High Quality Ge Virtual Substrates on Si Wafers with Standard STI Patterning

Further improving complementary metal oxide semiconductor performance beyond the 22 nm generation likely requires the use ofhigh mobility channel materials, such as Ge for p-type metal oxide semiconductor pMOS and III/V for n-type metal oxidesemiconductor devices. The complementary integration of both materials on Si substrates can be realized with selective epitaxialgrowth. We present two fabrication schemes for Ge virtual substrates using Si wafers with standard shallow trench isolation STI .This reduces the fabrication cost of these virtual substrates as the complicated isolation scheme in blanket Ge can be omitted. Thelow topography enables integration of ultrathin high-

[1]  Gang Wang,et al.  Fabrication of high quality Ge virtual substrates by selective epitaxial growth in shallow trench isolated Si (001) trenches , 2010 .

[2]  V. Destefanis,et al.  Reduced pressure chemical vapor deposition of Ge thick layers on Si(0 0 1), Si(0 1 1) and Si(1 1 1) , 2008 .

[3]  Selective epitaxial growth of GaAs on Ge by MOCVD , 2006, cond-mat/0703662.

[4]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[5]  V. D'costa,et al.  Molecular-based synthetic approach to new group IV materials for high-efficiency, low-cost solar cells and Si-based optoelectronics. , 2008, Journal of the American Chemical Society.

[6]  M. Tikhov,et al.  Comparative study of hydrogen adsorption on Ge(100) and Ge(111) surfaces , 1984 .

[7]  N. Taoka,et al.  Pure-edge dislocation network for strain-relaxed SiGe∕Si(001) systems , 2005 .

[8]  W. Eccleston,et al.  Mater. Res. Soc. Symp. Proc. , 2006 .

[9]  A. Larsen Epitaxial growth of Ge and SiGe on Si substrates , 2006 .

[10]  J. Michel,et al.  High Performance Ge Devices for Electronic-Photonic Integrated Circuits , 2008 .

[11]  N. Collaert,et al.  Successful Selective Epitaxial Si1 − x Ge x Deposition Process for HBT-BiCMOS and High Mobility Heterojunction pMOS Applications , 2003 .

[12]  Geert Hellings,et al.  Germanium MOSFET Devices: Advances in Materials Understanding, Process Development, and Electrical Performance , 2008 .

[13]  M. Ferenets,et al.  Thin Solid Films , 2010 .

[14]  Dimitri A. Antoniadis,et al.  High quality Ge on Si by epitaxial necking , 2000 .

[15]  P+/n junction leakage in thin selectively grown Ge-in-STI substrates , 2010 .

[16]  M. Carroll,et al.  Defect reduction of selective Ge epitaxy in trenches on Si(001) substrates using aspect ratio trapping , 2007 .

[17]  M. Halbwax,et al.  Kinetics of Ge growth at low temperature on Si(001) by ultrahigh vacuum chemical vapor deposition , 2005 .

[18]  H. Bender,et al.  Structural and optical properties of Ge islands grown in an industrial chemical vapor deposition reactor , 2001 .

[19]  John Kouvetakis,et al.  TIN-BASED GROUP IV SEMICONDUCTORS: New Platforms for Opto- and Microelectronics on Silicon , 2006 .

[20]  E. Fitzgerald,et al.  Dislocations in Relaxed SiGe/Si Heterostructures , 1999 .

[21]  L. Clavelier,et al.  Epitaxial growth of Ge thick layers on nominal and 6° off Si(0 0 1); Ge surface passivation by Si , 2009 .

[22]  K. Saraswat,et al.  Defect Reduction of Ge on Si by Selective Epitaxy and Hydrogen Annealing , 2008 .

[23]  Y. Bogumilowicz,et al.  Reduced pressure-chemical vapor deposition of intrinsic and doped Ge layers on Si(0 0 1) for microelectronics and optoelectronics purposes , 2005 .

[24]  Jurgen Michel,et al.  Totally relaxed GexSi1−x layers with low threading dislocation densities grown on Si substrates , 1991 .

[25]  Stefan Zollner,et al.  Ge–Sn semiconductors for band-gap and lattice engineering , 2002 .

[26]  Gang Wang,et al.  A model of threading dislocation density in strain-relaxed Ge and GaAs epitaxial films on Si (100) , 2009 .

[27]  G. Wang,et al.  Selective Epitaxial Growth of Germanium on Si Wafers with Shallow Trench Isolation: An Approach for Ge Virtual Substrates , 2008 .

[28]  Kazumi Wada,et al.  High-quality Ge epilayers on Si with low threading-dislocation densities , 1999 .

[29]  S. M. Ting,et al.  Metal-organic chemical vapor deposition of single domain GaAs on Ge/GexSi1−x/Si and Ge substrates , 2000 .

[30]  M. Carroll,et al.  Defect reduction of GaAs epitaxy on Si (001) using selective aspect ratio trapping , 2007 .

[31]  O. Richard,et al.  Defect-Free Si Thinning by In Situ HCI Vapour Etching , 2003 .

[32]  M. Wistey,et al.  Chemical routes to Ge /Si(100) structures for low temperature Si-based semiconductor applications , 2007 .

[33]  R. Loo,et al.  Defects, Junction Leakage and Electrical Performance of Ge pFET Devices , 2009 .

[34]  H. Lüth,et al.  Formation of Heterogeneous Thickness Modulations During Epitaxial Growth of LPCVD-Si1−xGex/Si Quantum Well Structures , 1992 .

[35]  A. Lochtefeld,et al.  Facet formation and lateral overgrowth of selective Ge epitaxy on SiO2-patterned Si(001) substrates , 2008 .

[36]  Laurent Vivien,et al.  Reduced pressure–chemical vapor deposition of Ge thick layers on Si(001) for 1.3–1.55-μm photodetection , 2004 .

[37]  Judy L. Hoyt,et al.  Selective Epitaxial Growth of Ge-on-Si for Photodiode Applications , 2008 .