of high pressure CO2 at Pb, Hg and In electrodes in an aqueous KHCO3 solution , 1995 .

[15]  Tsunehiro Tanaka,et al.  PHOTOREDUCTION OF CARBON DIOXIDE WITH HYDROGEN OVER ZRO2 , 1997 .

[16]  H. Kisch,et al.  Photoreduction of carbon dioxide catalysed by free and supported zinc and cadmium sulphide powders , 1997 .

[17]  S. Martin,et al.  Environmental Applications of Semiconductor Photocatalysis , 1995 .

[18]  M. Halmann,et al.  Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells , 1978, Nature.

[19]  Yuichi Ichihashi,et al.  Photocatalytic Reduction of CO2 with H2O on Titanium Oxides Anchored within Micropores of Zeolites: Effects of the Structure of the Active Sites and the Addition of Pt , 1997 .

[20]  G. Guan,et al.  Reduction of carbon dioxide with water under concentrated sunlight using photocatalyst combined with Fe-based catalyst , 2003 .

[21]  Ajay K. Ray,et al.  Novel swirl‐flow reactor for kinetic studies of semiconductor photocatalysis , 1997 .

[22]  R. L. Pozzo,et al.  Supported titanium oxide as photocatalyst in water decontamination: State of the art , 1997 .

[23]  D. Cahen,et al.  Tungsten trioxide as a photoanode for a photoelectrochemical cell (PEC) , 1976, Nature.

[24]  Alberto E. Cassano,et al.  Reaction engineering of suspended solid heterogeneous photocatalytic reactors , 2000 .

[25]  A. J. Frank,et al.  Selective photoreduction of carbon dioxide/bicarbonate to formate by aqueous suspensions and colloids of palladium-titania , 1990 .

[26]  M. Anpo,et al.  Photocatalytic Reduction of CO2 with H2O on Ti−β Zeolite Photocatalysts: Effect of the Hydrophobic and Hydrophilic Properties , 2001 .

[27]  M. Anpo,et al.  Synthesis of transparent Ti-containing mesoporous silica thin film materials and their unique photocatalytic activity for the reduction of CO2 with H2O , 2003 .

[28]  Akihiko Kudo,et al.  Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte , 1995 .

[29]  I-Hsiang Tseng,et al.  Photoreduction of CO2 using sol–gel derived titania and titania-supported copper catalysts , 2002 .

[30]  Kohei Inoue,et al.  Photocatalysed reduction of CO2 in aqueous TiO2 suspension mixed with copper powder , 1992 .

[31]  H. Frei,et al.  Mechanistic Study of CO2 Photoreduction in Ti Silicalite Molecular Sieve by FT-IR Spectroscopy , 2000 .

[32]  Xudong Yang,et al.  Photocatalytic oxidation for indoor air purification: a literature review , 2003 .

[33]  A. Couper,et al.  Book reviewMolecular quantum mechanics, 2nd ed.: (a) By P. W. Atkins. Pp. 471, (a) Hard cover £29.50, paperback £13.95 , 1984 .

[34]  K. Tennakone,et al.  Photoreduction of carbonic acid by mercury coated n-titanium dioxide , 1984 .

[35]  T. Tatsumi,et al.  Photocatalytic reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 mesoporous zeolite catalysts , 1998 .

[36]  Shinichi Ichikawa,et al.  Hydrogen production from water and conversion of carbon dioxide to useful chemicals by room temperature photoelectrocatalysis , 1996 .

[37]  S. Nozaki,et al.  Characterization of self-standing Ti-containing porous silica thin films and their reactivity for the photocatalytic reduction of CO2 with H2O , 2002 .

[38]  Alberto E. Cassano,et al.  Photocatalysis in water environments using artificial and solar light , 2000 .

[39]  George S. Attard,et al.  Liquid-crystalline phases as templates for the synthesis of mesoporous silica , 1995, Nature.

[40]  E. Dalchiele,et al.  Photocatalytic removal of Hg from solid wastes of chlor-alkali plant , 2002 .

[41]  Osamu Ishitani,et al.  Photocatalytic reduction of carbon dioxide to methane and acetic acid by an aqueous suspension of metal-deposited TiO2 , 1993 .

[42]  Gabor A. Somorjai,et al.  The photoassisted reaction of gaseous water and carbon dioxide adsorbed on the SrTiO3 (111) crystal face to form methane , 1978 .

