Magnetic Feshbach resonances between atoms in $^2$S and $^3$P$_0$ states: mechanisms and dependence on atomic properties

Magnetically tunable Feshbach resonances exist in ultracold collisions between atoms in $^2$S and $^3$P$_0$ states, such as an alkali-metal atom colliding with Yb or Sr in a clock state. We investigate the mechanisms of these resonances and identify the terms in the collision Hamiltonian responsible for them. They involve indirect coupling between the open and closed channels, via intermediate channels involving atoms in $^3$P$_1$ states. The resonance widths are generally proportional to the square of the magnetic field and are strongly enhanced when the magnitude of the background scattering length is large. For any given pair of atoms, the scattering length can be tuned discretely by choosing different isotopes of the $^3$P$_0$ atom. For each combination of an alkali-metal atom and either Yb or Sr, we consider the prospects of finding an isotopic combination that has both a large background scattering length and resonances at high but experimentally accessible field. We conclude that $^{87}$Rb+Yb, Cs+Yb and $^{85}$Rb+Sr are particularly promising combinations.

[1]  S. Cornish,et al.  Observation of magnetic Feshbach resonances between Cs and ${}^{173}$Yb , 2022, 2208.06291.

[2]  J. Hutson,et al.  Feshbach resonances and molecule formation in ultracold mixtures of Rb and Yb(P3) atoms , 2021, Physical Review A.

[3]  Alaina M. Green,et al.  Feshbach Resonances in p-Wave Three-Body Recombination within Fermi-Fermi Mixtures of Open-Shell 6Li and Closed-Shell 173Yb Atoms , 2019, Physical review. X.

[4]  B. Yang,et al.  Magnetic Feshbach resonances in ultracold collisions between Cs and Yb atoms , 2019, Physical Review A.

[5]  Alaina M. Green,et al.  Two-photon photoassociation spectroscopy of the Σ+2 YbLi molecular ground state , 2019, Physical Review A.

[6]  Jeremy M. Hutson,et al.  molscat: A program for non-reactive quantum scattering calculations on atomic and molecular collisions , 2018, Comput. Phys. Commun..

[7]  Jeremy M. Hutson,et al.  bound and field: Programs for calculating bound states of interacting pairs of atoms and molecules , 2018, Comput. Phys. Commun..

[8]  S. Cornish,et al.  Two-photon photoassociation spectroscopy of CsYb: Ground-state interaction potential and interspecies scattering lengths , 2018, Physical Review A.

[9]  S. Cornish,et al.  Production of ultracold Cs*Yb molecules by photoassociation , 2018, Physical Review A.

[10]  P. Żuchowski,et al.  Observation of Feshbach resonances between alkali and closed-shell atoms , 2017, Nature Physics.

[11]  M. Shundalau,et al.  Multi-reference perturbation theory study on the CsYb molecule including the spin-orbit coupling , 2017 .

[12]  S. Cornish,et al.  Interspecies thermalization in an ultracold mixture of Cs and Yb in an optical trap , 2017, 1704.03270.

[13]  J. Lutz,et al.  Deviations from Born-Oppenheimer mass scaling in spectroscopy and ultracold molecular physics , 2016, 1608.02141.

[14]  R. Ferber,et al.  Ab initio multi-reference perturbation theory calculations of the ground and some excited electronic states of the RbYb molecule , 2016 .

[15]  Alaina M. Green,et al.  Photoassociative production of ultracold heteronuclear YbLi * molecules , 2016, 1606.03120.

[16]  J. Bohn,et al.  Shielding Σ2 ultracold dipolar molecular collisions with electric fields , 2015, 1510.06601.

[17]  W. Ernst,et al.  Ab initio study of the RbSr electronic structure: potential energy curves, transition dipole moments, and permanent electric dipole moments. , 2014, The Journal of chemical physics.

[18]  P. Żuchowski,et al.  Ground- and excited-state properties of the polar and paramagnetic RbSr molecule: A comparative study , 2014, 1402.0702.

[19]  K. B. Whaley,et al.  Infrared-dressed entanglement of cold open-shell polar molecules for universal matchgate quantum computing , 2014, 1402.0381.

[20]  S. Kokkelmans,et al.  Feshbach resonances in ultracold gases , 2014, 1401.2945.

[21]  R. Ciuryło,et al.  Scattering lengths in isotopologues of the RbYb system , 2013, 1309.3131.

