Efficient synthesis of highly soluble doubly-bridged porphyrin-fullerene dyad

The double-linked porphyrin-fullerene dyad has been prepared in high yield. The title compound is soluble in a wide range of solvents with different polarity, such as n-pentane or benzonitrile.

[1]  M. Prato,et al.  Parallel (face-to-face) versus perpendicular (edge-to-face) alignment of electron donors and acceptors in fullerene porphyrin dyads: the importance of orientation in electron transfer. , 2001, Journal of the American Chemical Society.

[2]  M. Prato,et al.  Transient EPR Studies of Excited Triplet States in Polyadducts of C60 and Bis(ethoxycarbonyl)methylene , 1997 .

[3]  F. Diederich,et al.  Tether-Directed Remote Functionalization of Buckminsterfullerene: Regiospecific Hexaadduct Formation† , 1994 .

[4]  M. Anikin,et al.  Arrangement of a Hydrophobically Shielded Porphyrin, 5,10,15,20-Tetrakis(3,5-di-tert-butylphenyl)porphyrin, in Octadecylamine Langmuir−Blodgett Multilayers , 1997 .

[5]  D. Guldi,et al.  Photophysical Properties of Mono- and Multiply-Functionalized Fullerene Derivatives , 1997 .

[6]  Nicola Armaroli,et al.  Charge-transfer interactions in face-to-face porphyrin-fullerene systems: solvent-dependent luminescence in the infrared spectral region , 2000, Chemistry.

[7]  M. Prato,et al.  USE OF TRANSIENT EPR SPECTROSCOPY OF EXCITED TRIPLET STATE FOR THE STRUCTURAL ASSIGNMENT OF BISADDUCTS OF FULLERENE C60 , 1997 .

[8]  S. Shinkai,et al.  Efficient photocurrent generation in novel self-assembled multilayers comprised of [60]fullerene-cationic homooxacalix[3]arene inclusion complex and anionic porphyrin polymer. , 2001, Journal of the American Chemical Society.

[9]  N. Ogata,et al.  Fabrication and electrical properties of fullerene/phthalocyaninatometal Langmuir-Blodgett films , 1997 .

[10]  F. Diederich,et al.  Synthesis, and Optical and Electrochemical Properties of Cyclophane-Type Molecular Dyads Containing a Porphyrin in Close, Tangential Orientation Relative to the Surface oftrans-1 Functionalized C60. Preliminary Communication , 1998 .

[11]  F. Diederich,et al.  Regioselective Synthesis of trans-1 Fullerene Bis-Adducts Directed by a Crown Ether Tether: Alkali Metal Cation Modulated Redox Properties of Fullerene-Crown Ether Conjugates. , 1998, Angewandte Chemie.