Organometallic Chemistry of Arene Ruthenium and Osmium Complexes

[1]  C. Bruneau,et al.  Acetylene in Catalysis: a One-step Synthesis of Vinylcarbamates with [RuCl2(norbornadiene)]n , 1988 .

[2]  E. Piers,et al.  Deconjugation-alkylation of ethyl 3-(trimethylstannyl)-2-alkenoates. Stereocontrolled synthesis of ethyl 2-alkylidene-3-methylenecyclobutanecarboxylates , 1988 .

[3]  P. Dixneuf,et al.  Synthesis of .beta.-oxopropyl esters by catalytic addition of carboxylic acids and N-protected amino acids to propargyl alcohol , 1988 .

[4]  A. Shaver,et al.  Chemistry of cyclopentadienylruthenium and -osmium complexes. 4. The facile synthesis of cyclopentadienylruthenium(IV) and -osmium(IV) allyl complexes and the characterization of a novel ruthenium(IV) intermediate in the dehydrohalogenation and dehydrogenation of 3-bromocyclohexene. The x-ray crysta , 1987 .

[5]  H. Werner,et al.  Hydride Abstraction From [C6H6Os(CO)(CH3)2]: Does a Metal‐bound Methyl Group Migrate Preferentially to a CO or to a CH2 Ligand? , 1987 .

[6]  N. N. Greenwood,et al.  Organo-ruthenaborane and -osmaborane cluster compounds: preparation and NMR studies of [6-(η6-C6Me6)-nido-6-MB9H13] (M = Ru, Os) and the rearranged cluster [5-(η6-C6Me6)-nido-5-RuB9H11-7-(PMe2Ph)] , 1987 .

[7]  M. Rybinskaya,et al.  Synthesis of cationic metallocyclophanes with arene and cyclopentadienyl ligands , 1987 .

[8]  L. Oro,et al.  Synthesis of ruthenium-palladium and ruthenium-rhodium complexes linked by pyrazolate groups and chlorine atoms. Crystal structure of [(p-cymene)ClRu(μ-Cl)(μ-pz)Pd(C8H11)] , 1987 .

[9]  H. Werner,et al.  A Novel Route to Azaalkenylidene‐Metal Complexes , 1987 .

[10]  H. Higuchi,et al.  The synthesis and electrochemical behavior of bis (η6-hexamethylbenzene)(η6,η6-triple-layered [2.2]paracyclophane)diruthenium(II,II) tetrakis(tetrafluoroborate) and its related mixed-valence ion , 1987 .

[11]  J. Atwood,et al.  REACTIVITY OF THE DIPHOSPHINE Ph2PCH2PPh2WITH [(η6-p-CH3C6H4Pri)RuCl2]2. CRYSTAL STRUCTURES OF RUTHENIUM COMPLEXES CONTAINING MONODENTATE AND SINGLY-BRIDGING DIPHOSPHINE LIGANDS , 1987 .

[12]  M. Walkinshaw,et al.  Reactions of phosphine, arsine, and stibine with carbonylbis(triethylphosphine)iridium(I) halides. Part 1. Reactions in toluene; X-ray crystal structures of [Ir(CO)ClH(PEt3)2(AsH2)] and [Ir(CO)XH(PEt3)2(µ-ZH2)RuCl2(η6-MeC6H4CHMe2-p)](X = Br, Z = P; X = Cl, Z = As) , 1987 .

[13]  N. N. Greenwood,et al.  The isolation and characterisation of the 1- and 2-isomers of nido-[(η6-C6Me6)RuB9H13]—but is the 1-isomer nido or arachno? , 1987 .

[14]  C. Bruneau,et al.  Catalytic synthesis of O-β-oxoalkylcarbamates , 1987 .

[15]  P. Dixneuf,et al.  Ruthenium-catalyzed synthesis of vinyl carbamates from carbon dioxide, acetylene, and secondary amines , 1987 .

[16]  Malcolm L. H. Green,et al.  Synthesis using metal atoms of [RuH(?-C6H6)(PMe3)(?-C6H5)], [OsH(?-C6H6)(PMe3)(?-C6H5)], [MnH(?-C6H6)(PMe3)2], and [Mn(?-C5H5)(PMe3)3]: arene ligand-exchange reactions of [RuH(?-C6H6)(PMe3)(?-C6H5)] , 1987 .

[17]  R. Moriarty,et al.  A new method for indole functionalization. Nucleophilic displacement reactions of [η6-(4- or 5-chloroindole)](η5-cyclopentadienyl)ruthenium(II) hexafluorophosphates , 1987 .

[18]  M. Gallop,et al.  Scalar coupling to naturally abundant 187Os: a new probe of the fluxionality of osmium carbonyl cluster complexes , 1987 .

[19]  A. Orpen,et al.  Co-ordination of benzyne at tetra- and pentra-ruthenium centres: a model for dissociative chemisorption of benzene on a stepped metal (111) surface , 1987 .

[20]  N. N. Greenwood,et al.  Organoruthenaborane chemistry. Part 5. Products of the reaction between closo-[B10H10]2– and [(η6-C6Me6)ClRuB3H8]. Nuclear magnetic resonance studies and the crystal and molecular structure of [{(η6-C6Me6)2Ru2H4}RuB10H8(OEt)2] , 1987 .