[22]  R. Krems,et al.  Sensitive imaging of electromagnetic fields with paramagnetic polar molecules , 2012, 1202.1857.

[23]  A. Görlitz,et al.  Two-photon photoassociation spectroscopy of heteronuclear YbRb. , 2011, Physical chemistry chemical physics : PCCP.

[24]  J. Hutson,et al.  Magnetically tunable Feshbach resonances in ultracold Li-Yb mixtures. , 2011, Physical review letters.

[25]  V. V. Ivanov,et al.  Quantum Degenerate Mixture of Ytterbium and Lithium Atoms , 2011, 1105.5751.

[26]  V. V. Ivanov,et al.  Sympathetic cooling in an optically trapped mixture of alkali and spin-singlet atoms. , 2011, Physical review letters.

[27]  Peng Zhang,et al.  Structure and spectroscopy of ground and excited states of LiYb. , 2010, The Journal of chemical physics.

[28]  R. Krems,et al.  External field control of collective spin excitations in an optical lattice of 2Σ molecules , 2010, 1007.0458.

[29]  Anpei Ye,et al.  Dipole polarizabilities and magic wavelengths for a Sr and Yb atomic optical lattice clock , 2010 .

[30]  P. Żuchowski,et al.  Ultracold RbSr molecules can be formed by magnetoassociation. , 2010, Physical review letters.

[31]  V. Dzuba,et al.  Dynamic polarizabilities and related properties of clock states of the ytterbium atom , 2009, 0908.2278.

[32]  E. Meyer,et al.  Electron electric-dipole-moment searches based on alkali-metal- or alkaline-earth-metal-bearing molecules , 2009, 0907.4179.

[33]  S. Tassy,et al.  Production of heteronuclear molecules in an electronically excited state by photoassociation in a mixture of ultracold Yb and Rb , 2008, 0807.0852.

[34]  R. Krems,et al.  Inelastic collisions of cold polar molecules in nonparallel electric and magnetic fields. , 2007, The Journal of chemical physics.

[35]  P. Julienne,et al.  Simple Theoretical Models for Resonant Cold Atom Interactions , 2006, physics/0609013.

[36]  P. Soldán,et al.  Molecule formation in ultracold atomic gases , 2006, physics/0607234.

[37]  P. Zoller,et al.  A toolbox for lattice-spin models with polar molecules , 2005, quant-ph/0512222.

[38]  M. Rosa Laser-cooling molecules , 2004 .

[39]  R. Santra,et al.  Properties of metastable alkaline-earth-metal atoms calculated using an accurate effective core potential , 2003, physics/0312033.

[40]  James F. Babb,et al.  High-precision calculations of van der Waals coefficients for heteronuclear alkali-metal dimers , 2001, physics/0102030.

[41]  M. Raoult,et al.  Analysis of threshold effects in ultracold atomic collisions , 2000 .

[42]  É. Audouard,et al.  Quantization of the highest levels in a molecular potential , 1998 .

[43]  Bowers,et al.  Experimental investigation of excited-state lifetimes in atomic ytterbium. , 1996, Physical review. A, Atomic, molecular, and optical physics.

[44]  J. Hutson Coupled channel methods for solving the bound-state Schrödinger equation , 1994 .

[45]  M. Dubernet,et al.  ATOM-MOLECULE VAN DER WAALS COMPLEXES CONTAINING OPEN-SHELL ATOMS. I: GENERAL THEORY AND BENDING LEVELS , 1994 .

[46]  V. Flambaum,et al.  Calculation of the scattering length in atomic collisions using the semiclassical approximation. , 1993, Physical review. A, Atomic, molecular, and optical physics.

[47]  F. Mies A multichannel quantum defect analysis of diatomic predissociation and inelastic atomic scattering , 1984 .

[48]  R. Bernstein,et al.  Dissociation Energy and Long‐Range Potential of Diatomic Molecules from Vibrational Spacings of Higher Levels , 1970 .

[49]  K. Tang Dynamic Polarizabilities and van der Waals Coefficients , 1969 .

[50]  P. Julienne,et al.  Spatial separation in a thermal mixture of ultracold 174 Yb and 87 Rb atoms , 2011 .

[51]  P. Julienne,et al.  Manipulation of Feshbach resonances in ultracold atomic collisions using time-dependent magnetic fields , 2000 .