Synergistic Effect of Benincasa hispida Peel Extract and KI on the Corrosion Inhibition of Mild Steel in HCl

This study employed Benincasa hispida peel as a raw material for the preparation of Benincasa hispida peel extract (BHPE) via hot water extraction and freeze-drying processes. The synergistic effect of BHPE and KI on the corrosion inhibition of mild steel in 1 M HCl was investigated. The compositional analysis shows that BHPE consists mainly of a mixture of sugars, characterized by a high density of hydroxyl groups and unsaturated functional groups, characteristic of highly effective corrosion inhibitors. Electrochemical experiments and surface analysis show that the composite of BHPE and KI can effectively provide protection to mild steel. Moreover, the synergistic coefficient of BHPE and KI under various concentration conditions was greater than 1, and the highest corrosion inhibition efficiency was 94.4%. In addition, the corrosion inhibition mechanism of BHPE was thoroughly investigated using quantum chemistry (QC) and molecular dynamics simulation (MDS).

[1]  A. Delimi,et al.  The curious case of polyphenols as green corrosion inhibitors: a review on their extraction, design, and applications , 2023, Environmental Science and Pollution Research.

[2]  X. Guo,et al.  Fructus cannabis protein extract powder as a green and high effective corrosion inhibitor for Q235 carbon steel in 1 M HCl solution. , 2023, International journal of biological macromolecules.

[3]  Kelvin O. Yoro,et al.  Sustainable approach for corrosion control in mild steel using plant-based inhibitors: A review , 2023, Materials Today Sustainability.

[4]  Qiang Yu,et al.  Extraction of bioactive compounds from cinnamon residues with deep eutectic solvents and its molecular mechanism , 2023, Chemical Engineering and Science.

[5]  N. Xu,et al.  Chitosan derivatives as promising green corrosion inhibitors for carbon steel in acidic environment: Inhibition performance and interfacial adsorption mechanism. , 2023, Journal of colloid and interface science.

[6]  Zhitao Yan,et al.  Application of Biomass Corrosion Inhibitors in Metal Corrosion Control: A Review , 2023, Molecules.

[7]  A. Zarrouk,et al.  Coupling of experimental and theoretical studies to apprehend the action of benzodiazepine derivative as a corrosion inhibitor of carbon steel in 1M HCl , 2023, Journal of Molecular Structure.

[8]  R. Solmaz,et al.  Investigation of adsorption, corrosion inhibition, synergistic inhibition effect and stability studies of Rheum ribes leaf extract on mild steel in 1 M HCl solution , 2023, Journal of the Taiwan Institute of Chemical Engineers.

[9]  G. Du,et al.  Synergistic Mixture of Eupatorium Adenophora Spreng Leaves Extract and Ki as a Novel Green Inhibitor for Steel Corrosion in 5.0 M H3po4 Solution , 2023, SSRN Electronic Journal.

[10]  E. A. Badr,et al.  Preparation of zwitterionic ionic surfactants-based sulphonyl for steel protections: Experimental and theoretical insights , 2023, Zeitschrift für Physikalische Chemie.

[11]  R. Oukhrib,et al.  Carissa macrocarpa extract (ECM) as a new efficient and ecologically friendly corrosion inhibitor for copper in nitric acid: Experimental and theoretical approach , 2023, Journal of the Taiwan Institute of Chemical Engineers.

[12]  A. Fouda,et al.  Insights into the adsorption and corrosion inhibition properties of newly synthesized diazinyl derivatives for mild steel in hydrochloric acid: synthesis, electrochemical, SRB biological resistivity and quantum chemical calculations , 2022, RSC advances.

[13]  M. Zertoubi,et al.  Insight on the corrosion inhibition performance of Glebionis coronaria plant extract in various acidic mediums , 2022, Journal of Applied Electrochemistry.

[14]  B. Ramezanzadeh,et al.  Pepper extract effectiveness as a natural inhibitor against corrosion of steel samples (SS) in 1 M hydrochloric acid; Theoretical (DFT calculation – MD simulation), thermodynamic, and electrochemical-surface studies , 2022, Industrial Crops and Products.

[15]  J. González-Rodríguez,et al.  KI effects on corrosion inhibition for 1018 steel in acid media using Medicago sativa , 2022, Frontiers in Chemistry.

[16]  Zhitao Yan,et al.  Insight into the anti–corrosion behavior of Reineckia Carnea leaves extract as an eco–friendly and high–efficiency corrosion inhibitor , 2022, Industrial Crops and Products.

