A novel poly(2,6-dimethyl-1,4-phenylene oxide) with trifunctional ammonium moieties for alkaline anion exchange membranes.

2,4,6-Tri(dimethylaminomethyl)-phenol was synthesized as a trifunctional moiety and incorporated onto poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) to obtain a novel quaternary ammonium functionalized PPO (PPO-TQA). Membranes of the polymer were fabricated and exhibited high conductivity, a low swelling ratio and water uptake.

[1]  Y. Meng,et al.  Synthesis and properties of anion conductive multiblock copolymers containing tetraphenyl methane moieties for fuel cell application , 2013 .

[2]  H. Abruña,et al.  Phosphonium-functionalized polyethylene: a new class of base-stable alkaline anion exchange membranes. , 2012, Journal of the American Chemical Society.

[3]  Nanwen Li,et al.  Highly stable, anion conductive, comb-shaped copolymers for alkaline fuel cells. , 2013, Journal of the American Chemical Society.

[4]  K. M. Lee,et al.  Alkaline fuel cell membranes from xylylene block ionenes , 2009 .

[5]  Zhongwei Chen,et al.  A soluble and highly conductive ionomer for high-performance hydroxide exchange membrane fuel cells. , 2009, Angewandte Chemie.

[6]  Junhua Wang,et al.  Synthesis of multi-block poly(arylene ether sulfone) copolymer membrane with pendant quaternary ammo , 2011 .

[7]  Jing Pan,et al.  High‐Performance Alkaline Polymer Electrolyte for Fuel Cell Applications , 2010 .

[8]  M. Guiver,et al.  Guanidinium-Functionalized Anion Exchange Polymer Electrolytes via Activated Fluorophenyl-Amine Reaction , 2011 .

[9]  T. Xu,et al.  Synthesis and characterizations of novel, positively charged hybrid membranes from poly(2,6-dimethyl-1,4-phenylene oxide) , 2006 .

[10]  Dc Kitty Nijmeijer,et al.  Anion exchange membranes for alkaline fuel cells: A review , 2011 .

[11]  Liang Wu,et al.  Development of imidazolium-type alkaline anion exchange membranes for fuel cell application , 2012 .

[12]  Cy H. Fujimoto,et al.  Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells , 2009 .

[13]  M. Hickner Ion-containing polymers: new energy & clean water , 2010 .

[14]  Qiang Zhang,et al.  A novel guanidinium grafted poly(aryl ether sulfone) for high-performance hydroxide exchange membranes. , 2010, Chemical communications.

[15]  Andrew M. Herring,et al.  Tertiary sulfonium as a cationic functional group for hydroxide exchange membranes , 2012 .

[16]  S. Nam,et al.  Imidazolium-functionalized poly(arylene ether sulfone) block copolymer as an anion exchange membrane for alkaline fuel cell , 2013 .

[17]  Yushan Yan,et al.  Self-crosslinking for dimensionally stable and solvent-resistant quaternary phosphonium based hydroxide exchange membranes. , 2011, Chemical communications.

[18]  Michael A. Hickner,et al.  Quantitative 1H NMR Analysis of Chemical Stabilities in Anion-Exchange Membranes. , 2013, ACS macro letters.

[19]  W. Li,et al.  Novel anion exchange membranes based on polymerizable imidazolium salt for alkaline fuel cell applications , 2011 .

[20]  J. Varcoe,et al.  Anion-exchange membranes for alkaline polymer electrolyte fuel cells: comparison of pendent benzyltrimethylammonium- and benzylmethylimidazolium-head-groups , 2012 .

[21]  Liang Wu,et al.  Alkali resistant and conductive guanidinium-based anion-exchange membranes for alkaline polymer electrolyte fuel cells , 2012 .

[22]  Dan Wu,et al.  Preparation and characterization of CPPO/BPPO blend membranes for potential application in alkaline direct methanol fuel cell , 2008 .

[23]  Junhua Wang,et al.  Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes , 2009 .

[24]  F. Yan,et al.  A Soluble and Conductive Polyfluorene Ionomer with Pendant Imidazolium Groups for Alkaline Fuel Cell Applications , 2011 .

[25]  P. Jannasch,et al.  Proton‐Conducting Aromatic Polymers Carrying Hypersulfonated Side Chains for Fuel Cell Applications , 2007 .

[26]  Timothy J. Peckham,et al.  Structure‐Morphology‐Property Relationships of Non‐Perfluorinated Proton‐Conducting Membranes , 2010, Advanced materials.

[27]  Nanwen Li,et al.  Comb-shaped polymers to enhance hydroxide transport in anion exchange membranes , 2012 .

[28]  Jian‐mei Lu,et al.  Cross-Linked Alkaline Ionic Liquid-Based Polymer Electrolytes for Alkaline Fuel Cell Applications , 2010 .

[29]  Huamin Zhang,et al.  Imidazolium functionalized polysulfone anion exchange membrane for fuel cell application , 2011 .

[30]  Jing Pan,et al.  Designing advanced alkaline polymer electrolytes for fuel cell applications. , 2012, Accounts of chemical research.

[31]  Liang Wu,et al.  Enhancement of hydroxide conduction by self-assembly in anion conductive comb-shaped copolymers , 2013 .

[32]  R. Slade,et al.  Prospects for Alkaline Anion‐Exchange Membranes in Low Temperature Fuel Cells , 2005 .

[33]  Artur Makarewicz,et al.  Electronic Supplementary Material ( ESI ) for ChemComm , 2015 .

[34]  Michael A. Hickner,et al.  Anion Exchange Membranes by Bromination of Benzylmethyl-Containing Poly(sulfone)s , 2010 .

[35]  B. Améduri,et al.  Polymeric materials as anion-exchange membranes for alkaline fuel cells , 2011 .

[36]  Manabu Tanaka,et al.  Anion conductive block poly(arylene ether)s: synthesis, properties, and application in alkaline fuel cells. , 2011, Journal of the American Chemical Society.

[37]  Cy H. Fujimoto,et al.  Transport Properties of Hydroxide and Proton Conducting Membranes , 2008 .

[38]  Q. Liu,et al.  Quaternized cardo polyetherketone anion exchange membrane for direct methanol alkaline fuel cells , 2009 .

[39]  M. Koike,et al.  Anion Conductive Aromatic Ionomers Containing Fluorenyl Groups , 2010 .

[40]  Junhua Wang,et al.  Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications , 2010 .

[41]  Y. Elabd,et al.  Block Copolymers for Fuel Cells , 2011 .