A flexible and accurate quantification algorithm for electron probe X-ray microanalysis based on thin-film element yields

Abstract Quantitative analysis by means of electron probe X-ray microanalysis (EPXMA) of low Z materials such as silicate glasses can be hampered by the fact that ice or other contaminants build up on the Si(Li) detector beryllium window or (in the case of a windowless detector) on the Si(Li) crystal itself. These layers act as an additional absorber in front of the detector crystal, decreasing the detection efficiency at low energies (

[1]  J. Cazaux,et al.  Electron Probe Microanalysis of Insulating Materials: Quantification Problems and Some Possible Solutions , 1996 .

[2]  Koen Janssens,et al.  Comparison of several background compensation methods useful for evaluation of energy-dispersive X-ray fluorescence spectra , 1995 .

[3]  H E Bishop,et al.  The prospects for an improved absorption correction in electron probe microanalysis , 1974 .

[4]  J. Owen,et al.  Compositional Characteristics of 18th Century Derby Porcelains: Recipe Changes, Phase Transformations, and Melt Fertility , 1997 .

[5]  A. Casoli,et al.  Technology of Production of Fine Pottery Excavated on a Western Greek Site Investigated by Scanning Electron Microscopy Coupled with Energy-Dispersive X-ray Detection , 1996 .

[6]  M. C. Cox,et al.  A versatile atomic number correction for electron-probe microanalysis , 1978 .

[7]  J. Cazaux,et al.  Some considerations on the electric field induced in insulators by electron bombardment , 1986 .

[8]  O. Dugne,et al.  Standardless semi-quantitative analysis with WDS-EPMA , 1999 .

[9]  A. Zambon,et al.  Microstructural and compositional characterization of Roman coins , 1999 .

[10]  A. Casoli,et al.  SCIENTIFIC ANALYSIS OF ROMAN GLASS FROM AUGUSTA PRAETORIA , 1993 .

[11]  A. Adriaens Elemental composition and microstructure of Early Bronze Age and medieval tin slags , 1996 .

[12]  M. Verità,et al.  X-RAY MICROANALYSIS OF ANCIENT GLASSY MATERIALS: A COMPARATIVE STUDY OF WAVELENGTH DISPERSIVE AND ENERGY DISPERSIVE TECHNIQUES* , 1994 .

[13]  S. Ilani,et al.  Bronze Alloys from Canaan During the Middle Bronze Age , 1997 .

[14]  G. Love,et al.  Evaluation of a new correction procedure for quantitative electron probe microanalysis , 1978 .

[15]  L. Yablonsky,et al.  CHEMICAL ANALYSES OF GLASS BEADS FOUND IN TWO SARMATIAN BURIALS , 1997 .

[16]  K. Janssens,et al.  Composition of 15-17th century archaeological glass vessels excavated in Antwerp, Belgium , 1998 .

[17]  P. Acquafredda,et al.  Chemical characterization of obsidians from different Mediterranean sources by non-destructive SEM-EDS analytical method , 1999 .

[18]  G. Love,et al.  Quantitative Electron Probe Microanalysis , 2001 .