Delta-doped electron-multiplied CCD with absolute quantum efficiency over 50% in the near to far ultraviolet range for single photon counting applications.

We have used molecular beam epitaxy (MBE) based delta-doping technology to demonstrate nearly 100% internal quantum efficiency (QE) on silicon electron-multiplied charge-coupled devices (EMCCDs) for single photon counting detection applications. We used atomic layer deposition (ALD) for antireflection (AR) coatings and achieved atomic-scale control over the interfaces and thin film materials parameters. By combining the precision control of MBE and ALD, we have demonstrated more than 50% external QE in the far and near ultraviolet in megapixel arrays. We have demonstrated that other important device performance parameters such as dark current are unchanged after these processes. In this paper, we briefly review ultraviolet detection, report on these results, and briefly discuss the techniques and processes employed.

[1]  Michael E. Hoenk,et al.  Direct detection of 0.1–20keV electrons with delta doped, fully depleted, high purity silicon p-i-n diode arrays , 2006 .

[2]  P.-A. Besse,et al.  Design and characterization of a CMOS 3-D image sensor based on single photon avalanche diodes , 2005, IEEE Journal of Solid-State Circuits.

[3]  Michael E. Hoenk,et al.  Delta-doped back-illuminated CMOS imaging arrays: progress and prospects , 2009, Organic Photonics + Electronics.

[4]  David Schiminovich,et al.  Ultraviolet antireflection coatings for use in silicon detector design. , 2011, Applied optics.

[5]  Kenneth L. Shepard,et al.  A low-noise, single-photon avalanche diode in standard 0.13 μm complementary metal-oxide-semiconductor process , 2010 .

[6]  Michael E. Hoenk,et al.  Delta-doped CCDs: high QE with long-term stability at UV and visible wavelengths , 1994, Astronomical Telescopes and Instrumentation.

[7]  Frank Greer,et al.  A system and methodologies for absolute quantum efficiency measurements from the vacuum ultraviolet through the near infrared. , 2011, The Review of scientific instruments.

[8]  P D Feldman,et al.  Vacuum-ultraviolet quantum efficiency of a thinned, backside-illuminated charge-coupled device. , 1995, Applied optics.

[9]  David Griffiths,et al.  The Galaxy Evolution Explorer , 2003, SPIE Astronomical Telescopes + Instrumentation.

[10]  Michael E. Hoenk,et al.  Characterization and absolute QE measurements of delta-doped N-channel and P-channel CCDs , 2010, Astronomical Telescopes + Instrumentation.

[11]  Ray Bell,et al.  Subelectron read noise at MHz pixel rates , 2001, IS&T/SPIE Electronic Imaging.

[12]  Ray Bell,et al.  The LLCCD: low-light imaging without the need for an intensifier , 2001, IS&T/SPIE Electronic Imaging.

[13]  James R. Janesick,et al.  Photon transfer : DN --> [lambda] , 2007 .

[14]  R. A. Kimble,et al.  WFC3 detectors: on-orbit performance , 2010, Astronomical Telescopes + Instrumentation.

[15]  Michael E. Hoenk,et al.  Enhanced quantum efficiency of high-purity silicon imaging detectors by ultralow temperature surface modification using Sb doping , 2005 .

[16]  M. Deen,et al.  Fully Integrated Single Photon Avalanche Diode Detector in Standard CMOS 0.18- $\mu$m Technology , 2008, IEEE Transactions on Electron Devices.

[17]  J. Hynecek Impactron-a new solid state image intensifier , 2001 .

[18]  Michael E. Hoenk,et al.  Growth of a delta‐doped silicon layer by molecular beam epitaxy on a charge‐coupled device for reflection‐limited ultraviolet quantum efficiency , 1992 .

[19]  Elena Sabbi,et al.  Wide Field Camera 3 CCD quantum efficiency hysteresis: characterization and mitigation , 2009, Optical Engineering + Applications.

[20]  J. Neill,et al.  A turbulent wake as a tracer of 30,000 years of Mira’s mass loss history , 2007, Nature.

[21]  Manijeh Razeghi,et al.  III-nitride avalanche photodiodes , 2007, OPTO.

[22]  Joe C. Campbell,et al.  GaN avalanche photodiodes , 2000 .

[23]  Raj Korde,et al.  Absolute silicon photodiodes for 160 nm to 254 nm photons , 1998 .