[21]  M. A. Bennett,et al.  Preparation of Hydrido η6-Hexamethylbenzene Complexes of Ruthenium(II) Containing Various Tertiary Phosphines. Displacement of Coordinated Triphenylarsine or Triphenylstibine From RuHCl (η6-C6Me6)L (L = AsPh3, SbPh3) , 1987 .

[22]  N. N. Greenwood,et al.  The preparation of [Ru(NCMe)6][7-(η6-C6Me6)-nido-7-RuB10H13]2 and its characterization by single-crystal X-ray diffraction analysis and nuclear magnetic resonance spectroscopy: a triply hydrogen-bridged eleven-vertex nido-7-metallaundecaborane , 1987 .

[23]  P. Dixneuf,et al.  Formation of arene(carbene)ruthenium complexes via vinylideneruthenium intermediates , 1986 .

[24]  N. N. Greenwood,et al.  arachno-[(η6-C6Me6)RuB8H14]; a nine-vertex structural analogue of n-B9H15 rather than of iso-B9H15 , 1986 .

[25]  A. Shaver,et al.  The chemistry of cyclopentadienyl-ruthenium and -osmium complexes. 1. The preparation and substitution reactions of (.eta.4-cycloocta-1,5-diene)(.eta.5-cyclopentadienyl)haloruthenium(II) complexes. Versatile new synthetic precursors to open-face cyclopentadienylruthenium(II) chemistry , 1986 .

[26]  R. Finke,et al.  Bis(.eta.6-Hexamethylbenzene)[.eta.4,.eta.6-[24](1,2,4,5)cyclophane]diruthenium(0,II) bis(tetrafluoroborate). A novel mixed-valence ion (class II) exhibiting a net two-electron intervalence transfer , 1986 .

[27]  R. Roulet,et al.  Chemistry derived from ruthenium atoms. 2. Synthesis and reactivity of the monocarbonyl complexes formed from ruthenium-cyclohexadiene cocondensates , 1986 .

[28]  H. Werner,et al.  Formation of four-membered OsC2P metallaheterocycles via cationic hydrido- and deuterido-methylene intermediates: an unprecedented example of intramolecular CH-activation , 1986 .

[29]  H. Werner,et al.  Basische metalle.: LVII. Bildung und struktur von [C6Me6RuH(NH2Pri)PMe3]PF6: Beispiel einer reduktiven aminierung von aceton durch einen dihydridometall-komplex , 1986 .

[30]  N. N. Greenwood,et al.  Hexamethylbenzene-ruthenaborane and -osmaborane chemistry , 1986 .

[31]  H. Dieck,et al.  Ruthenium complexes with diazadienes. 4. Arene diazadiene ruthenium(II) complexes [(.eta.6-arene)(RN:CR':CR':NR)Ru(L)]n+ (n = 1, L = Cl, I, alkyl; n = 2, L = MeCN, .eta.2-C2H4) and arene diazadiene ruthenium(0) , 1986 .

[32]  H. Werner,et al.  Aromaten(phosphan)metall-komplexe: XI. Fünfgliedrige osma-heterocyclen durch alkin-insertion in eine OsI- oder Os-H-bindung , 1986 .

[33]  V. Boekelheide,et al.  Ruthenium complexes of [2n]cyclophanes. A general synthesis of bis(.eta.6-[2n]cyclophane)ruthenium(II) compounds and related chemistry , 1986 .

[34]  H. Werner,et al.  Aromaten(phosphan)metall-Komplexe, XII. Unerwartete Bildungsweise der Monohydrido(phosphan)-osmium(II)-Komplexe C6H6OsH[PMe2(OR)]I aus C6H6Os(PMe2H)I2. Eine Verbindung mit einer OsPMe2-Bindung als Zwischenstufe? , 1986 .

[35]  H. Werner,et al.  Ethylen(hydrido)-metallkomplexe aus M(CH2)CH3-vorstufen: modellreaktionen für einen elementarschritt der fischer-tropsch-synthese , 1986 .

[36]  H. Buergi,et al.  Syntheses and NMR spectra of ruthenium(II) .eta.5-dienyl .eta.6-arene compounds. The crystal and molecular structure of ruthenium(II) .eta.5-cyclooctadienyl .eta.6-p-toluenesulfonate, Ru(.eta.5-C8H11)(.eta.6-C7H7SO3) , 1986 .

[37]  H. Werner,et al.  Cycloadditionsreaktionen von organometallkomplexen: VIII. Vinyliden-metallkomplexe als bausteine für neuartige fünfgliedrige metalla-heterocyclen☆ , 1986 .

[38]  P. Dixneuf,et al.  A novel catlytic synthesis of vinyl carboamtes from carbon dioxide, diethylamine, and alkynes in the presence of Ru3(CO)12 , 1986 .

[39]  H. Adams,et al.  The reactions of the tri-µ-hydroxo-bis[η6-p-cymeneosmium(II)] cation with aldehydes and acids and the homogeneously catalysed oxidation of acetaldehyde and propionaldehyde with water. X-Ray structure of [(p-MeC6H4CHMe2)2Os2(µ-HCO2)(µ-OH)(µ-H)][PF6] , 1986 .

