EXPERIMENTAL DESIGN AND OPTIMIZATION OF DISPERSION PROCESS FOR SINGLE-WALLED CARBON NANOTUBE BUCKY PAPER

This paper presents a new processing method to produce nanotube reinforced composites by using single-walled nanotube (SWNT) bucky paper as reinforcement. The SWNT bucky paper is an entangled mat of SWNTs, which is a highly porous mesh structure. To successfully produce SWNT bucky paper reinforced composites, it is essentially important to prepare a high-quality bucky paper. In this study, the quality of the bucky paper related to the dispersion of nanotubes within the bucky paper, which was quantitatively-characterized with rope size distribution and pore size distribution. An experimental study was conducted to investigate the effects of various process parameters on the dispersion of nanotubes using design of experiments (DOEs) approach. Based on the experimental analysis, the dispersion process of nanotubes within the bucky paper was optimized by selecting appropriate process parameters.

[1]  Linda S. Schadler,et al.  LOAD TRANSFER IN CARBON NANOTUBE EPOXY COMPOSITES , 1998 .

[2]  Deron A. Walters,et al.  Elastic strain of freely suspended single-wall carbon nanotube ropes , 1999 .

[3]  K. Lozano,et al.  Nanofiber‐reinforced thermoplastic composites. I. Thermoanalytical and mechanical analyses , 2001 .

[4]  G. A. D. Briggs,et al.  Elastic and shear moduli of single-walled carbon nanotube ropes , 1999 .

[5]  Elizabeth C. Dickey,et al.  Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites , 2000 .

[6]  J. S. Hunter,et al.  Statistics for experimenters : an introduction to design, data analysis, and model building , 1979 .

[7]  G. Xu,et al.  Dynamic mechanical behavior of melt-processed multi-walled carbon nanotube/poly(methyl methacrylate) composites , 2001 .

[8]  Otto Zhou,et al.  Deformation of carbon nanotubes in nanotube–polymer composites , 1999 .

[9]  A. Rinzler,et al.  ALIGNED SINGLE-WALL CARBON NANOTUBES IN COMPOSITES BY MELT PROCESSING METHODS , 2000 .

[10]  Otto Zhou,et al.  Alignment of carbon nanotubes in a polymer matrix by mechanical stretching , 1998 .

[11]  Bingqing Wei,et al.  Study on poly(methyl methacrylate)/carbon nanotube composites , 1999 .

[12]  M. Shaffer,et al.  Fabrication and Characterization of Carbon Nanotube/Poly(vinyl alcohol) Composites , 1999 .

[13]  Jun Liu,et al.  Surfactant-assisted processing of carbon nanotube/polymer composites , 2000 .

[14]  D. Qian,et al.  In‐situ transmission electron microscopy studies of polymer–carbon nanotube composite deformation , 2001, Journal of microscopy.

[15]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[16]  Serge Lefrant,et al.  Characterization of singlewalled carbon nanotubes-PMMA composites , 2000 .

[17]  Karen Lozano,et al.  A study on nanofiber-reinforced thermoplastic composites (II): Investigation of the mixing rheology and conduction properties , 2001 .

[18]  Milo S. P. Shaffer,et al.  Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties , 1999 .