Influences of low temperature silicon nitride films on the electrical performances of hydrogenated amorphous silicon thin film transistors

Influences of silicon nitride (SiNx) films on the electrical performances of hydrogenated amorphous silicon thin film transistors (a-Si : H TFTs) are studied. Relatively low temperature (200 °C) SiNx films are prepared by plasma enhanced chemical vapour deposition at different radio-frequency powers. Results indicate that the SiNx films at a radio-frequency power of 340 W (Power density = 1.96 × 10−1 W cm−2) are near-stoichiometric and have better interface quality. Therefore, a-Si : H TFTs with this SiNx gate dielectric layer have a high field effect mobility and sustain the bias stress. The field effect mobility is 0.59 cm2 V−1 s−1 and the threshold voltage shift after a constant voltage stress (CVS) for 2.8 h is 3.18 V. The electrical degradation mechanism of a-Si : H TFTs is studied from the capacitance–voltage measurement. The degradation of the a-Si : H TFT after CVS is due to the defect generation in the SiNx gate dielectric and a-Si : H active layers. However, when the surface roughness of the SiNx film is poor, the degradation from the a-Si : H/SiNx interface is predominated. Therefore, if the SiNx film is used as a gate dielectric layer to fabricate a-Si : H TFTs, the surface roughness and chemical composition of the SiNx film should be considered simultaneously.

[1]  Arokia Nathan,et al.  Dielectric performance of low temperature silicon nitride films in a-Si:H TFTs , 2002 .

[2]  Fabrication of Low-Stress SiN x H y Membranes Deposited by PECVD , 2007 .

[3]  K. Takechi,et al.  High-Mobility and High-Stability a-Si:H Thin Film Transistors with Smooth SiNx/a-Si Interface , 1991 .

[4]  Eray S. Aydil,et al.  Low temperature plasma deposition of silicon nitride from silane and nitrogen plasmas , 1998 .

[5]  Properties of hydrogenated amorphous silicon thin film transistors fabricated at 150°C , 2000 .

[6]  Sadayoshi Hotta Sadayoshi Hotta,et al.  Plasma-Enhanced Chemical Vapor Deposition of Silicon Nitride , 1992 .

[7]  K. Ando,et al.  BONDING CONFIGURATIONS OF NITROGEN ABSORPTION PEAK AT 960 CM-1 IN SILICON OXYNITRIDE FILMS , 1999 .

[8]  Hsi-Chao Chen,et al.  Investigation of thermal annealing of optical properties and residual stress of ion-beam-assisted TiO2 thin films with different substrate temperatures. , 2006, Applied optics.

[9]  A. Izumi,et al.  Electrical properties of silicon nitride films deposited by catalytic chemical vapor deposition on catalytically nitrided Si(100) , 2003 .

[10]  Jerzy Kanicki,et al.  Stability of electrical properties of nitrogen-rich, silicon-rich, and stoichiometric silicon nitride films , 1989 .

[11]  P. Srivastava,et al.  Effect of low temperature oxidation on dielectric properties of mercury sensitized photo-deposited silicon nitride films , 2005 .

[12]  Y. Kuo Thin Film Transistors : Materials and Processes , 2003 .

[13]  D. Schroder Semiconductor Material and Device Characterization , 1990 .

[14]  J. Plummer,et al.  Electron mobility in inversion and accumulation layers on thermally oxidized silicon surfaces , 1980 .

[15]  B. Hekmatshoar,et al.  Effect of $\hbox{SiN}_{x}$ Gate Dielectric Deposition Power and Temperature on a-Si:H TFT Stability , 2007, IEEE Electron Device Letters.

[16]  S. Fonash,et al.  Characteristics of low-temperature silicon nitride (SiNx:H) using electron cyclotron resonance plasma , 2000 .

[17]  G. Parsons,et al.  Low hydrogen content stoichiometric silicon nitride films deposited by plasma‐enhanced chemical vapor deposition , 1991 .

[18]  A. Nathan,et al.  Stability of nc-Si:H TFTs With Silicon Nitride Gate Dielectric , 2007, IEEE Transactions on Electron Devices.

[19]  Y. Kuo Etch mechanism in the low refractive index silicon nitride plasma-enhanced chemical vapor deposition process , 1993 .