[40]  P. Guenot,et al.  Carbon-carbon coupling and alkylation of furan and thiophene, involving C-H bond activation, with ruthenium catalysts in alcohols , 1986 .

[41]  A. Siedle,et al.  Organometallic chemistry of fluorocarbon acids. Synthesis and structural and dynamic properties of (.pi.-arene)Ru(H)(PPh3)2+ derivatives , 1986 .

[42]  P. Dixneuf,et al.  One-step synthesis of vinyl carbamates catalyzed by mononuclear ruthenium complexes via addition of carbon dioxide and amine to terminal alkynes , 1986 .

[43]  P. Dixneuf,et al.  Synthesis of enol esters from terminal alkynes catalyzed by ruthenium complexes , 1986 .

[44]  J. McCleverty,et al.  Reactions of benzene–ruthenium(II) complexes with pyrazoles. Possible formation of amidine complexes [Ru(η-C6H6){NHCMe(R2pz)}(R2Hpz)]2+(R = H or Me, Hpz = pyrazole) , 1986 .

[45]  Román E. Enrique,et al.  A novel access to the anionic permethylated fac-tripod ligand [C5Me5Co&P(O)(OEt)2&3]−, and its derived trinuclear and binuclear complexes , 1986 .

[46]  M. Martínez-Ripoll,et al.  Preparation, characterization and crystal structure of N,N-dimethylanilinium β-octamolybdate dihydrate , 1986 .

[47]  Malcolm L. H. Green,et al.  Arene–osmium chemistry: synthesis via osmium atoms of [Os(η6-C6H6)(η4-C6H6)],[{OS(η6-C6H3Me3-1,3,5)}2(µ-H)2{µ-CH(C6H3Me2-3,5)}], [{OS(η6-C6H3Me3-1,3,5)}2(µ-CHC6H3Me2-3,5)], and [{OS(η6-C6H6)}3{µ3-(CH2)3CH}(µ-H)3]. X-Ray crystal structure of [{Os(η6-C6H3Me3-1,3,5)}2(µ-CHC6H3Me2-3,5)] , 1986 .

[48]  F. Lahoz,et al.  Heterobinuclear pyrazolate-bridged ruthenium(II)―rhodium(I), iridium(III)―rhodium(I), and rhodium(III)―iridium(I) complexes: crystal structure of [(p-cymene)Ru(μ-Cl)2(μ-pz)Rh(tetrafluorobenzo[5.6]bicyclo[2.2.2]octan-2,5,7-triene)] , 1985 .

[49]  H. Werner,et al.  Aromaten(phosphan)metall‐Komplexe, IX. Synthese und Elektrophilie dikationischer (Aromaten)metall(II)‐Komplexe des Typs [C6R6′M(PMe3)2C2H3R]2+ (M Ru, Os) , 1985 .

[50]  H. Werner,et al.  Aromaten(phosphan)metall-komplexe: X. Protonierungsreaktionen der dimethylruthenium(II)-verbindungen C6Me6Ru(CH3)2PR3 und eine metallzentrierte bildung von 2-styryldiphenylphosphan , 1985 .

[51]  P. Maitlis,et al.  Mononuclear η6-p-cymeneosmium(II) complexes and their reactions with Al2Me6 and other methylating reagents , 1985 .

[52]  T. A. Stephenson,et al.  Synthesis and reactions of some heterobimetallic and multimetallic complexes containing η-arene-ruthenium(II), -osmium(II) and η-Pentamethylcyclopentadienyl-rhodium(III) moieties , 1985 .

[53]  Y. Struchkov,et al.  Synthesis of substituted π-cyclopentadienyl complexes of ruthenium, rhodium and iridium by a novel reaction of intramolecular condensation of π-allyl ligand and alkyne: X-ray structure of [η-C6H6Ru(η-C5H3Ph2-1,2)]BF4 , 1985 .

[54]  H. Werner,et al.  Studien zur CH-aktivierung: III. Vorstufen für ein 16-elektronen-fragment [C6H6Os(PR3)] und bildung von aryl(hydrido)osmium(II)-komplexen durch intermolekulare CH-addition , 1985 .

[55]  J. Huffman,et al.  Synthesis of (.pi.-arene)metallacarbaboranes containing ruthenium or osmium and a (.pi.-cyclohexadienyl)cobaltacarbaborane. Crystal structure of 2,5,6-(.eta.-C6H6)RuC2B7H11 , 1985 .

[56]  P. Raithby,et al.  Benzene in a new face-capping bonding mode: molecular structures of [Ru6C(CO)11(µ3-η2: η2:η2-C6H6)(η6-C6H6)] and [Os3(CO)9(µ3-η2: η2:η2-C6H6)] , 1985 .

[57]  Malcolm L. H. Green,et al.  Formation of the trinuclear osmium cluster [Os(η-C6H6)(µ-H)]3{µ3-(CH2)3CH} involving activation of the three methyl groups of 2-methylpropane , 1985 .

[58]  H. Werner,et al.  Novel p-cymene-osmium(II) and -osmium(0) complexes: a ring ligand determining inter-vs. intra-molecular C–H addition , 1985 .

