Effect of Pre-Aging Treatment on the Mechanical Properties of Cold Rolled Cu-6 wt% Ni-1.4 wt% Si Alloy

Cu-Ni-Si alloys were strengthened by Ni2Si intermetallic compound precipitation in a Cu matrix during aging. The Cu-6 wt% Ni-1.4wt%Si alloy was prepared by water quenching (solution treatment) or air cooling (homogenization treatment) after heating 980 C for 2 hours and aging at 500 C for 6 hours. After maintaining a high temperature single phase region, the structure of the precipitate in the matrix was changed significantly by varying the cooling rate. The solution treated aged alloy had discontinuous precipitation with fiber shaped precipitates throughout the specimen, however, the alloy with homogenization had normal spherical shaped particles. The aged alloy after homogenization treatment had higher strength, ductility and electrical conductivity, of 628 MPa, 18%, 48% IACS, respectively, than aged alloy after solution treatment, which had 582 MPa, 15.5% and 50 % IACS, respectively. In contrast to the tendency of values after aging, after rolling and a 75% area reduction at room temperature after homogenization treatment the alloy had lower strength, ductility and electrical conductivity, of 774 MPa, 10.5%, 48% IACS, than the alloy after solution treatment, with 885 MPa, 6.5%, and 48% IACS, respectively. The Cu-6 wt% Ni-1.4wt%Si alloy with fully discontinuous precipitation had lower strength and higher electrical conductivity than the counterpart alloy with normal precipitation. However, inversely, the strength increased compared to the alloy with normal precipitation after rolling with 75% area reduction, without sacrificing electrical conductivity. (Received April 23, 2020; Accepted May 25, 2020)

[1]  S. Hong,et al.  Compositional tuning-induced permanent color adjustment and mechanical properties: Binary Cu-Mg colored metallic system , 2019, Materials & Design.

[2]  S. Semboshi,et al.  Effect of Composition on the Strength and Electrical Conductivity of Cu-Ti Binary Alloy Wires Fabricated by Aging and Intense Drawing , 2019, Metallurgical and Materials Transactions A.

[3]  Je-hyun Lee,et al.  Effect of Prior Cold Working before Aging on the Precipitation Behavior in a Cu-3.5 wt% Ti Alloy , 2019, Korean Journal of Metals and Materials.

[4]  Young Seok Kim,et al.  Investigation on the Relationship Between Transition Energy and the Color Change of Cu–M Alloys , 2018, Metals and Materials International.

[5]  Simultaneous increase in strength and ductility by decreasing interface energy between Zn and Al phases in cast Al-Zn-Cu alloy , 2017, Scientific Reports.

[6]  Je-hyun Lee,et al.  Optimization of conductivity and strength in Cu-Ni-Si alloys by suppressing discontinuous precipitation , 2016, Metals and Materials International.

[7]  M. Goto,et al.  Increasing strength and conductivity of Cu alloy through abnormal plastic deformation of an intermetallic compound , 2016, Scientific Reports.

[8]  M. Goto,et al.  Increasing toughness by promoting discontinuous precipitation in Cu–Ni–Si alloys , 2016 .

[9]  Byungchan Han,et al.  Design of exceptionally strong and conductive Cu alloys beyond the conventional speculation via the interfacial energy-controlled dispersion of γ-Al2O3 nanoparticles , 2015, Scientific Reports.

[10]  Je-hyun Lee,et al.  Ti-added alumina dispersion-strengthened Cu alloy fabricated by oxidation , 2015 .

[11]  S. Semboshi,et al.  Age-hardening behavior of a single-crystal Cu–ti alloy , 2014 .

[12]  Q. Lei,et al.  A new ultrahigh strength Cu-Ni-Si alloy , 2013 .

[13]  Hossein Vahid Dastjerdi,et al.  Influence of ageing process on sound velocity in C17200 copper-beryllium alloy , 2010 .

[14]  L. Yagmur Effect of microstructure on internal friction and Young's modulus of aged Cu–Be alloy , 2009 .

[15]  Y. Waseda,et al.  Improvement in strength and electrical conductivity of Cu–Ni–Si alloys by aging and cold rolling , 2006 .

[16]  Jun Wang,et al.  Study on high-strength and high-conductivity Cu–Fe–P alloys , 2006 .

[17]  D. Laughlin,et al.  High-strength age hardening copper–titanium alloys: redivivus , 2004 .

[18]  D. Markovic,et al.  Influence of degree of deformation in rolling on anneal hardening effect of a cast copper alloy , 2003 .

[19]  D. S. Sarma,et al.  Effect of prior cold work on mechanical properties, electrical conductivity and microstructure of aged Cu-Ti alloys , 1999 .

[20]  D. S. Sarma,et al.  On the variation of mechanical properties with solute content in Cu–Ti alloys , 1999 .

[21]  E. Gibson,et al.  Strength and conductivity ofin situ Cu-Fe alloys , 1989 .