[17]  Entian Li,et al.  Choline amino acid ionic liquids as green corrosion inhibitors of mild steel in acidic medium , 2022, Colloids and Surfaces A: Physicochemical and Engineering Aspects.

[18]  Bokai Liao,et al.  Insight into The Anti-corrosion Performance of Acanthopanax Senticosus Leaf Extract as Eco-friendly Corrosion Inhibitor for Carbon Steel in Acidic Medium , 2022, Journal of Industrial and Engineering Chemistry.

[19]  Yan‐Chao Wu,et al.  Investigation of adsorption and corrosion inhibition property of Hyperoside as a novel corrosion inhibitor for Q235 steel in HaCl medium , 2022, Journal of Molecular Liquids.

[20]  Y. Ko,et al.  Adsorption Mechanism of Eco-Friendly Corrosion Inhibitors for Exceptional Corrosion Protection of Carbon Steel: Electrochemical and First-Principles DFT Evaluations , 2022, Metals.

[21]  Zezhou Liang,et al.  Protective behaviour of naphthylamine derivatives for steel reinforcement in the simulated concrete pore solutions: Detailed experimental and computational explorations , 2022, Journal of Molecular Structure.

[22]  Ashok Kumar,et al.  Experimental and Theoretical study of Sodium Cocoyl Glycinate as corrosion inhibitor for mild steel in hydrochloric acid medium , 2022, Journal of Molecular Liquids.

[23]  Qian Wang,et al.  Valorization of Polysaccharides From Benincasa hispida: Physicochemical, Moisturizing, and Antioxidant Skincare Properties , 2022, Frontiers in Pharmacology.

[24]  Qi Zhang,et al.  Insight into the anti–corrosion performance of Artemisia argyi leaves extract as eco–friendly corrosion inhibitor for carbon steel in HCl medium , 2022, Sustainable Chemistry and Pharmacy.

[25]  Manik Chandra Sil,et al.  Study of synergy of monoethanolamine and urea on copper corrosion inhibition in alkaline solution , 2022, Journal of Molecular Liquids.

[26]  X. Guo,et al.  Kapok leaves extract and synergistic iodide as novel effective corrosion inhibitors for Q235 carbon steel in H2SO4 medium , 2022, Industrial Crops and Products.

[27]  Xueming Li,et al.  An overview of microbiologically influenced corrosion: mechanisms and its control by microbes , 2022, Corrosion Reviews.

[28]  Qi Zhang,et al.  Insight into anti–corrosion behavior of Centipeda minima leaves extract as high–efficiency and eco–friendly inhibitor , 2022, Colloids and Surfaces A: Physicochemical and Engineering Aspects.

[29]  J. Sharifi‐Rad,et al.  A Literature-Based Update on Benincasa hispida (Thunb.) Cogn.: Traditional Uses, Nutraceutical, and Phytopharmacological Profiles , 2021, Oxidative medicine and cellular longevity.

[30]  Srilatha Rao,et al.  Discotic anthraquinones as novel corrosion inhibitor for mild steel surface , 2021, Journal of Molecular Liquids.

[31]  M. Mansha,et al.  A Novel Trans-Esterified Water Soluble Hyperbranched Polymer for Surface Protection of X60 Steel: Experimental and Theoretical Approach , 2021, Journal of Molecular Liquids.

[32]  Supriya Bangera,et al.  An integrated electrochemical and theoretical approach on the potency of Senegalia rugata leaf extract as a novel inhibitor for mild steel in acidic medium , 2021, Journal of Applied Electrochemistry.

[33]  Mohammed S. Alqahtani,et al.  N–hydroxybenzothioamide derivatives as green and efficient corrosion inhibitors for mild steel: Experimental, DFT and MC simulation approach , 2021 .

[34]  A. Joseph,et al.  Extended protection of mild steel in molar HCl using the Garcinia Indica fruit rind extract (GIW) and iodide ions; electrochemical, thermodynamic and kinetic studies , 2021, Journal of the Indian Chemical Society.

[35]  Xianghong Li,et al.  Synergistic inhibition effect of Mikania micrantha extract with KI on steel corrosion in H2SO4 solution , 2021, Journal of Molecular Liquids.

[36]  Mariem. M. Motawea.  Experimental, computational studies and spectroscopic analysis on the effective Aeluropus lagopoides extract as water-soluble green corrosion inhibitor for carbon steel in 1 M HCl solution , 2021, Journal of Adhesion Science and Technology.

[37]  Xiaowang Liu,et al.  Chemically modified resveratrol as green corrosion inhibitor for Q235 steel: Electrochemical, SEM, UV and DFT studies , 2021, Journal of Molecular Liquids.

