Quantum dot light-emitting devices

Colloidal semiconductor nanocrystals, also known as “quantum dots” (QDs), represent an example of a disruptive technology for display and lighting applications. The QDs’ high luminescence efficiency and precisely tunable, narrow emission are nearly ideal for achieving saturated colors and enriching the display or TV color gamut. Quantum dot light-emitting diodes (QLEDs) can provide saturated emission colors and allow inexpensive solution-based device fabrication on almost any substrate. The first incorporation of QDs into the consumer market is using them as optical down-converters. Blue light from an efficient high energy light source (e.g., GaN blue LED) is absorbed and reemitted at any desired lower energy wavelength. Alternatively, electric current can be used for direct excitation of QDs. QLEDs are an exciting technical challenge and commercial opportunity for display and solid-state lighting applications. Recent developments in the field show that efficiency and brightness of QLEDs can match those of organic LEDs.

[1]  Rebecca J. Anthony,et al.  High-efficiency silicon nanocrystal light-emitting devices. , 2011, Nano letters.

[2]  A. Rogach,et al.  Evolution of an Ensemble of Nanoparticles in a Colloidal Solution: Theoretical Study , 2001 .

[3]  D. Balding,et al.  HLA Sequence Polymorphism and the Origin of Humans , 2006 .

[4]  V. Bulović,et al.  Emergence of colloidal quantum-dot light-emitting technologies , 2012, Nature Photonics.

[5]  U. Banin,et al.  Efficient Near-Infrared Polymer Nanocrystal Light-Emitting Diodes , 2002, Science.

[6]  Liang Li,et al.  One-pot synthesis of highly luminescent InP/ZnS nanocrystals without precursor injection. , 2008, Journal of the American Chemical Society.

[7]  M. Bawendi,et al.  Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites , 1993 .

[8]  Eun Kyung Lee,et al.  Full-colour quantum dot displays fabricated by transfer printing , 2011 .

[9]  A. Rogach,et al.  Organization of Matter on Different Size Scales: Monodisperse Nanocrystals and Their Superstructures , 2002 .

[10]  Mihrimah Ozkan,et al.  Trilayer hybrid polymer-quantum dot light-emitting diodes , 2004 .

[11]  Alf Mews,et al.  Synthesis and characterization of highly luminescent CdSe-core CdS/Zn0.5Cd0.5S/ZnS multishell nanocrystals. , 2005, Journal of the American Chemical Society.

[12]  M. Petruska,et al.  Multicolor light-emitting diodes based on semiconductor nanocrystals encapsulated in GaN charge injection layers. , 2005, Nano letters.

[13]  A. Alivisatos,et al.  Improved efficiencies in light emitting diodes made with CdSe(CdS) core/shell type nanocrystals and a semiconducting polymer , 1997 .

[14]  A. Jen,et al.  Efficient CdSe/CdS quantum dot light-emitting diodes using a thermally polymerized hole transport layer. , 2006, Nano letters.

[15]  G. Gigli,et al.  White-light-emitting diodes using semiconductor nanocrystals , 2007 .

[16]  Ou Chen,et al.  Compact high-quality CdSe-CdS core-shell nanocrystals with narrow emission linewidths and suppressed blinking. , 2013, Nature materials.

[17]  V. Bulović,et al.  Color-saturated green-emitting QD-LEDs. , 2006, Angewandte Chemie.

[18]  V. Bulović,et al.  High-efficiency quantum-dot light-emitting devices with enhanced charge injection , 2013, Nature Photonics.

[19]  R. Raffaelle,et al.  Quantum dot solar cells , 2002 .

[20]  Nicholas A. Kotov,et al.  Layer-by-Layer Assembled Films of HgTe Nanocrystals with Strong Infrared Emission , 2000 .

[21]  D. Y. Yoon,et al.  Bright and efficient full-color colloidal quantum dot light-emitting diodes using an inverted device structure. , 2012, Nano letters.

[22]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[23]  John B. Shoven,et al.  I , Edinburgh Medical and Surgical Journal.