[59]  J. Segal.  Aromatic polyether synthesis via activated in a ruthenium(II) complex of p-dichlorobenzene , 1985 .

[60]  H. Werner,et al.  Novel benzeneosmium complexes containing alkynyl, vinyl and vinylidene groups as ligands , 1985 .

[61]  W. Wickramasinghe,et al.  Protonation of dicyclopentadiene complexes of ruthenium(0), osmium(0), rhodium(I), and iridium(I). Single-crystal X-ray study of [Os(2,3,5-η-C10H13)(η-C6H 3Me3-1,3,5)]PF6, a complex containing an Os-H-C interaction , 1985 .

[62]  C. Burschka,et al.  Aromaten(phosphan)metall-komplexe: VIII. Synthese und struktur eines diaromatenruthenium-komplexes mit π-gebundenem triphenylphosphan-liganden , 1984 .

[63]  R. Lazzaroni,et al.  (η6-Arene)(η4-cycloocta-1,5-diene)ruthenium(0) complexes as homogeneous hydrogenation catalysts , 1984 .

[64]  M. A. Bennett,et al.  Synthesis of monohydridohexamethylbenzeneruthenium(II) complexes containing group V donor ligands. Isomerism arising from cyclometallation of a tertiary phosphine at aliphatic and aromatic carbon atoms , 1984 .

[65]  M. A. Bennett,et al.  Synthesis and spectroscopic characterization of dinuclear mono(.mu.-hydrido)arene complexes of divalent ruthenium , 1984 .

[66]  K. R. Mann,et al.  Effect of arene substituents and temperature on the arene replacement reactions of ((eta/sup 5/-C/sub 5/H/sub 5/)Fe(eta/sup 6/-arene))/sup +/ and ((eta/sup 5/-C/sub 5/H/sub 5/)Ru(eta/sup 6/-arene))/sup +/ , 1984 .

[67]  K. R. Mann,et al.  Effect of arene substituents and temperature on the arene replacement reactions of [(η5-C5H5)Fe(η6-arene)]+ and [(η5-C5H5)Ru(η6-arene)]+ , 1984 .

[68]  N. Taylor,et al.  Phosphido-bridged mixed-metal (ruthenium/cobalt) compounds via the reaction of (arene)RuCl2(PPh2X) (X = H, Cl) with Co2(CO)8: x-ray structure of RuCo2(.mu.-PPh2)2(.mu.-CO)(CO)7 , 1984 .

[69]  A. N. Kitaigorodskii,et al.  Reactivity of arenecyclopentadienylruthenium cations , 1984 .

[70]  D. Tocher,et al.  Structural characterisation of hydroxo-bridged arene-ruthenium and -osmium complexes: Further reactions of hydroxo-bridged complexes , 1984 .

[71]  D. Tocher,et al.  Synthesis and reactions of some triple alkoxo- and thioato-bridged areneruthenium(II) complexes. X-ray structure determination of [Ru2(η-C6H6)2(OMe)3][BPh4] , 1984 .

[72]  A. Coleman,et al.  Dehalogenation of binuclear arene-ruthenium complexes: a new route to homonuclear triruthenium and heteronuclear ruthenium-iron cluster complexes containing chelating phosphorus ligands. Crystal structure of Ru3(CO)10(Ph2PCH2PPh2) , 1984 .

[73]  V. Boekelheide,et al.  Conversion of .eta.4,.eta.6-bis(arene)ruthenium(0) complexes to cyclohexadienyl analogs of ruthenocene , 1984 .

[74]  R. Morris,et al.  Benzene carbon-hydrogen bond activation using Ru(C6Me6)[PH(C6H11(2]H2 , 1984 .

[75]  Malcolm L. H. Green,et al.  (η6-Arene)osmium chemistry: crystal structure of [(η6-C6H3Me3)Os(µ-CHC6H3Me2-3,5)Os(η6-C6H3Me3)] , 1984 .

[76]  P. Pertici,et al.  Arene ligand exchange reactions in (η4-cyclo-octa-1,5-diene)(η6-naphthalene)ruthenium(0): a convenient route to new ruthenium(0) complexes , 1984 .

[77]  W. Gladfelter,et al.  η4-Bonding in (arene)ruthenium complexes of octamethylnaphthalene , 1984 .

[78]  H. Werner,et al.  Aromaten(phosphan)metall‐Komplexe, V. Zur Addition von Carbanionen an (Benzol)ruthenium(II)‐ und ‐osmium(II)‐Komplexe. Kristall‐ und Molekülstruktur von (exo‐6‐n‐C4H9‐η5‐C6H6)OsI(PMe3)2 , 1984 .

[79]  H. Werner,et al.  Aromaten(phosphan)metall‐Komplexe, VI. Synthese von [(RC6H5)OsI(PMe3)2PF6 aus (exo‐6‐RC6H6)OsI(PMe3)2: Ein Beitrag zum Mechanismus der Aromatisierung substituierter Cyclohexadienylliganden durch „endo‐H‐Abstraktion”︁ , 1984 .

