Quantitative mechanistic studies of the photoreactions of trinuclear metal carbonyl clusters of iron, ruthenium and osmium

[1]  A. Friedman,et al.  Photoreactions of the triruthenium cluster HRu3(CO)10 (.mu.-COCH3). Isomerization of the bridging alkylidyne ligand and competing ligand substitutions , 1989 .

[2]  W. Gladfelter,et al.  The reactivity of decacarbonylnitrosyltriruthenate: synthesis and characterization of [Ru(CO)3(NO)]− , 1988 .

[3]  H. Gafney,et al.  Thermal and photochemical reactions of triruthenium dodecacarbonyl adsorbed onto porous Vycor glass , 1988 .

[4]  M. Gallop,et al.  Photoisomerisation of benzenetriosmium cluster complexes: a model for arene activation on flat metal surfaces , 1988 .

[5]  M. Wrighton,et al.  Wavelength-dependent primary photoprocesses of triosmium dodecacarbonyl in fluid solution and in rigid alkane glasses at low temperature: spectroscopic detection, characterization, and reactivity of coordinatively unsaturated triosmium undecacarbonyl , 1987 .

[6]  M. Wrighton,et al.  Wavelength-, medium-, and temperature-dependent competition between photosubstitution and photofragmentation in triruthenium dodecacarbonyl and triiron dodecacarbonyl: detection and characterization of coordinatively unsaturated trimetal undecacarbonyl complexes , 1987 .

[7]  A. Friedman,et al.  Photoisomerization of the ruthenium cluster HRu3(CO)10(.mu.-COCH3), an unprecedented oxygen-to-carbon alkyl migration. , 1986, Journal of the American Chemical Society.

[8]  V. Sekhar,et al.  Photofragmentation and photosubstitution kinetics of dodecacarbonyltriosmium , 1986 .

[9]  D. Wink,et al.  Photoreactions of the triruthenium cluster Ru/sub 3/(CO)/sub 12/ and substituted analogues , 1986 .

[10]  J. Takats,et al.  Photochemical reactivity of Os3(CO)12 and thermal activation of diosmacyclobutanes towards alkynes , 1986 .

[11]  T. Meyer,et al.  Photochemistry of Metal-Metal Bonds , 1985 .

[12]  Takayoshi Kobayashi,et al.  Laser photolysis study on the photosubstitution in dimanganese and dirhenium decacarbonyls , 1985 .

[13]  A. Stiegman,et al.  Photochemical disproportionation of metalmetal bonded carbonyl dimers , 1985 .

[14]  D. Wink,et al.  Flash photolysis of triruthenium dodecacarbonyl. Evidence for intermediates in the competing fragmentation and ligand-substitution photoreactions of Ru3(CO)12 , 1985 .

[15]  R. Herrick Flash Photolysis Studies of Dinuclear Manganese Carbonyl Compounds , 1984 .

[16]  M. Wrighton,et al.  Photochemical conversion of H2Os3(CO)10(P-donor) to H2Os3(CO)9(P-donor) in solution and on high-surface-area silica , 1984 .

[17]  Deborah E. Samkoff,et al.  Structural studies on polynuclear osmium carbonyl hydrides. 25. Synthesis, characterization, and reversible photochemical/thermal interconversion of .eta.1- and .eta.2-bridged (aryldiazo)triosmium clusters. Crystal structure of (.mu.-H)Os3(CO)10(.mu.-.eta.2-N:NPh) , 1984 .

[18]  I. Horváth,et al.  Synthesis of sulfidoosmium carbonyl cluster compounds by the photochemical decomposition of HOs3(CO)10(μ-SPh) and its subsequent reactions with selected small molecules. Synthesis and crystal and molecular structure of Os3(CO)9(μ3-CO)(μ3-S) , 1984 .

[19]  I. Horváth,et al.  Unusual metal-metal bonding in transition-metal carbonyl cluster compounds. The synthesis, reactivity, and crystal and molecular structure of [Os3(CO)8(μ3-S)2]2 , 1984 .

[20]  G. Geoffroy,et al.  Photoinduced formation of phosphido-bridged clusters derived from Ru3(CO)9(PPh2H)3. Crystal and molecular structure of Ru3(μ-H)(μ-PPh2)3(CO)7 , 1983 .

