Temperature measurements using a lithium niobate (LiNbO 3 ) pyroelectric ceramic

Temperature measurements from a power generation system could improve its overall safety and efficiency. In addition, real time temperature measurement could lead to a qualitative assessment of the health of the energy system. The challenge of real time temperature measurement inside of a power generation unit lies in the sustainability and the reliability of sensing materials in high temperature and corrosive environments. In this paper, a pyroelectric ceramic material (lithium niobate, LiNbO 3 ) capable of sustaining high temperatures, is considered as the temperature sensing material. LiNbO 3 is a pyroelectric material that generates current proportional to the rate of temperature change with time. This property is sustained by LiNbO 3 until it reaches its Curie temperature (1210 °C). The generated current could be used for many applications including temperature sensing and energy harvesting from waste heat recovery. This paper presents the temperature measurement results using a LiNbO 3 pyroelectric ceramic. Ceramics with dimensions of 1 cm × 1 cm with two different thicknesses, 2 mm and 1 mm, were used as the temperature measurement sensors. Two samples were heated by a 14.5 W/cm 2 heat flux and cooled with natural convection. Electrodes were made on both surfaces of the samples with high purity silver paint and two electrical leads were connected to a picoammeter to measure the generated current with respect to the rate of temperature change of the material during heating and natural cooling. A K-type surface thermocouple was attached on top of LiNbO 3 to compare the temperature measurements and maximum 8% and 6.7% differences were found for 2 mm and 1 mm thick samples, respectively.

[1]  Xingbo Liu,et al.  Development of self-powered wireless high temperature electrochemical sensor for in situ corrosion monitoring of coal-fired power plant. , 2015, ISA transactions.

[2]  Norman Love,et al.  Self-powered wireless thermoelectric sensors , 2014 .

[3]  Y. Çengel Heat and Mass Transfer: Fundamentals and Applications , 2000 .

[4]  V. Ferrari,et al.  Thermal energy harvesting through pyroelectricity , 2010 .

[5]  Chin-Hsiang Cheng,et al.  The Optimization of the Thermal Response on the ZnO Flexible Pyroelectric Film Temperature Sensor , 2012, IEEE Sensors Journal.

[6]  M. Rashid,et al.  Pyroelectric detectors and their applications , 1989, Conference Record of the IEEE Industry Applications Society Annual Meeting,.

[7]  J T McMullan,et al.  Clean coal technologies , 1997 .

[8]  Yi Jia,et al.  A Passive Wireless Temperature Sensor for Harsh Environment Applications , 2008, Sensors.

[9]  Chenguo Hu,et al.  Harvesting heat energy from hot/cold water with a pyroelectric generator , 2014 .

[11]  Kam K. Leang,et al.  Energy Harvesting by Pyroelectric Effect Using PZT , 2008 .

[12]  Alessandro Franco,et al.  The future challenges for “clean coal technologies”: Joining efficiency increase and pollutant emission control , 2009 .

[13]  Roger W. Whatmore,et al.  Pyroelectric devices and materials , 1986 .

[14]  Ichiro Terasaki,et al.  Large thermoelectric power in NaCo 2 O 4 single crystals , 1997 .

[15]  F. Carré,et al.  Structural materials challenges for advanced reactor systems , 2009 .

[16]  P. Childs,et al.  Review of temperature measurement , 2000 .

[17]  Yan Zhang,et al.  Pyroelectric nanogenerators for driving wireless sensors. , 2012, Nano letters.