Low resistance Ti Ohmic contacts to 4H-SiC by reducing barrier heights without high temperature annealing

Ti Ohmic contacts to relatively highly doped (1 × 1018 cm−3) n-type 4H-SiC have been produced, without high temperature annealing, by means of low temperature electronic cyclotron resonance microwave hydrogen plasma pre-treatment (HPT) of the SiC surface. The as-deposited Ti/4H-SiC contacts show Ohmic properties, and the specific contact resistance obtained is as low as 2.07 × 10−4 Ω·cm2 after annealing at low temperatures (400 °C). This is achieved by low barrier height at Ti/SiC interface, which could be attributed to decrease of surface states density by the HPT releasing Fermi level pinning, and to band-gap narrowing, image-force, and thermionic-field emission at high doping.

[1]  A. Yu,et al.  Electron tunneling and contact resistance of metal-silicon contact barriers , 1970 .

[2]  L. Calcagno,et al.  Schottky--ohmic transition in nickel silicide/SiC-4H system: is it really a solved problem? , 2003 .

[3]  S. Han,et al.  Interpretation of Fermi level pinning on 4H-SiC using synchrotron photoemission spectroscopy , 2004 .

[4]  P. Machac,et al.  Role of titanium in Ti/Ni ohmic contact on n-type 6H-SiC , 2010 .

[5]  S. Mohammad Contact mechanisms and design principles for alloyed ohmic contacts to n-GaN , 2004 .

[6]  M. Kuijk,et al.  Ohmic contact formation on n-type Ge , 2008 .

[7]  Ho Won Jang,et al.  Ohmic contact formation mechanism of Ni on n-type 4H–SiC , 2001 .

[8]  A. Lebedev,et al.  Surface barrier height in metal-n-6H-SiC structures , 1995 .

[9]  H. Tsuchida,et al.  Infrared attenuated total reflection spectroscopy of 6H–SiC(0001) and (0001̄) surfaces , 1999 .

[10]  In-Bok Yom,et al.  Millimeter Wave MMIC Low Noise Amplifiers Using a 0.15 um Commercial pHEMT Process , 2002 .

[11]  E. H. Rhoderick,et al.  Metal–Semiconductor Contacts , 1979 .

[12]  M. Satoh,et al.  Schottky barrier height of a new ohmic contact NiSi2 to n-type 6H-SiC , 2002 .

[13]  B. Santo,et al.  Solid State , 2012 .

[14]  Weijie Lu,et al.  Carbon structural transitions and ohmic contacts on 4H-SiC , 2003 .

[15]  Lingqi Huang,et al.  Cleaning of SiC surfaces by low temperature ECR microwave hydrogen plasma , 2011 .

[16]  J. Waldrop,et al.  Schottky barrier height and interface chemistry of annealed metal contacts to alpha 6H‐SiC: Crystal face dependence , 1993 .

[17]  K. Lau,et al.  Study of Schottky barrier of Ni on p-GaN , 2001 .

[18]  E. Augendre,et al.  Schottky-Barrier Height Lowering by an Increase of the Substrate Doping in PtSi Schottky Barrier Source/Drain FETs , 2007, IEEE Electron Device Letters.

[19]  Yashvir Singh,et al.  A new 4H-SiC lateral merged double Schottky (LMDS) rectifier with excellent forward and reverse characteristics , 2001 .

[20]  H. Morkoç,et al.  GaN grown on hydrogen plasma cleaned 6H‐SiC substrates , 1993 .

[21]  Koji Kajimura,et al.  IDEAL OHMIC CONTACT TO N-TYPE 6H-SIC BY REDUCTION OF SCHOTTKY BARRIER HEIGHT , 1997 .

[22]  K. Kavanagh,et al.  Scanning spreading resistance microscopy current transport studies on doped III V semiconductors , 2002 .

[23]  M. Shur Physics of Semiconductor Devices , 1969 .

[24]  W. Lee,et al.  Creating room temperature Ohmic contacts to 4H-SiC: studied by specific contact resistance measurements and X-ray photoelectron spectroscopy , 2004 .

[25]  M. Bozack,et al.  High‐temperature ohmic contact to n‐type 6H‐SiC using nickel , 1995 .

[26]  L. Ley,et al.  Surface Fermi level position of hydrogen passivated Si(111) surfaces , 1996 .

[27]  Interface passivation for silicon dioxide layers on silicon carbide , 2005 .

[28]  K. Emtsev,et al.  Schottky barrier between 6H-SiC and graphite: Implications for metal/SiC contact formation , 2006 .

[29]  R. Yakimova,et al.  Electrical properties of the graphene/4H-SiC (0001) interface probed by scanning current spectroscopy , 2009 .

[30]  Current conduction mechanism of Si/Ti-based Ohmic contacts to n-GaN , 2000 .

[31]  T. Seyller,et al.  Electronic and chemical passivation of hexagonal 6H–SiC surfaces by hydrogen termination , 2001 .

[32]  F. Frisina,et al.  Structural characterisation of titanium silicon carbide reaction , 2000 .

[33]  S.M.Sze,et al.  Surface States and Barrier Height of Metal‐Semiconductor Systems , 1965 .