[21]  G. Maciel,et al.  Characterization and photochemistry of surface-confined mononuclear and trinuclear phosphine/carbonyl complexes of ruthenium(0). Interim technical report , 1983 .

[22]  J. Takats,et al.  Photochemical synthesis of olefin-carbonylosmium complexes: serendipitous formation of a 1,2-diosmacyclobutane derivative , 1983 .

[23]  A. Poë,et al.  PHOTOCHEMICAL FRAGMENTATION KINETICS OF TRIRUTHENIUM DODECACARBONYL , 1982 .

[24]  M. Desrosiers,et al.  Photochemical fragmentation of the cluster Ru3(CO)12: evidence against homolytic bond cleavage , 1982 .

[25]  B. Delley,et al.  Spectroscopic and theoretical studies of metal cluster complexes. Part 2. X.alpha. calculations and spectroscopic studies of triruthenium and triosmium dodecacarbonyls , 1982 .

[26]  H. C. Foley,et al.  Photochemistry of the tetranuclear clusters tridecacarbonyldihydrotetraruthenium, tridecacarbonyldihydroirontriruthenium, and tridecacarbonyldihydroirontriosmium , 1981 .

[27]  W. Trogler,et al.  Electronic structures of transition metal cluster complexes , 1981 .

[28]  J. Takats,et al.  (.eta.2-Olefin)tetracarbonylruthenium complexes: photochemical syntheses from dodecacarbonyltriruthenium and quantum yield determinations , 1981 .

[29]  M. Wrighton,et al.  HYDROGEN ISOTOPE EFFECTS ON THE EXCITED-STATE DECAY PROPERTIES OF POLYNUCLEAR METAL CARBONYL HYDRIDES. EMISSION PROPERTIES OF (DODECACARBONYL)TETRAKIS(HYDRORHENIUM) AND BIS(TETRABUTYLAMMONIUM)(DODECACARBONYL)HEXAHYDROTETRARHENATE , 1981 .

[30]  H. Gray,et al.  Studies of the photochemical behavior of Fe/sub 3/(CO)/sub 11//sup 2 -/ in solution , 1981 .

[31]  H. Gray,et al.  Studies of the photoreactions of dodecacarbonyltriosmium with chlorocarbons and with triphenylphosphine in solution , 1980 .

[32]  R. Sanner,et al.  Photoactivation of cluster catalysis: a comparison of 1-pentene isomerization by tetracarbonyl(triphenylphosphine)ruthenium and 1,1,1,2,2,2,3,3,3-nonacarbonyl-1,2,3-tris(triphenylphosphine)-triangulo-triruthenium , 1979 .

[33]  H. Gray,et al.  Electronic structures and spectra of trinuclear carbonyl complexes , 1978 .

[34]  G. Geoffroy,et al.  Photoinduced declusterification of nonacarbonyl(.mu.3-methylidyne)tricobalt, nonacarbonyl(.mu.3-ethylidyne)tricobalt, and tricarbonylhydro(tri-.mu.-carbonylhexacarbonyltricobalt)iron , 1977 .

[35]  M. Wrighton,et al.  Ordering the reactivity of photogenerated, 17 valence electron, metal carbonyl radicals , 1977 .

[36]  M. Wrighton,et al.  Photooxidation of a tetranuclear cluster complex in the presence of halocarbons. Photochemistry of the carbonyl(.eta.5-cyclopentadienyl)iron(I) tetramer , 1977 .

[37]  R. Laine,et al.  Reactivity of metal radicals generated photochemically. Effects of solvent and of trapping agent concentrations on quantum yields for photolysis of hexacarbonylbis(.pi.-cyclopentadienyl)ditungsten(I), [.pi.-CpW(CO)3]2 , 1977 .

[38]  M. Twigg,et al.  Photochemical reactions of Ru3(CO)12 involving metalmetal bond fission , 1974 .

[39]  W. Cullen,et al.  Preparation and characterization of fluorocarbon-bridged di(tertiary phosphine and arsine) complexes derived from triruthenium dodecacarbonyl , 1970 .