论文信息 - Enantioselective hydrogenation of itaconate using rhodium bihelicenol phosphite complex. Matched/mismatched phenomena between helical and axial chirality

Enantioselective hydrogenation of itaconate using rhodium bihelicenol phosphite complex. Matched/mismatched phenomena between helical and axial chirality

Abstract Phosphites prepared from bihelicenol, menthol (or 1-phenylethanol), and PCl3 are effective ligands for the rhodium-catalyzed enantioselective hydrogenation of dimethyl itaconate. Stereochemistry of the helicene moiety plays an important role in the asymmetric induction, and matched/mismatched phenomena are observed between helical and axial chirality.

M. Yamaguchi | Masahiko Yamaguchi | Daisuke Nakano | D. Nakano

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