[24]  Xiaogang Peng,et al.  Control of photoluminescence properties of CdSe nanocrystals in growth. , 2002, Journal of the American Chemical Society.

[25]  M. Bawendi,et al.  Electroluminescence from heterostructures of poly(phenylene vinylene) and inorganic CdSe nanocrystals , 1998 .

[26]  G. Ozin,et al.  Multicolor silicon light-emitting diodes (SiLEDs). , 2013, Nano letters.

[27]  M. A. Malik,et al.  A Novel Route for the Preparation of CuSe and CuInSe2 Nanoparticles , 1999 .

[28]  V. Bulović,et al.  Electroluminescence from single monolayers of nanocrystals in molecular organic devices , 2002, Nature.

[29]  A. Rogach,et al.  Infrared-emitting colloidal nanocrystals: synthesis, assembly, spectroscopy, and applications. , 2007, Small.

[30]  V. Bulović,et al.  Electroluminescence from a mixed red-green-blue colloidal quantum dot monolayer. , 2007, Nano letters.

[31]  Alexander A. Balandin,et al.  Miniband formation in a quantum dot crystal , 2001 .

[32]  Vladimir Bulovic,et al.  Tuning the performance of hybrid organic/inorganic quantum dot light-emitting devices , 2003 .

[33]  N. J. Ekins-Daukes,et al.  Quantum dot solar concentrators , 2004 .

[34]  Lilac Amirav,et al.  PbSe Nanocrystal Assemblies: Synthesis and Structural, Optical, and Electrical Characterization , 2004 .

[35]  R. Schaller,et al.  Carrier multiplication in InAs nanocrystal quantum dots with an onset defined by the energy conservation limit. , 2007, Nano letters.

[36]  Louis E. Brus,et al.  Electronic wave functions in semiconductor clusters: experiment and theory , 1986 .

[37]  A. Alivisatos,et al.  Light-emitting diodes made from cadmium selenide nanocrystals and a semiconducting polymer , 1994, Nature.

[38]  V. Bulović,et al.  Electronic and excitonic processes in light-emitting devices based on organic materials and colloidal quantum dots , 2008 .

[39]  Hilmi Volkan Demir,et al.  White light generation using CdSe/ZnS core–shell nanocrystals hybridized with InGaN/GaN light emitting diodes , 2007 .

[40]  Xiaogang Peng,et al.  Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility , 1997 .

[41]  Miroslaw Batentschuk,et al.  Silica‐Coated InP/ZnS Nanocrystals as Converter Material in White LEDs , 2008 .

[42]  E. Fred Schubert,et al.  Light-Emitting Diodes , 2003 .

[43]  Andreas Kornowski,et al.  CdSe/CdS/ZnS and CdSe/ZnSe/ZnS Core−Shell−Shell Nanocrystals , 2004 .

[44]  V. Bulović,et al.  Large‐Area Ordered Quantum‐Dot Monolayers via Phase Separation During Spin‐Casting , 2005 .

[45]  Peter Reiss,et al.  Highly Luminescent CdSe/ZnSe Core/Shell Nanocrystals of Low Size Dispersion , 2002 .

[46]  A. McGaughey,et al.  Surface chemistry mediates thermal transport in three-dimensional nanocrystal arrays. , 2013, Nature materials.

[47]  Yongfang Li,et al.  Bright, multicoloured light-emitting diodes based on quantum dots , 2007 .

[48]  Kyung-Sang Cho,et al.  Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles. , 2005, Journal of the American Chemical Society.

[49]  Darryl L. Smith,et al.  Energy-transfer pumping of semiconductor nanocrystals using an epitaxial quantum well , 2004, Nature.

[50]  V. Bulović,et al.  NiO as an inorganic hole-transporting layer in quantum-dot light-emitting devices. , 2006, Nano letters.

[51]  Klavs F. Jensen,et al.  Full Color Emission from II–VI Semiconductor Quantum Dot–Polymer Composites , 2000 .