[80]  Y. Chung,et al.  Dependence of the electrophilicity of coordinated cyclic π-hydrocarbons on the metal in the chromium, manganese, and iron triads , 1983 .

[81]  H. Werner,et al.  Aryl(hydrido)ruthenium Complexes by C ? H Addition: Isolation of a Four‐Membered Metallacycle as Intermediate , 1983 .

[82]  V. Boekelheide,et al.  Syntheses of [22](1,4)cyclophane-ruthenium(II) complexes via the mono-Birch reduction product of 4,5,7,8-tetramethyl[22](1,4)cyclophane , 1983 .

[83]  M. Rosenblum,et al.  ([2.2]Paracyclophane)iron(II) complexes. Synthesis and intramolecular charge-transfer interactions , 1983 .

[84]  H. Werner,et al.  Metallabis(phosphonate) als chelatliganden: V. Synthese und struktur von benzolbis(dimethylphosphonat)osmium(II)-komplexen. Anpassung der kristallstruktur des anions C6H6OsI[P(O)(OMe)2]2− an das gegenion H+ oder Na+ , 1983 .

[85]  J. Guss,et al.  Cluster chemistry: XXII. Crystal structures of [M3(μ3-C6H4)(μ-PPh2)2(CO)7], M Ru and Os , 1983 .

[86]  H. Werner,et al.  Aromaten(phosphan)metall-Komplexe, III. Die Metall-Basen C6H6M(PMe3)C2H3R und ihre korrespondierenden Säuren [C6H6MH(PMe3)C2H3R]+ , 1983 .

[87]  M. Rybinskaya,et al.  A new preparative route to cationic arene complexes of ruthenium(II), rhodhium(III) and iridium(III) , 1983 .

[88]  K. Itoh,et al.  SELECTIVE [π6s + π2s] CYCLOADDITION OF A COORDINATED CYCLIC TRIENE WITH ALKYNES. FORMATION OF BICYCLO[4.2.2]DECATRIENE SKELETON ON A Ru(0) TEMPLATE , 1983 .

[89]  H. Werner,et al.  Basische metalle: XLIII. Synthese kationischer trishydridoruthenium(IV)-komplexe durch protonierung neutraler dihydridoruthenium(II)-verbindungen , 1983 .

[90]  R. Finke,et al.  Multielectron-transfer electrochemistry. Two-electron reduction of bis (.eta.6-hexamethylbenzene)ruthenium(2+) and (.eta.6-hexamethylbenzene)(.eta.6-cyclophane)ruthenium(2+) complexes , 1983 .

[91]  L. Sawyer,et al.  Areneruthenium(II) carboxylates: reactions with ligands and the X-ray structure of the p-cymene pyrazine complex [Ru(η-p-MeC6H4CHMe2)Cl(pyz)2]PF6 , 1983 .

[92]  P. Raithby,et al.  Some reactions of [Os3(CO)10(NCMe)2] with arenes; the molecular structure of [Os3H2(CO)9(C6H4)] , 1983 .

[93]  H. Werner,et al.  A Model Reaction of an Elementary Step in the Fischer‐Tropsch Synthesis:[C6Me6RuH(C2H4)PR3]+ from C6Me6Ru(CH3)2PR3 , 1983 .

[94]  M. Bruce,et al.  Vinylidene and Propadienylidene (Allenylidene) Metal Complexes , 1983 .

[95]  W. Gladfelter,et al.  Synthesis, structure, and reactivity of Ru(.eta.6-C6Me6)[.eta.4-C6Me4(CH2)2]. An unusual transition-metal o-xylylene complex , 1982 .

[96]  H. Werner,et al.  Aromaten(phosphan)metall‐Komplexe, I. Die Vorstufen zur Synthese der Metall‐Basen ArM(PR3)2 und ArM(PR3)L (M = Ru, Os) , 1982 .

[97]  H. Werner,et al.  Aromaten(phosphan)metall-Komplexe, II. Synthese und Reaktivität der Metall-Basen ArM(PR3)2 und ArM(PMe3)L (M = Ru, Os) , 1982 .

[98]  R. Regragui,et al.  Nouveaux complexes heterobinucleaires a liaison ruthenium—cobalt pontee par un groupement diphenylphosphido , 1982 .

[99]  N. Cooper,et al.  Electron-transfer mechanism for a hydride-transfer reaction: evidence for selective .alpha.-hydride abstraction from a transition metal alkyl , 1982 .

[100]  M. Rybinskaya,et al.  Synthesis and reduction of cationic bis-arene-ruthenium complexes , 1982 .

[101]  M. A. Bennett,et al.  Dinuclear μ-hydrido arene complexes of ruthenium(II) , 1982 .

[102]  H. Werner,et al.  Synthese und eigenschaften stabiler hexamethylbenzol(phosphin)dimethyl- und -dihydrido-ruthenium(II)-komplexe , 1982 .

[103]  D. Tocher,et al.  Synthesis and characterisation of the mixed sandwich cations [M(η-arene)(η-C5H5)]+ (M Ru, Os) , 1982 .

[104]  R. D. Adams,et al.  Cleavage of aryl carbon-sulfur bonds by a trinuclear cluster. Reaction of alkyl phenyl sulfides with dodecacarbonyltriosmium , 1982 .

