A layer-structured Na2CoP2O7 pyrophosphate cathode for sodium-ion batteries

We introduce Na2CoP2O7 pyrophosphate as a new potential cathode for sodium-ion batteries. Based on a layered structure, it offers a two-dimensional Na-diffusion pathway delivering a reversible capacity close to 80 mA h g−1 involving Co3+/Co2+ redox activity with an average potential of 3 V.

[1]  E. M. Holt,et al.  Crystal structures of two allotropic forms of Na2CoP2O7 , 1991 .

[2]  Kazuma Gotoh,et al.  Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard‐Carbon Electrodes and Application to Na‐Ion Batteries , 2011 .

[3]  Teófilo Rojo,et al.  Na-ion batteries, recent advances and present challenges to become low cost energy storage systems , 2012 .

[4]  K. Abraham Intercalation positive electrodes for rechargeable sodium cells , 1982 .

[5]  Jeremy Barker,et al.  A Sodium-Ion Cell Based on the Fluorophosphate Compound NaVPO4 F , 2003 .

[6]  Jean-Marie Tarascon,et al.  Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi1/3Mn1/3Co1/3O2 , 2012 .

[7]  M. Armand,et al.  Structural, transport, and electrochemical investigation of novel AMSO4F (A = Na, Li; M = Fe, Co, Ni, Mn) metal fluorosulphates prepared using low temperature synthesis routes. , 2010, Inorganic chemistry.

[8]  Shin-ichi Nishimura,et al.  High‐Voltage Pyrophosphate Cathodes , 2012 .

[9]  Kathryn E. Toghill,et al.  A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries. , 2007, Nature materials.

[10]  P. Hagenmuller,et al.  Electrochemical intercalation of sodium in NaxCoO2 bronzes , 1981 .

[11]  Philippe Moreau,et al.  Structure and Stability of Sodium Intercalated Phases in Olivine FePO4 , 2010 .

[12]  Dong-Hwa Seo,et al.  New iron-based mixed-polyanion cathodes for lithium and sodium rechargeable batteries: combined first principles calculations and experimental study. , 2012, Journal of the American Chemical Society.

[13]  Shinichi Komaba,et al.  P2-type Na(x)[Fe(1/2)Mn(1/2)]O2 made from earth-abundant elements for rechargeable Na batteries. , 2012, Nature materials.

[14]  Yuki Yamada,et al.  Eco-efficient splash combustion synthesis of nanoscale pyrophosphate (Li2FeP2O7) positive-electrode using Fe(III) precursors , 2012 .

[15]  J-M Tarascon,et al.  Study of the insertion/deinsertion mechanism of sodium into Na0.44MnO2. , 2007, Inorganic chemistry.

[16]  P. Bruce,et al.  Nanomaterials for rechargeable lithium batteries. , 2008, Angewandte Chemie.

[17]  R. Sáez-Puche,et al.  Studies on tetragonal Na2CoP2O7, a novel ionic conductor , 1999 .

[18]  B. Hwang,et al.  The P2-Na(2/3)Co(2/3)Mn(1/3)O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery. , 2011, Dalton transactions.

[19]  M. Armand,et al.  Issues and challenges facing rechargeable lithium batteries , 2001, Nature.

[20]  M. Armand,et al.  Building better batteries , 2008, Nature.

[21]  A. Yamada,et al.  Magnetic structure and properties of the Na2CoP2O7 pyrophosphate cathode for sodium-ion batteries: a supersuperexchange-driven non-collinear antiferromagnet. , 2013, Inorganic chemistry.

[22]  Shinichi Komaba,et al.  Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2 , 2010 .

[23]  Takayuki Komatsu,et al.  Fabrication of Na2FeP2O7 glass-ceramics for sodium ion battery , 2012 .

[24]  Wataru Murata,et al.  Fluorinated ethylene carbonate as electrolyte additive for rechargeable Na batteries. , 2011, ACS applied materials & interfaces.

[25]  Shinichi Komaba,et al.  Study on the reversible electrode reaction of Na(1-x)Ni(0.5)Mn(0.5)O2 for a rechargeable sodium-ion battery. , 2012, Inorganic chemistry.

[26]  A. Yamada,et al.  New lithium iron pyrophosphate as 3.5 V class cathode material for lithium ion battery. , 2010, Journal of the American Chemical Society.

[27]  J. Tarascon,et al.  CoO2, the end member of the LixCoO2 solid solution , 1996 .

[28]  Yuki Yamada,et al.  Sodium iron pyrophosphate: A novel 3.0 V iron-based cathode for sodium-ion batteries , 2012 .

[29]  A. Yamada,et al.  Electrochemical Redox Mechanism in 3.5 V Li2-xFeP2O7 (0 ≤ x ≤ 1) Pyrophosphate Cathode , 2012 .

[30]  Jean-Marie Tarascon,et al.  Is lithium the new gold? , 2010, Nature chemistry.