[38]  M. Taleb,et al.  Chemical, electrochemical, quantum, and surface analysis evaluation on the inhibition performance of novel imidazo[4,5-b] pyridine derivatives against mild steel corrosion , 2021 .

[39]  Qi Zhang,et al.  Two amino acid derivatives as high efficient green inhibitors for the corrosion of carbon steel in CO2-saturated formation water , 2021 .

[40]  R. Loto,et al.  Synergistic corrosion inhibition of low carbon steel in HCl and H2SO4 media by 5-methyl-3-phenylisoxazole-4-carboxylic acid and iodide ions , 2021, Journal of Adhesion Science and Technology.

[41]  R. Hassan,et al.  Performance and efficiency of methyl-cellulose polysaccharide as a green promising inhibitor for inhibition of corrosion of magnesium in acidic solutions , 2021 .

[42]  S. Kaya,et al.  Papaver somniferum as an efficient corrosion inhibitor for iron alloy in acidic condition: DFT, MC simulation, LCMS and Electrochemical studies , 2021 .

[43]  R. Idouhli,et al.  Contribution to understanding synergistic effect of Punica granatum extract and potassium iodide as corrosion inhibitor of S355 steel , 2021 .

[44]  Nisha Bhardwaj,et al.  Phytochemicals as steel corrosion inhibitor: an insight into mechanism , 2021 .

[45]  Xianghong Li,et al.  Synergistic inhibition effect of walnut green husk extract and potassium iodide on the corrosion of cold rolled steel in trichloroacetic acid solution , 2020 .

[46]  Yuanhua Lin,et al.  A new series of synthesized compounds as corrosion mitigator for storage tanks: Detailed electrochemical and theoretical investigations , 2020 .

[47]  A. Alavi,et al.  A theoretical and experimental study of castor oil-based inhibitor for corrosion inhibition of mild steel in acidic medium at elevated temperatures , 2020 .

[48]  B. Ramezanzadeh,et al.  Steel corrosion lowering in front of the saline solution by a nitrogen-rich source of green inhibitors: Detailed surface, electrochemical and computational studies , 2020 .

[49]  D. S. Chauhan,et al.  Polar group substituted imidazolium zwitterions as eco-friendly corrosion inhibitors for mild steel in acid solution , 2020 .

[50]  J. Jacob,et al.  Synergistic effect of salts on the corrosion inhibitive action of plant extract: a review , 2020 .

[51]  J. Rodríguez,et al.  The influence of iodide in corrosion inhibition by organic compounds on carbon steel: Theoretical and experimental studies , 2020 .

[52]  E. Ebenso,et al.  Highly functionalized epoxy macromolecule as an anti-corrosive material for carbon steel: Computational (DFT, MDS), surface (SEM-EDS) and electrochemical (OCP, PDP, EIS) studies , 2020 .

[53]  H. Ke,et al.  Density Functional Theory: An Essential Partner in the Integrated Computational Materials Engineering Approach to Corrosion , 2019, Corrosion.

[54]  S. Lele,et al.  Physicochemical and functional properties of ash gourd/bottle gourd beverages blended with jamun , 2018, Journal of Food Science and Technology.

[55]  J. Porcayo-Calderón,et al.  Development and evaluation of a green corrosion inhibitor based on rice bran oil obtained from agro-industrial waste , 2018, Industrial Crops and Products.

[56]  I. Obot,et al.  Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors. Part 1: An overview , 2015 .

[57]  M. Deyab.  Egyptian licorice extract as a green corrosion inhibitor for copper in hydrochloric acid solution , 2015 .

[58]  Kuiwu Wang,et al.  Characterization and antioxidant activities of polysaccharide extracted from Benincasa hispida var. chieh-qua How , 2022, Food Science and Technology.

[59]  X. Guo,et al.  Soybean extract firstly used as a green corrosion inhibitor with high efficacy and yield for carbon steel in acidic medium , 2022, Industrial Crops and Products.

[60]  M. O. Nkiko.  Evaluating the Deterioration of Galvanized Steel in an Acidic Medium using Pinus Oocarpa Seed Extract as Inhibitor , 2022, Portugaliae Electrochimica Acta.

[61]  F. Bentiss,et al.  Assessment of corrosion inhibition performance of origanum compactum extract for mild steel in 1 M HCl: Weight loss, electrochemical, SEM/EDX, XPS, DFT and molecular dynamic simulation , 2022, Industrial Crops and Products.

[62]  Xiao-guang Xie,et al.  Synergistic inhibition effects of bamboo leaf extract/major components and iodide ion on the corrosion of steel in H3PO4 solution , 2014 .