[105]  R. Lazzaroni,et al.  A simple preparation for (η6-arene)(η4-cyclo-octa-1,5-diene)ruthenium-(0) complexes and their conversion into the corresponding arene–dichlororuthenium(II) complexes , 1982 .

[106]  T. W. Turney,et al.  Reversible Double Deprotonation of Hexamethylbenzene on Ruthenium: Formation of a Fluxional trihapto‐Benzyl Compound by Protonation of an o‐Xylylene Complex of Zerovalent Ruthenium , 1982 .

[107]  K. R. Mann,et al.  Photochemical properties of the cyclopentadienyl(.eta.6-benzene)ruthenium(II) cation. The synthesis and reactions of a synthetically useful intermediate: the cyclopentadienyltris(acetonitrile)ruthenium(II) cation , 1982 .

[108]  P. Dixneuf,et al.  Synthesis and X-ray structure of [RuCo3(µ-CO)2(CO)7(µ-PPh2)(µ4-η2-ButCCH)]: a novel heteronuclear butterfly cluster via the fragmentation of a phosphinoalkyne , 1982 .

[109]  P. Maitlis,et al.  The selective reduction of benzene to cyclohexene , 1982 .

[110]  J. Huffman,et al.  Synthesis of π-(arene)metallocarboranes containing iron and ruthenium. Crystal structure of 3,1,2-(η6-1,3,5-(CH3)3C6H3)FeC2B9H11 , 1982 .

[111]  I. Bernal,et al.  Crystal and molecular structure and absolute configuration of (-)436-(.eta.6-C6H6)Ru(SnCl3)(CH3)[Ph2PNHCH(CH3)Ph] , 1981 .

[112]  P. Guenot,et al.  Synthesis of novel halo-bridged trinuclear ruthenium-iron derivatives. X-ray structure of FeRu2(.mu.-Cl)2(CO)8(Ph2PC.tplbond.C-tert-Bu)2 , 1981 .

[113]  H. Werner,et al.  Synthese von Hydrido(phenyl)-osmium(II)- aus Benzol-osmium(0)-Komplexen: Intramolekulare Insertion eines Lewis-basischen Metallatoms in eine sp2-C–H-Bindung , 1981 .

[114]  P. Tucker,et al.  Protonation of arene cyclooctatetraene complexes of zerovalent ruthenium. Single-crystal x-ray study of the isomeric cyclooctatrienyl complexes [Ru(1-5-.eta.-C8H9)(1,3,5-C6H3Me3)]PF6 and [Ru(1-3:6-7-.eta.-C8H9)(1,3,5-C6H3Me3)]PF6 , 1981 .

[115]  F. Ciardelli,et al.  Versatile polystyrene—ruthenium hydrogenation catalysts , 1981 .

[116]  H. Werner,et al.  Untersuchungen zur reaktivität von metall-π-komplexen : XXXIV. Synthese dikationisher η5-dienylphosphonium-ruthenium(II)-komplexe [(η5-C6H6PR3)RuL3]2+ und ihre reaktion zu [C6H6RuL3]2+ , 1981 .

[117]  T. Arthur,et al.  Synthesis of triple halide-bridged arene complexes of ruthenium(II) and osmium(II) , 1981 .

[118]  D. Tocher,et al.  Synthesis of binuclear hydroxo- and alkoxo-bridged arene complexes of ruthenium(II) and osmium(II) , 1981 .

[119]  P. Maitlis,et al.  Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 33. The metal-catalysed disproportionation of acetaldehyde into acetic acid and ethanol , 1981 .

[120]  P. Maitlis,et al.  Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part 30. Trimethylphosphine-chloro-, -acetato-, and -hydrido-complexes and related compounds of (hexamethylbenzene)ruthenium , 1981 .

[121]  M. Hursthouse,et al.  Solution behaviour of some benzyne complexes of osmium and the X-ray crystal structure of µ3-benzyne-1,1,1,2,2,2,3,3,3-nonacarbonyl-µ-dimethylarsino-µ-hydrido-triosmium(2Os–Os) , 1981 .

[122]  R. Finke,et al.  Multilayered transition metal complexes of cyclophanes , 1980 .

[123]  D. Robertson,et al.  Ruthenium complexes containing group VB donor ligands : IX. Cationic η6-arene and η5-cyclohexadienyl complexes of ruthenium containing nitrogen and phosphorus donor ligands , 1980 .

[124]  P. Domaille,et al.  Nucleophilic addition of tertiary phosphines to the bis(benzene)metal(II) cations of the iron triad , 1980 .

[125]  H. Werner,et al.  Basic metals : XXIII. Synthesis and reactivity of Lewis-base osmium(0) complexes , 1980 .

[126]  P. Tucker,et al.  Highly fluxional arene cyclooctatetraene complexes of zerovalent iron, ruthenium, and osmium. Single-crystal x-ray study of (cyclooctatetraene)(hexamethylbenzene)ruthenium(0), Ru(.eta.6HMB)(1-4-.eta.-COT) , 1980 .

[127]  M. Paci,et al.  A new synthetic method for the preparation of cyclo-olefin ruthenium complexes , 1980 .