[43]  Photochemistry at high temperatures – potential of ZnO as a high temperature photocatalyst , 1996 .

[44]  W. Struve,et al.  Fundamentals of molecular spectroscopy , 1990 .

[45]  C. Turchi,et al.  Heterogeneous photocatalysis for water purification: Contaminant mineralization kinetics and elementary reactor analysis , 1990 .

[46]  Y. Ku,et al.  Photocatalytic reduction of carbonate in aqueous solution by UV/TiO2 process , 2004 .

[47]  Y. Wada,et al.  Effect of Surface Structures on Photocatalytic CO2 Reduction Using Quantized CdS Nanocrystallites , 1997 .

[48]  A. Fujishima,et al.  Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders , 1979, Nature.

[49]  T. Xie,et al.  Application of surface photovoltage technique in photocatalysis studies on modified TiO2 photo-catalysts for photo-reduction of CO2 , 2001 .

[50]  Tsunehiro Tanaka,et al.  Photoreduction of carbon dioxide by hydrogen over magnesium oxide , 2001 .

[51]  K. Tennakone,et al.  Selective photoreduction of carbon dioxide to methanol with hydrous cuprous oxide , 1989 .

[52]  Edward S Rubin,et al.  A technical, economic, and environmental assessment of amine-based CO2 capture technology for power plant greenhouse gas control. , 2002, Environmental science & technology.

[53]  Yoshiyuki Sasaki,et al.  Efficient rhenium-catalyzed photochemical carbon dioxide reduction under high pressure , 2003 .

[54]  Geoffrey A. Ozin,et al.  Registered growth of mesoporous silica films on graphite , 1997 .

[55]  N. Alonso‐Vante,et al.  A screening for the photo reduction of carbon dioxide supported on metal oxide catalysts for C1-C3 selectivity , 1999 .

[56]  T. Hirose,et al.  Photocatalytic carbon dioxide photoreduction by Co(bpy)32+ sensitized by Ru(bpy)32+ fixed to cation exchange polymer , 2003 .

[57]  J. Wu,et al.  Effects of sol–gel procedures on the photocatalysis of Cu/TiO2 in CO2 photoreduction , 2004 .

[58]  A. Fujishima,et al.  Electrochemical reduction of CO2 with high current density in a CO2 + methanol medium II. CO formation promoted by tetrabutylammonium cation , 1995 .

[59]  H. Hori,et al.  Rhenium-Mediated Photochemical Carbon Dioxide Reduction in Compressed Carbon Dioxide , 2000 .

[60]  Yoko Suzuki,et al.  High-pressure photocatalytic reduction of carbon dioxide using [fac-Re(bpy)(CO)3P(OiPr)3]+ (bpy = 2,2'-bipyridine) , 2002 .

[61]  H. Yoneyama,et al.  Photocatalytic reduction of CO2 using surface-modified CdS photocatalysts in organic solvents , 1998 .

[62]  Y. Shimizu,et al.  Photocatalytic reduction of high pressure carbon dioxide using TiO2 powders with a positive hole scavenger , 1998 .

[63]  M. Ogawa A simple sol–gel route for the preparation of silica–surfactant mesostructured materials , 1996 .

[64]  R. L. Sawhney,et al.  Treatment of Hazardous Organic and Inorganic Compounds through Aqueous-Phase Photocatalysis: A Review , 2004 .

[65]  Gregory B. Raupp,et al.  Three‐dimensional developing flow model for photocatalytic monolith reactors , 1999 .

[66]  Y. Kaya Impact of carbon dioxide emission control on GNP growth : Interpretation of proposed scenarios , 1989 .

[67]  J. Kiwi,et al.  Photoassisted carbon dioxide reduction on aqueous suspensions of titanium dioxide , 1984 .

[68]  M. Anpo,et al.  Local structures, excited states, and photocatalytic reactivities of highly dispersed catalysts constructed within zeolites , 2003 .

[69]  N. Gokon,et al.  Photocatalytic effect of ZnO on carbon gasification with CO2 for high temperature solar thermochemistry , 2003 .

[70]  K. Ohta,et al.  Photocatalytic reduction of carbon dioxide to hydrocarbon using copper-loaded titanium dioxide , 1994 .

[71]  John L. Falconer,et al.  Transient Studies of 2-Propanol Photocatalytic Oxidation on Titania , 1995 .