Electrochromic properties of hydrothermally grown Prussian blue film and device

Abstract We have demonstrated that nanostructured Prussian blue (PB) film can be directly grown on fluorine-doped tin oxide (FTO)-coated glass substrate by using a facile and template-free hydrothermal technique. The as-grown film with a lot of nanochannels is well adhesive to substrate. An electrochromic device fabricated using the as-grown PB film shows a fast coloration/bleaching response of 2.4/1.0 s and a high coloration efficiency of 87.4 cm 2  C −1 , which shows a promising application in high-performance electrochromic smart windows.

[1]  K. Ho,et al.  Amperometric detection of morphine at a Prussian blue-modified indium tin oxide electrode. , 2004, Biosensors & bioelectronics.

[2]  Vernon D. Neff,et al.  Electrochemical Oxidation and Reduction of Thin Films of Prussian Blue , 1978 .

[3]  Qing Wang,et al.  A TCO-free Prussian blue-based redox-flow electrochromic window , 2016 .

[4]  Ji Hoon Park,et al.  Graphene-based electrochromic systems: the case of Prussian Blue nanoparticles on transparent graphene film. , 2012, Chemical communications.

[5]  M. Eckhoff,et al.  Electrochromism in the mixed-valence hexacyanides. 1. Voltammetric and spectral studies of the oxidation and reduction of thin films of Prussian blue , 1981 .

[6]  M. Grätzel,et al.  Electrochromic devices based on surface-modified nanocrystalline TiO2 thin-film electrodes , 1999 .

[7]  Jinmin Wang,et al.  Flower-like nickel oxide micro/nanostructures: synthesis and enhanced electrochromic properties , 2015 .

[8]  D. He,et al.  Synthesis of two-dimensional micron-size single-crystalline Prussian blue nanosheets by hydrothermal methods assisted by glucose , 2009 .

[9]  C. Lampert,et al.  Electrochromic materials and devices for energy-efficient windows. [161 references] , 1984 .

[10]  Anders Hjelm,et al.  Recent Advances in Electrochromics for Smart Windows Applications , 1998, Optical Interference Coatings.

[11]  Chunye Xu,et al.  Highly contrasted and stable electrochromic device based on well-matched viologen and triphenylamine , 2014 .

[12]  P. R. Bueno,et al.  Electrochromic Switching Mechanism of Iron Hexacyanoferrates Molecular Compounds: The Role of Fe2+(CN)6 Vacancies , 2009 .

[13]  Joong-Kee Lee,et al.  Fullerene coated indium tin oxide counter electrode of Prussian blue electrode for enhanced electrochromic properties , 2015 .

[14]  Satyen K. Deb,et al.  Reminiscences on the discovery of electrochromic phenomena in transition metal oxides , 1995 .

[15]  A. Rougier,et al.  Room Temperature UV treated WO3 thin films for electrochromic devices on paper substrate , 2014 .

[16]  L. Vayssieres Growth of Arrayed Nanorods and Nanowires of ZnO from Aqueous Solutions , 2003 .

[17]  Yunqing Luo,et al.  Preparation, characterization, and property of polyaniline/prussian blue micro-composites in a low-temperature hydrothermal process , 2007 .

[18]  Hongjing Wu,et al.  Facile synthesis and optical properties of Prussian Blue microcubes and hollow Fe2O3 microboxes , 2015 .

[19]  Xiao Wei Sun,et al.  A bi-functional device for self-powered electrochromic window and self-rechargeable transparent battery applications , 2014, Nature Communications.

[20]  Ming Hu,et al.  Three-dimensional hierarchical Prussian blue composed of ultrathin nanosheets: enhanced hetero-catalytic and adsorption properties. , 2015, Chemical communications.

[21]  S. Creager,et al.  Inkjet-printed electrochromic devices utilizing polyaniline–silica and poly(3,4-ethylenedioxythiophene)–silica colloidal composite particles , 2008 .

[22]  T. Xu,et al.  Growth of Prussian blue microcubes under a hydrothermal condition: Possible nonclassical crystallization by a mesoscale self-assembly , 2007 .

[23]  L. Gorton,et al.  Prussian-Blue-based amperometric biosensors in flow-injection analysis. , 1996, Talanta.

[24]  Yinjuan Xie,et al.  Novel Metastable Hexagonal MoO3 Nanobelts: Synthesis, Photochromic, and Electrochromic Properties , 2009 .

[25]  M. Higuchi,et al.  Electrochromic properties of polythiophene polyrotaxane film. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[26]  Ali E Aliev,et al.  Fabrication of silver vanadium oxide and V2O5 nanowires for electrochromics. , 2008, ACS nano.

[27]  Xiao Wei Sun,et al.  Efficient synthesis of plate-like crystalline hydrated tungsten trioxide thin films with highly improved electrochromic performance. , 2012, Chemical communications.

[28]  A. Zarbin,et al.  Electrochromic properties of carbon nanotubes/Prussian blue nanocomposite films , 2013 .

[29]  Kingo Itaya,et al.  Spectroelectrochemistry and electrochemical preparation method of Prussian blue modified electrodes , 1982 .

[30]  A. Karyakin,et al.  Prussian blue based nanoelectrode arrays for H(2)O(2) detection. , 2004, Analytical chemistry.

[31]  Zhanhu Guo,et al.  Electrochromic polyaniline/graphite oxide nanocomposites with endured electrochemical energy storage , 2013 .

[32]  Johannes Svensson,et al.  Electrochromic tungsten oxide films for energy efficient windows , 1984 .

[33]  Zhen Liu,et al.  A Prussian Blue/Zinc Secondary Battery with a Bio-Ionic Liquid-Water Mixture as Electrolyte. , 2016, ACS applied materials & interfaces.

[34]  A. Zarbin,et al.  Transparent films from carbon nanotubes/Prussian blue nanocomposites: preparation, characterization, and application as electrochemical sensors , 2012 .

[35]  Lin-Chi Chen,et al.  Multicolor electrochromic thin films and devices based on the Prussian blue family nanoparticles , 2016 .

[36]  Satyen K. Deb,et al.  Opportunities and challenges in science and technology of WO3 for electrochromic and related applications , 2008 .

[37]  Zhimin Zhang,et al.  Nanogold-enwrapped graphene nanocomposites as trace labels for sensitivity enhancement of electrochemical immunosensors in clinical immunoassays: Carcinoembryonic antigen as a model. , 2010, Biosensors & bioelectronics.

[38]  A. Rougier,et al.  Improved electrochromic performances of NiO based thin films by lithium addition: From single layers to devices , 2012 .

[39]  Kingo Itaya,et al.  Prussian‐blue‐modified electrodes: An application for a stable electrochromic display device , 1982 .