[128]  D. A. Sweigart.  Trialkyl phosphite addition to the bis(benzene)-iron(II) and -ruthenium(II) dications: catalysed hydrolysis to dialkyl phosphites , 1980 .

[129]  A. Nesmeyanov,et al.  Ligand exchange at ruthenocene , 1979 .

[130]  E. Muetterties,et al.  Arene transition metal chemistry , 1979 .

[131]  T. Matheson,et al.  A simple preparation of bis-arene-ruthenium cationic complexes, including those containing different arenes , 1979 .

[132]  H. Werner,et al.  Basische metalle : XX. Synthese und reaktivität von C6Me6Ru(CO)PMe3. Ein stabiler aromaten-ruthenium(0)-carbonyl-komplex , 1979 .

[133]  H. Werner,et al.  Basische metalle : XIX. Zur reaktivität strukturanaloger ethylen-hydridound ethylen-methyl-ruthenium(II)-kationen gegenüber trimethylphosphan , 1979 .

[134]  T. Arthur,et al.  A convenient synthetic route to triple halide bridged arene complexes of ruthenium(II) and osmium(II) , 1979 .

[135]  M. Darensbourg,et al.  ARENE-TRANSITION METAL COMPLEXES. 1. SITE EXCHANGE AND CHEMICAL CHARACTERISTICS OF η6-C6(CH3)6RU-η4-C6(CH3)6 , 1979 .

[136]  A. Nesmeyanov,et al.  Allylmercury compounds, convenient reagents for synthesis of π-allyl derivatives of transition metals , 1979 .

[137]  T. Matheson,et al.  Isolation of a co-ordinated ketol intermediate in the hydrolysis of PF6– initiated by the labile cations [Ru(η6-arene)(acetone)3]2+; X-ray crystal structure of acetone(4-hydroxy-4-methylpentan-2-one)(η6-mesitylene)ruthenium bistetrafluoroborate , 1979 .

[138]  D. Astruc,et al.  Ligand exchange in ruthenocene , 1979 .

[139]  T. W. Turney,et al.  Dinuclear arene hydrido-complexes of ruthenium(II): reactions with olefins and catalysis of homogeneous hydrogenation of arenes , 1979 .

[140]  F. Faraone,et al.  Neutral binuclear and cattonic mononuclear η6-benzeneruthenium(II) complexes containing neutral bidentate ligands , 1979 .

[141]  D. Osella,et al.  Products of the reaction of Ru3(CO)12 with 1,3-cyclohexadiene. X-ray structure of (η-benzene)nonacarbonyl-1-cyclohexen-1,2-ylenetetraruthenium, Ru4(CO)9(C6H6)(C6H8) , 1979 .

[142]  H. Werner,et al.  Ein neuer Typ von Ruthenium(0)‐Komplexen mit Halbsandwichstruktur: C6H6RuL2[1] , 1978 .

[143]  Antonio Lucherini,et al.  Cyclotrimerization of acetylenic compounds with (benzene)(1,3-cyclohexadiene)ruthenium(0): preparation of bis-arene derivatives of ruthenium having different arene ligands , 1978 .

[144]  T. Matheson,et al.  Arene-olefin complexes of zerovalent iron and ruthenium , 1978 .

[145]  H. Brunner,et al.  Optically active transition metal complexes: LVI. Preparation and Stereochemistry of (+)578- and (-)578-(n-C6H6RuX(Me) [Ph2PNHCH(Me) (Ph)], where x = Cl, SnCl3 , 1978 .

[146]  R. King,et al.  Preparative applications of metal vapours obtained by evaporation of metal powders from coated filaments: a new preparation of dibenzeneruthenium and observation of its limiting n.m.r. spectrum , 1978 .

[147]  F. Faraone,et al.  (η6-C6H6)Ru(CNC6H11Cl2. A mixed arene—isocyanide complex , 1978 .

[148]  D. Robertson,et al.  Some η5-Cyclohexadienyl Complexes of Ruthenium. , 1977 .

[149]  R. Crabtree,et al.  Arene—ruthenium complexes containing nitrogen donor ligands , 1977 .

[150]  E. Muetterties,et al.  Catalytic homogeneous hydrogenation of arenes. 5. The bis(hexamethylbenzene)ruthenium catalyst , 1977 .

[151]  M. C. Baird,et al.  Chiral η6-C6H6 ruthenium complexes , 1977 .

[152]  G. Simonelli,et al.  (η4-Cyclo-octa-1,4-diene)(η6-cyclo-octa-1,3,5-triene)ruthenium(0) chemistry: the role of molecular hydrogen in a new synthetic route to cyclo-olefin ruthenium complexes , 1977 .

[153]  E. Singleton,et al.  Conversion of bonded cyclo-octadiene into a cyclo-octadienyl ligand and cleavage of boron–phenyl bonds of arene-bonded tetraphenylborate anions in ruthenium(II) systems: X-ray crystal and molecular structures of [Ru(η6-C6H5BL3)(1–3,5,6-η-C8H11)](L = Ph or F) , 1977 .

[154]  H. Brunner,et al.  Synthesis of optically active η6-benzene–ruthenium complexes , 1977 .

