Improvement of interfacial shear strengths of polybenzobisoxazole fiber/epoxy resin composite by n-TiO2 coating

Smooth polybenzobisoxazole (PBO) fiber has limited interfacial interaction with resin matrix. In this article, nano-TiO2 coating on PBO fiber is applied to improve the interfacial adhesion between PBO fiber and epoxy resin. The test results suggest that the PBO fiber had good interaction with epoxy resin matrix after its treatment with n-TiO2 sol. Nano TiO2 particle embedded onto PBO fiber surface, acting as a chock, which made fiber implanted into the resin better. This greatly improved the shear strengths (IFSS) of PBO fiber/epoxy resin composite. It has been found that a 56% increase in interfacial IFSS has achieved without sacrificing mechanical properties of fiber. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013

[1]  Bo Song,et al.  Study on photoaging of poly(p‐phenylene benzobisoxazole) fiber , 2012 .

[2]  Bo Song,et al.  Effect of Heat Treatment on Properties and Structural Changes of Poly(p-Phenylene Benzobisoxazole) Fiber , 2011 .

[3]  Bo Song,et al.  Mechanism of degradation of poly(p-phenylene benzobisoxazole) under hydrolytic conditions , 2011 .

[4]  Q. Zhuang,et al.  Protonation Effect of Polybenzoxazole: Experimental Evidence , 2010 .

[5]  Q. Zhuang,et al.  Rigid‐rod polybenzoxazoles containing perylene bisimide: Synthesis, structures and photophysical properties , 2010 .

[6]  Q. Zhuang,et al.  Synthesis and photoluminescence stability of non-conjugated polymers based on fluorene and benzoxazole , 2010 .

[7]  Ping Chen,et al.  Effects of oxygen plasma treatment power on surface properties of poly(p-phenylene benzobisoxazole) fibers , 2008 .

[8]  Q. Zhuang,et al.  Shear flow behaviors of poly(p-phenylene benzobisoxazole) spinning dope , 2008 .

[9]  J. Wosnitza,et al.  Adhesion of PBO fiber in epoxy composites , 2007 .

[10]  Wu Gwo-Mei Oxygen plasma treatment of high performance fibers for composites , 2004 .

[11]  Soojin Park,et al.  Relationship between surface characteristics and interlaminar shear strength of oxyfluorinated carbon fibers in a composite system. , 2003, Journal of colloid and interface science.

[12]  A. T. Seyhan,et al.  Investigating the effects of a polyester preforming binder on the mechanical and ballistic performance of E-glass fiber reinforced polyester composites , 2003 .

[13]  R. Young,et al.  Deformation of PBO/epoxy plain weave fabric laminae followed using Raman spectroscopy , 2001 .

[14]  A. Sen,et al.  Improved interfacial adhesion via chemical coupling of cis-polybenzobisoxazole fibre-polymer systems , 1996 .

[15]  J. Mcgrath,et al.  Synthesis and characterization of fluorinated polybenzoxazoles via solution cyclization techniques , 1994 .

[16]  David C. Martin,et al.  Ultrastructure of poly(p-phenylenebenzobisoxazole) fibers , 1991 .

[17]  J. Im,et al.  Some Physical and Mechanical Properties of Pbo Fiber , 1988 .

[18]  Bernard Miller,et al.  A microbond method for determination of the shear strength of a fiber/resin interface , 1987 .