[155]  P. Tucker,et al.  Highly fluxional tetrahapto-cyclooctatetraene complexes of ruthenium(0) , 1976 .

[156]  D. Robertson,et al.  Cationic and anionic complexes of ruthenium(ii) containing η6-arene ligands , 1976 .

[157]  P. Maitlis,et al.  Solvolysis of the Hexafluorophosphate Ion and the Structure of [Tris(μ‐difluorophosphato)bis(penta‐methylcyclopentadienylrhodium)] Hexafluorophosphate , 1976 .

[158]  M. Mcpartlin,et al.  PRODUCTS OF THE REACTION OF (H2OS3(CO)10) WITH CYCLOHEXA-1,3-DIENE AND BUTADIENE; X-RAY STRUCTURE OF THE HEXADIENYL COMPLEX (HOS3(CO)9C6H7). , 1976 .

[159]  D. O'sullivan,et al.  Structure of poly(1-pyrazolyl)-metal complexes with carbocyclic .pi.-acceptor ligands. Synthesis, crystal, and molecular structures of [tetrakis(1-pyrazolyl)borato](.eta.6-benzene)ruthenium(II) and [hydrotris(1-pyrazolyl)borato](.eta.5-pentamethylcyclopentadienyl)rhodium(II) hexafluorophosphates , 1975 .

[160]  R. J. Haines,et al.  Reactions of metal carbonyl derivatives : XVI. A comparative study of the reactivity of chloro- dicarbonyl-η-cyclopentadienylruthenium and chlorobis(triphenylphosphine)-η-cyclopentadienyl- ruthenium towards certain nucleophiles , 1975 .

[161]  P. Pertici,et al.  Improved synthesis of cyclo-olefin complexes of ruthenium via metallic zinc reduction , 1975 .

[162]  S. Schmitt,et al.  Über die Synthese neutraler π‐Olefin‐Ruthenium‐Komplexe mittels der Isopropyl‐Grignard‐Methode , 1975 .

[163]  Jack Lewis,et al.  The chemistry of polynuclear compounds. Part XXVI. Products of the pyrolysis of dodecacarbonyl-triangulo-triruthenium and -triosmium , 1975 .

[164]  A. Z. Rubezhov,et al.  Synthesis of π-allyl-π-benzeneosmium chlorides , 1974 .

[165]  Anthony K. Smith,et al.  Arene ruthenium(II) complexes formed by dehydrogenation of cyclohexadienes with ruthenium(III) trichloride , 1974 .

[166]  G. Kruger,et al.  Preparation, and crystal and molecular structure of π-cyclopentadienyl-η-(tetraphenylborato)ruthenium(II) , 1974 .

[167]  R. Iwata,et al.  Hydrogenation of olefins by π-arene ruthenium complexes , 1973 .

[168]  M. C. Baird,et al.  Reactions of π-benzeneruthenium(II) complexes with alkylating reagents , 1972 .

[169]  M. A. Bennett,et al.  Divalent ruthenium complexes containing non-planar hexahapto-benzene , 1972 .

[170]  M. C. Baird,et al.  Benzene Complexes of Ruthenium(II) , 1972 .

[171]  G. Huttner,et al.  Transition metal complexes of cyclic π‐ligands. IV. The crystal and molecular structure of bis(hexamethylbenzene)ruthenium(0), a complex containing a bent tetrahapto benzene nucleus , 1972 .

[172]  M. C. Baird,et al.  Reactions of benzene complexes of ruthernium(II) , 1972 .

[173]  M. Bruce,et al.  Chemistry of the metal carbonyls. Part LXV. Reactions between dodecacarbonyltriruthenium and tertiary phosphines or arsines , 1972 .

[174]  E. Singleton,et al.  Cationic complexes of ruthenium(II) , 1972 .

[175]  R. J. Haines,et al.  Extraction of a phenyl group from the tetraphenylboron anion by some .pi.-cyclopentadienyl derivatives of ruthenium. Ruthenium complex containing the tetraphenylboron anion directly bonded to the metal , 1971 .

[176]  C. Elschenbroich,et al.  Über Aromatenkomplexe von Metallen, CXI über Diaromaten‐metall‐Komplexe des Rutheniums(II) und Rutheniums(0) mit Benzol und Hexamethylbenzol , 1970 .

[177]  C. Elschenbroich,et al.  Über aromatenkomplexe von metallen XCVI. über einen kationischen bisnaphthalin-π-komplex des ruthenium(II) , 1967 .

[178]  G. Winkhaus,et al.  Ruthen(II)-komplexe mit zweizähnigem cycloheptatrien und benzol , 1967 .

[179]  E. Fischer,et al.  Metall‐π‐Komplexe des Rutheniums und Osmiums mit 6‐und 8‐gliedrigen cyclischen Oligoolefinen , 1963 .

[180]  G. Wilkinson,et al.  863. π-Cyclohexadienyl compounds of manganese, rhenium, iron, and ruthenium , 1962 .

[181]  H. Fritz,et al.  π‐Komplexe benzoider Systeme mit Übergangsmetallen , 1961 .

[182]  E. Fischer,et al.  Über Aromatenkomplexe von Metallen. Ein Komplex des Ruthenium(II) mit Mesitylen , 1957 .